The structures of all monochloro products obtainable by the radical chlorination of 2-methylpentane are to be given and named. Among them which are chiral is also to be stated. Concept introduction: The hydrogens present in an alkane can be classified into different types depending upon the nature of other groups attached to the carbon bearing them. During substitution reactions, the halogen will get substituted for all types of hydrogens leading to a mixture of monochloro substitution products. A molecule is chiral and will be optically active if it has at-least one carbon atom bonded to four different groups. To draw and name: All the monochloro substitution products C 6 H 13 Cl, obtainable when 2-methylbutane reacts with chlorine. To state: Which among the products obtained are chiral and optically active.

Question

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Answer 1

Question

Chapter 10.2, Problem 3P

Interpretation Introduction

Interpretation:

The structures of all monochloro products obtainable by the radical chlorination of 2-methylpentane are to be given and named. Among them which are chiral is also to be stated.

Concept introduction:

The hydrogens present in an alkane can be classified into different types depending upon the nature of other groups attached to the carbon bearing them. During substitution reactions, the halogen will get substituted for all types of hydrogens leading to a mixture of monochloro substitution products.

A molecule is chiral and will be optically active if it has at-least one carbon atom bonded to four different groups.

To draw and name:

All the monochloro substitution products C₆H₁₃Cl, obtainable when 2-methylbutane reacts with chlorine.

To state:

Which among the products obtained are chiral and optically active.

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Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 10.2, Problem 3P

Interpretation Introduction

Interpretation:

The structures of all monochloro products obtainable by the radical chlorination of 2-methylpentane are to be given and named. Among them which are chiral is also to be stated.

Concept introduction:

The hydrogens present in an alkane can be classified into different types depending upon the nature of other groups attached to the carbon bearing them. During substitution reactions, the halogen will get substituted for all types of hydrogens leading to a mixture of monochloro substitution products.

A molecule is chiral and will be optically active if it has at-least one carbon atom bonded to four different groups.

To draw and name:

All the monochloro substitution products C₆H₁₃Cl, obtainable when 2-methylbutane reacts with chlorine.

To state:

Which among the products obtained are chiral and optically active.

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Answer 3

Question

Chapter 10.2, Problem 3P

Interpretation Introduction

Interpretation:

The structures of all monochloro products obtainable by the radical chlorination of 2-methylpentane are to be given and named. Among them which are chiral is also to be stated.

Concept introduction:

The hydrogens present in an alkane can be classified into different types depending upon the nature of other groups attached to the carbon bearing them. During substitution reactions, the halogen will get substituted for all types of hydrogens leading to a mixture of monochloro substitution products.

A molecule is chiral and will be optically active if it has at-least one carbon atom bonded to four different groups.

To draw and name:

All the monochloro substitution products C₆H₁₃Cl, obtainable when 2-methylbutane reacts with chlorine.

To state:

Which among the products obtained are chiral and optically active.

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Answer 4

Question

Chapter 10.2, Problem 3P

Interpretation Introduction

Interpretation:

The structures of all monochloro products obtainable by the radical chlorination of 2-methylpentane are to be given and named. Among them which are chiral is also to be stated.

Concept introduction:

The hydrogens present in an alkane can be classified into different types depending upon the nature of other groups attached to the carbon bearing them. During substitution reactions, the halogen will get substituted for all types of hydrogens leading to a mixture of monochloro substitution products.

A molecule is chiral and will be optically active if it has at-least one carbon atom bonded to four different groups.

To draw and name:

All the monochloro substitution products C₆H₁₃Cl, obtainable when 2-methylbutane reacts with chlorine.

To state:

Which among the products obtained are chiral and optically active.

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Answer 5

Chapter 10.2, Problem 3P

Interpretation Introduction

Interpretation:

The structures of all monochloro products obtainable by the radical chlorination of 2-methylpentane are to be given and named. Among them which are chiral is also to be stated.

Concept introduction:

The hydrogens present in an alkane can be classified into different types depending upon the nature of other groups attached to the carbon bearing them. During substitution reactions, the halogen will get substituted for all types of hydrogens leading to a mixture of monochloro substitution products.

A molecule is chiral and will be optically active if it has at-least one carbon atom bonded to four different groups.

To draw and name:

All the monochloro substitution products C₆H₁₃Cl, obtainable when 2-methylbutane reacts with chlorine.

To state:

Which among the products obtained are chiral and optically active.

Answer 6

Chapter 10.2, Problem 3P

Interpretation Introduction

Interpretation:

The structures of all monochloro products obtainable by the radical chlorination of 2-methylpentane are to be given and named. Among them which are chiral is also to be stated.

Concept introduction:

The hydrogens present in an alkane can be classified into different types depending upon the nature of other groups attached to the carbon bearing them. During substitution reactions, the halogen will get substituted for all types of hydrogens leading to a mixture of monochloro substitution products.

A molecule is chiral and will be optically active if it has at-least one carbon atom bonded to four different groups.

To draw and name:

All the monochloro substitution products C₆H₁₃Cl, obtainable when 2-methylbutane reacts with chlorine.

To state:

Which among the products obtained are chiral and optically active.

Answer 7

Chapter 10.2, Problem 3P

Interpretation Introduction

Interpretation:

The structures of all monochloro products obtainable by the radical chlorination of 2-methylpentane are to be given and named. Among them which are chiral is also to be stated.

Concept introduction:

The hydrogens present in an alkane can be classified into different types depending upon the nature of other groups attached to the carbon bearing them. During substitution reactions, the halogen will get substituted for all types of hydrogens leading to a mixture of monochloro substitution products.

A molecule is chiral and will be optically active if it has at-least one carbon atom bonded to four different groups.

To draw and name:

All the monochloro substitution products C₆H₁₃Cl, obtainable when 2-methylbutane reacts with chlorine.

To state:

Which among the products obtained are chiral and optically active.

Answer 8

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Answer 19

Ch. 10.1 - Prob. 1P Ch. 10.1 - Draw structures corresponding to the following...Ch. 10.2 - Prob. 3P Ch. 10.2 - Taking the relative reactivities of 1Â°, 2Â°, and...Ch. 10.4 - Prob. 5P Ch. 10.4 - The major product of the reaction of...Ch. 10.4 - Prob. 7P Ch. 10.5 - Prob. 8P Ch. 10.6 - Prob. 9P Ch. 10.6 - How might you replace a halogen substituent by a...

Solution Summary: The author explains the structures of all monochloro products obtainable by the radical chlorination of 2-methylpentane.

Chapter 10 Solutions