Foundations of Materials Science and Engineering
6th Edition
ISBN: 9781259696558
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 10.14, Problem 194SEP
(a) In selecting the materials for an infant milk bottle, what factors should you consider? (b) Would polystyrene be a good choice? (c) What material would you select for this application? Use chapter tables and the appendices in the back.
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Answer the following questions.
i) Write down the important properties of
polymers.
ii) What do you mean by a highly elastic
material and provide an example for that
material. .
iii) Which type of polymer is used to
manufacture plastic pipes and explain the
characteristics of that polymer. (Minimum 2
points) -
Molecular weight data for some polymer are tabulated here. Compute (a) the number-average
molecular weight, (b) the weight-average molecular weight. (c) If it is known that this material's degree of
polymerization is 710, which one of the polymers listed in Table 14.3 is this polymer? Why?
Molecular Weight
Range g/mol
15,000-30,000
Xi
Wi
0.04
0.01
30,000-45,000
0.07
0.04
45,000-60,000
0.16
0.11
60,000-75,000
0.26
0.24
75,000-90,000
0.24
0.27
90,000 105,000
0.12
0.16
105,000-120,000
0.08
0.12
120,000-135,000
0.03
0.05
(a) Draw a qualitative engineering stress-strain curve for
A Ductile polymer
(i)
(ii) A Metal
(iii) A ceramic
(Iv)
(v)
A glass
A Natural rubber
Label carefully. Rationalize your sketch for each material
Chapter 10 Solutions
Foundations of Materials Science and Engineering
Ch. 10.14 - Define and differentiate polymers, plastics, and...Ch. 10.14 - (a) Describe the atomic structural arrangement of...Ch. 10.14 - What is a pendant atom or group of atoms?Ch. 10.14 - (a)What type of bonding exists within the...Ch. 10.14 - Prob. 5KCPCh. 10.14 - Prob. 6KCPCh. 10.14 - Prob. 7KCPCh. 10.14 - (a) What is the repeating chemical unit of a...Ch. 10.14 - What are the three major reactions that occur...Ch. 10.14 - Prob. 10KCP
Ch. 10.14 - (a) Why must one consider the average degree of...Ch. 10.14 - Prob. 12KCPCh. 10.14 - Write structural formulas for the mers of the...Ch. 10.14 - Prob. 14KCPCh. 10.14 - Prob. 15KCPCh. 10.14 - Prob. 16KCPCh. 10.14 - Define stepwise polymerization of linear polymers....Ch. 10.14 - What are three basic raw materials used to produce...Ch. 10.14 - Describe and illustrate the following...Ch. 10.14 - Prob. 20KCPCh. 10.14 - Prob. 21KCPCh. 10.14 - Prob. 22KCPCh. 10.14 - Prob. 23KCPCh. 10.14 - Prob. 24KCPCh. 10.14 - Prob. 25KCPCh. 10.14 - Prob. 26KCPCh. 10.14 - Prob. 27KCPCh. 10.14 - Prob. 28KCPCh. 10.14 - Prob. 29KCPCh. 10.14 - (a) Describe the compression-molding process for...Ch. 10.14 - (a) Describe the transfer-molding process for...Ch. 10.14 - Prob. 32KCPCh. 10.14 - Define an engineering thermoplastic. Why is this...Ch. 10.14 - What is the structural formula for the amide...Ch. 10.14 - (a) In the designation nylon 6,6, what does the...Ch. 10.14 - Prob. 36KCPCh. 10.14 - Prob. 37KCPCh. 10.14 - Prob. 38KCPCh. 10.14 - Prob. 39KCPCh. 10.14 - Prob. 40KCPCh. 10.14 - Prob. 41KCPCh. 10.14 - Prob. 42KCPCh. 10.14 - Prob. 43KCPCh. 10.14 - Prob. 44KCPCh. 10.14 - (a) What are the major processing methods used for...Ch. 10.14 - Prob. 46KCPCh. 10.14 - Prob. 47KCPCh. 10.14 - Prob. 48KCPCh. 10.14 - What is natural rubber mainly made of? What other...Ch. 10.14 - Prob. 50KCPCh. 10.14 - Prob. 51KCPCh. 10.14 - Prob. 52KCPCh. 10.14 - Prob. 53KCPCh. 