Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th
Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th
9th Edition
ISBN: 9781305082144
Author: John E. McMurry
Publisher: Cengage Learning
bartleby

Concept explainers

Question
Book Icon
Chapter 10.SE, Problem 23AP
Interpretation Introduction

a) 2,3-Dichloro-4-methylhexane

Interpretation:

The structure corresponding to the IUPAC name 2,3-dichloro-4-methylhexane is to be given.

Concept introduction:

The longest continuous carbon chain in the molecule is chosen. The chain is numbered from the end which gives lowest number to the substituent either halo or alkyl group present. If different halogens are present they are numbered and listed in the alphabetical order while writing the name. If same two alternatives exist for different substituents, then the chain is numbered from the end that gives lowest number to the substituent that has alphabetical preference.

To give:

The structure corresponding to the IUPAC name 2,3-dichloro-4-methylhexane.

Interpretation Introduction

b) 4-Bromo-4-ethyl-2-methylhexane

Interpretation:

The structure corresponding to the IUPAC name 4-bromo-4-ethyl-2-ethylhexane is to be given.

Concept introduction:

The longest continuous carbon chain in the molecule is chosen. The chain is numbered from the end which gives lowest number to the substituent either halo or alkyl group present. If different halogens are present they are numbered and listed in the alphabetical order while writing the name. If same two alternatives exist for different substituents, then the chain is numbered from the end that gives lowest number to the substituent that has alphabetical preference.

To give:

The structure corresponding to the IUPAC name 4-bromo-4-ethyl-2-methylhexane.

Interpretation Introduction

c) 3-Iodo-2,2,4,4-tetramethylpentane

Interpretation:

The structure corresponding to the IUPAC name 3-iodo-2,2,4,4-tetramethylpentane is to be given.

Concept introduction:

The longest continuous carbon chain in the molecule is chosen. The chain is numbered from the end which gives lowest number to the substituent either halo or alkyl group present. If different halogens are present they are numbered and listed in the alphabetical order while writing the name. If same two alternatives exist for different substituents, then the chain is numbered from the end that gives lowest number to the substituent that has alphabetical preference.

To give:

The structure corresponding to the IUPAC name 3-iodo-2,2,4,4-tetramethylpentane.

Interpretation Introduction

d) cis-1-Bromo-2-ethycyclopentane

Interpretation:

The structure corresponding to the IUPAC name cis-1-bromo-2-ethylcyclopentane is to be given.

Concept introduction:

The number of carbon atoms present in a cycloalkane ring determine the parent name of the cycloalkane. If substituents are present the ring is numbered in such a way that lowest number is given to the substituents. While writing the name the substituents are arranged first in their alphabetical order followed by the parent name.

To give:

The structure corresponding to the IUPAC name cis-1-bromo-2-ethylcyclopentane.

Blurred answer
Students have asked these similar questions
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**
11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

Chapter 10 Solutions

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th

Ch. 10.7 - How would you carry out the following...Ch. 10.8 - Rank both sets of compounds in order of increasing...Ch. 10.8 - Tell whether each of the following reactions is an...Ch. 10.SE - Prob. 14VCCh. 10.SE - Prob. 15VCCh. 10.SE - Prob. 16VCCh. 10.SE - Draw the electron-pushing mechanism for each...Ch. 10.SE - Draw the electron-pushing mechanism for the...Ch. 10.SE - The formation of Br2 from NBS first involves the...Ch. 10.SE - In light of the fact that tertiary alkyl halides...Ch. 10.SE - Alkyl halides can be reduced to alkanes by a...Ch. 10.SE - Name the following alkyl halides:Ch. 10.SE - Prob. 23APCh. 10.SE - Draw and name all of the monochlorination products...Ch. 10.SE - How would you prepare the following compounds,...Ch. 10.SE - Prob. 26APCh. 10.SE - A chemist requires a large amount of...Ch. 10.SE - What product(s) would you expect from the reaction...Ch. 10.SE - What product(s) would you expect from the reaction...Ch. 10.SE - What product would you expect from the reaction of...Ch. 10.SE - Rank the compounds in each of the following series...Ch. 10.SE - Which of the following compounds have the same...Ch. 10.SE - Tell whether each of the following reactions is an...Ch. 10.SE - Prob. 34APCh. 10.SE - Alkylbenzenes such as toluene (methylbenzene)...Ch. 10.SE - Prob. 36APCh. 10.SE - Prob. 37APCh. 10.SE - Prob. 38APCh. 10.SE - Prob. 39APCh. 10.SE - Prob. 40APCh. 10.SE - The syntheses shown here are unlikely to occur as...Ch. 10.SE - Why do you suppose its not possible to prepare a...Ch. 10.SE - Prob. 43APCh. 10.SE - Identify the reagents a–c in the following...Ch. 10.SE - Prob. 45APCh. 10.SE - Prob. 46APCh. 10.SE - Prob. 47APCh. 10.SE - The relative rate of radical bromination is...Ch. 10.SE - Prob. 49APCh. 10.SE - Predict the product and provide the entire...
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY