Essential Organic Chemistry (3rd Edition)

3rd Edition

ISBN: 9780321937711

Author: Paula Yurkanis Bruice

Publisher: PEARSON

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NMR Spectroscopy

NMR stands for Nuclear Magnetic Resonance in which the study of different molecules is done based on the interaction of radiofrequency electromagnetic radiations with the nuclei of molecules placed in a strong magnetic field. A precise study of spectra o…

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Textbook Question

Chapter 10.28, Problem 46P

Describe the ¹H NMR spectrum you would expect for each of the following compounds, Indicating the relative positions of the signals:

a. BrCH₂CH₂CH₂CH₂Br
b. CH₃OCH₂CH₂CH₂Br
c. CH₃CH₂OCH₂CH₃
d. CH₃CH₂OCH₂Cl

Chapter 10.28, Problem 46P, Describe the 1H NMR spectrum you would expect for each of the following compounds, Indicating the , example 1

e. CH₃OCH₂CH₂CH₂OCH₃

Chapter 10.28, Problem 46P, Describe the 1H NMR spectrum you would expect for each of the following compounds, Indicating the , example 2

Chapter 10.28, Problem 46P, Describe the 1H NMR spectrum you would expect for each of the following compounds, Indicating the , example 3

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Chapter 10.28, Problem 45P

Chapter 10.28, Problem 47P

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Chapter 10 Solutions

Essential Organic Chemistry (3rd Edition)

Ch. 10.1 - Prob. 1P Ch. 10.2 - What would distinguish the mass spectrum of...Ch. 10.2 - Prob. 3P Ch. 10.3 - Prob. 5P Ch. 10.3 - Suggest possible molecular formulas for a compound...Ch. 10.3 - Prob. 7P Ch. 10.4 - Prob. 8P Ch. 10.4 - Prob. 9P Ch. 10.5 - Prob. 10P Ch. 10.5 - Prob. 11P

Ch. 10.6 - Identify the ketone responsible for the mass...Ch. 10.6 - Prob. 13P Ch. 10.8 - Prob. 14P Ch. 10.8 - Prob. 15P Ch. 10.12 - Which will occur at a larger wavenumber: a. a C :...Ch. 10.13 - Which will occur at a larger wavenumber: a. the C...Ch. 10.13 - Prob. 18P Ch. 10.13 - Prob. 19P Ch. 10.13 - Which will show an O 8 H stretch at a larger...Ch. 10.14 - Prob. 21P Ch. 10.14 - Prob. 22P Ch. 10.15 - Prob. 23P Ch. 10.15 - Prob. 24P Ch. 10.17 - Prob. 25P Ch. 10.18 - Prob. 26P Ch. 10.18 - Prob. 27P Ch. 10.19 - Prob. 28P Ch. 10.19 - Prob. 29P Ch. 10.22 - How many signals would you expect to see in the 1H...Ch. 10.22 - Prob. 31P Ch. 10.22 - Prob. 32P Ch. 10.23 - Where would you expect to find the 1H NMR signal...Ch. 10.24 - Prob. 34P Ch. 10.25 - Prob. 35P Ch. 10.25 - Prob. 36P Ch. 10.25 - Prob. 37P Ch. 10.26 - Prob. 38P Ch. 10.26 - Which of the following compounds is responsible...Ch. 10.27 - Prob. 40P Ch. 10.27 - Prob. 41P Ch. 10.27 - The 1H NMR spectra of two carboxylic acids with...Ch. 10.28 - Prob. 43P Ch. 10.28 - Prob. 44P Ch. 10.28 - Prob. 45P Ch. 10.28 - Describe the 1H NMR spectrum you would expect for...Ch. 10.28 - Identify the compound with molecular formula...Ch. 10.29 - Prob. 48P Ch. 10.29 - Prob. 49P Ch. 10.29 - Identify the compound with a molecular formula of...Ch. 10 - In the mass spectrum of the following compounds,...Ch. 10 - For each of the following pairs of compounds,...Ch. 10 - Draw the structure of a saturated hydrocarbon that...Ch. 10 - Prob. 54P Ch. 10 - Prob. 55P Ch. 10 - How could you use UV spectroscopy to distinguish...Ch. 10 - Prob. 57P Ch. 10 - Predict the relative intensities of the molecular...Ch. 10 - Prob. 59P Ch. 10 - List the following compounds in order from highest...Ch. 10 - How can 1H NMR be used to prove that the addition...Ch. 10 - There are four esters with molecular formula...Ch. 10 - Prob. 63P Ch. 10 - Prob. 64P Ch. 10 - Each of the IR spectra presented here is...Ch. 10 - Prob. 66P Ch. 10 - Five compounds are shown for each of the following...Ch. 10 - Prob. 68P Ch. 10 - Prob. 69P Ch. 10 - Phenolphthalein is an acidbase indicator. In...Ch. 10 - Which one of the following five compounds produced...Ch. 10 - Prob. 72P Ch. 10 - Prob. 73P Ch. 10 - Prob. 74P Ch. 10 - How could 1H NMR distinguish between the compounds...Ch. 10 - Prob. 76P Ch. 10 - Prob. 77P Ch. 10 - The 1H NMR spectra of three isomers with molecular...Ch. 10 - The 1H NMR spectra of three isomers with molecular...Ch. 10 - Identify the following compounds. (Relative...Ch. 10 - An alkyl halide reacts with an alkoxide ion to...Ch. 10 - Determine the structure of a compound with...

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Describe the 1 H NMR spectrum you would expect for each of the following compounds, Indicating the relative positions of the signals: a. BrCH 2 CH 2 CH 2 CH 2 Br b. CH 3 OCH 2 CH 2 CH 2 Br c. CH 3 CH 2 OCH 2 CH 3 d. CH 3 CH 2 OCH 2 Cl e. CH 3 OCH 2 CH 2 CH 2 OCH 3

Solution Summary: The author explains that the chemical shift values of the proton varies relative to the reference signal. The two non-equivalent sets of protons labelled as ‘a’ and ‘b’ are present in the compound.

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Chapter 10 Solutions