10.14 - What is the vulcanization process for natural...Ch. 10.14 - Prob. 55KCPCh. 10.14 - Prob. 56KCPCh. 10.14 - What are the silicones? What is the general...Ch. 10.14 - Prob. 58KCPCh. 10.14 - Prob. 59KCPCh. 10.14 - Prob. 60KCPCh. 10.14 - Prob. 61KCPCh. 10.14 - Define the creep modulus of a plastic material.Ch. 10.14 - What is a craze in a glassy thermoplastic?Ch. 10.14 - Describe the structure of a craze in a...Ch. 10.14 - Prob. 65KCPCh. 10.14 - Prob. 66AAPCh. 10.14 - Prob. 67AAPCh. 10.14 - Prob. 68AAPCh. 10.14 - An injection-molding polycarbonate material has an...Ch. 10.14 - Prob. 70AAPCh. 10.14 - Prob. 71AAPCh. 10.14 - Prob. 72AAPCh. 10.14 - Prob. 73AAPCh. 10.14 - How much sulfur must be added to 70 g of butadiene...Ch. 10.14 - If 5 g of sulfur is added to 90 g of butadiene...Ch. 10.14 - Prob. 76AAPCh. 10.14 - Prob. 77AAPCh. 10.14 - Prob. 78AAPCh. 10.14 - Prob. 79AAPCh. 10.14 - Prob. 80AAPCh. 10.14 - Prob. 81AAPCh. 10.14 - Prob. 82AAPCh. 10.14 - Prob. 83AAPCh. 10.14 - A polymeric material has a relaxation time of 60...Ch. 10.14 - Prob. 85AAPCh. 10.14 - Prob. 86AAPCh. 10.14 - Prob. 87AAPCh. 10.14 - Prob. 88AAPCh. 10.14 - Prob. 89AAPCh. 10.14 - Prob. 90AAPCh. 10.14 - Prob. 91AAPCh. 10.14 - Prob. 92AAPCh. 10.14 - Prob. 93AAPCh. 10.14 - (a) What causes a polyethylene molecular chain to...Ch. 10.14 - Prob. 95AAPCh. 10.14 - Prob. 96AAPCh. 10.14 - Prob. 97AAPCh. 10.14 - Prob. 98AAPCh. 10.14 - Write the reaction for the stepwise polymerization...Ch. 10.14 - Prob. 100AAPCh. 10.14 - Prob. 101AAPCh. 10.14 - How does chain branching affect the following...Ch. 10.14 - (a) Write the general reaction for the...Ch. 10.14 - Prob. 104AAPCh. 10.14 - Prob. 105AAPCh. 10.14 - Prob. 106AAPCh. 10.14 - Prob. 107AAPCh. 10.14 - Prob. 108AAPCh. 10.14 - Prob. 109AAPCh. 10.14 - Prob. 110AAPCh. 10.14 - Prob. 111AAPCh. 10.14 - Prob. 112AAPCh. 10.14 - Prob. 113AAPCh. 10.14 - Prob. 114AAPCh. 10.14 - Prob. 115AAPCh. 10.14 - Prob. 116AAPCh. 10.14 - Prob. 117AAPCh. 10.14 - Prob. 118AAPCh. 10.14 - Prob. 119AAPCh. 10.14 - Prob. 120AAPCh. 10.14 - What are two types of reaction sites that are...Ch. 10.14 - Prob. 122AAPCh. 10.14 - Prob. 123AAPCh. 10.14 - Prob. 124AAPCh. 10.14 - Prob. 125AAPCh. 10.14 - Prob. 126AAPCh. 10.14 - How does cross-linking with sulfur affect the...Ch. 10.14 - Prob. 128AAPCh. 10.14 - Can SBR be vulcanized? Explain.Ch. 10.14 - Prob. 130AAPCh. 10.14 - Write the repeating chemical structural unit for...Ch. 10.14 - Prob. 132AAPCh. 10.14 - Prob. 133AAPCh. 10.14 - Prob. 134AAPCh. 10.14 - Prob. 135AAPCh. 10.14 - Prob. 136AAPCh. 10.14 - Prob. 137AAPCh. 10.14 - Explain how highly polar atoms bonded to the main...Ch. 10.14 - Prob. 139AAPCh. 10.14 - Prob. 140AAPCh. 10.14 - Prob. 141AAPCh. 10.14 - Prob. 142AAPCh. 10.14 - Prob. 143AAPCh. 10.14 - Prob. 144AAPCh. 10.14 - Why do cured thermoset plastics not become viscous...Ch. 10.14 - Prob. 146AAPCh. 10.14 - Prob. 147AAPCh. 10.14 - Prob. 148AAPCh. 10.14 - Prob. 149AAPCh. 10.14 - Prob. 150AAPCh. 10.14 - Prob. 151AAPCh. 10.14 - Prob. 152AAPCh. 10.14 - Prob. 153AAPCh. 10.14 - Prob. 154AAPCh. 10.14 - Prob. 155AAPCh. 10.14 - Prob. 156AAPCh. 10.14 - Prob. 157AAPCh. 10.14 - Prob. 158AAPCh. 10.14 - Prob. 159AAPCh. 10.14 - Prob. 160AAPCh. 10.14 - Prob. 161AAPCh. 10.14 - Prob. 162AAPCh. 10.14 - Prob. 163AAPCh. 10.14 - Prob. 164AAPCh. 10.14 - Prob. 165AAPCh. 10.14 - Prob. 166AAPCh. 10.14 - Prob. 167AAPCh. 10.14 - Prob. 168AAPCh. 10.14 - Prob. 169AAPCh. 10.14 - Prob. 170AAPCh. 10.14 - Prob. 171AAPCh. 10.14 - Prob. 172AAPCh. 10.14 - Prob. 173AAPCh. 