The major product should be given, if NH 3 shift occurs. Concept introduction: Aromaticity: The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are, The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Answer 1

Question

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1

AE>AE₁ (Y/N) AE=AE₁ (Y/N) AE

Treatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and gives compound A. ? NH2 Br Br Propose a structural formula for compound A. You do not have to explicitly draw H atoms. You do not have to consider stereochemistry. In cases where there is more than one answer, just draw one. R3N C14H19NO2 + 2 R3NH*Br A

Answer 2

Question

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Answer 3

Question

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Answer 4

Question

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Answer 5

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 6

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 7

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 10.1 - Why are NH3 and CH3NH2 no longer nucleophiles when...Ch. 10.1 - Explain the difference in reactivity between...Ch. 10.1 - Prob. 5P Ch. 10.1 - Prob. 6P Ch. 10.1 - Prob. 8P Ch. 10.2 - Prob. 9P Ch. 10.3 - Prob. 11P Ch. 10.3 - Show how 1-propanol can be converted into the...Ch. 10.4 - Which of the following alcohols dehydrates the...Ch. 10.4 - Prob. 14P

Solution Summary: The author explains that aromatic compounds are type of organic compounds, which has a special property's in the reactivity and structure.

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