10.14 - Prob. 174AAPCh. 10.14 - Prob. 175AAPCh. 10.14 - Prob. 176AAPCh. 10.14 - Prob. 178AAPCh. 10.14 - Prob. 179AAPCh. 10.14 - What are some of the advantages of epoxy thermoset...Ch. 10.14 - How are most unsaturated polyesters reinforced?Ch. 10.14 - What are some applications for reinforced...Ch. 10.14 - Prob. 183AAPCh. 10.14 - Prob. 187SEPCh. 10.14 - Prob. 188SEPCh. 10.14 - Prob. 189SEPCh. 10.14 - Prob. 190SEPCh. 10.14 - Prob. 191SEPCh. 10.14 - Prob. 192SEPCh. 10.14 - Prob. 193SEPCh. 10.14 - (a) In selecting the materials for an infant milk...Ch. 10.14 - Prob. 195SEPCh. 10.14 - Prob. 196SEPCh. 10.14 - (a) In selecting the materials for compact discs,...Ch. 10.14 - Prob. 198SEPCh. 10.14 - Prob. 199SEPCh. 10.14 - Prob. 200SEPCh. 10.14 - (a) In selecting the materials for a bungee cord,...Ch. 10.14 - Prob. 202SEPCh. 10.14 - Prob. 203SEPCh. 10.14 - In orthopedic applications related to knee and hip...
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- ( B ) A stress of 6.7 MPa is employed to one type of a polymer under constant strain . After 40 days at 20 ° C the stress is reduced to only 8.4 MPa . When the same polymer is heated to 40 ° C the relaxation time is 40 days . 1- Calculate the relaxation time constant for this material at 25 ° C ? 2- Estimate the stress after 50 days at 25 ° C ? 3- Estimate the stress relaxation activation energy for the same polymer .arrow_forwardNowadays, many cooking utensils are made of polymeric materials. However, people believe that heating plastic utensils would cause harm such as releasing toxic substances. Hence, people are looking for other alternatives to replace plastic. Choose ONE cooking utensil (spatula) and identify the suitable material that will satisfy its criteria. Justify your answer. Your discussion must include the interrelationship between structure-properties-processing of the selected cooking utensil.arrow_forwardFrom the attached image. Annotate and explain the phases of the polymer stress-strain curve.arrow_forward
- sketch the generalized stress-strain curve for a semi-crystalline thermoplastic polymer.arrow_forwardi need the answer quicklyarrow_forwardQuestion Seven (Plastics) The data below is from a fibre reinforced plastic. Would this composite be suitable for use at 400°C? Explain your answer. Temperature (°C) 20 100 200 300 400 500 600 Plastic A Plastic B Plastic C Yield Strength (MPa) 270 350 47 Tensile Strength (MPa) 300 500 52 E (GPa) 130 3 14 115 100 95 Question Eight (Plastics) Identify the thermoplastic, the elastomer and the thermoset. 70 58 0 Young's Modulus (GPa) Elongation (%) 12 3 600arrow_forward
- Course: Engineering Materialsarrow_forwardAn unknown polymer sample was found to have the following molecular weight distribution: Molecular weight range 8,000 - 20,000 20,000 - 32,000 32,000 - 44,000 44,000 - 56,000 56,000 - 68,000 68,000 -80,000 80,000 - 92,000 0.03 Knowing that the monomer is methyl methacrylate, which of the below is the number average degree of polymerization for this polymer sample? Select one: O a. O b. DP 476 O C. DP = 338 DP = 664 O d. DP 544 O e. DP = 801 Xi 0.05 0.15 0.21 0.28 0.18 0.10 Wi 0.02 0.08 0.17 0.29 0.23 0.16 0.05arrow_forwardFor a given polymer, the activation energy for stress relaxation was measured to be 10 kJ/mol. If the stress relaxation time for this polymer at room temperature is 3,600 s, what would be the relaxation time at 100 ◦C?arrow_forward
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