
Basic Chemistry Plus Mastering Chemistry With Pearson Etext -- Access Card Package (6th Edition)
6th Edition
ISBN: 9780134983783
Author: Karen C. Timberlake
Publisher: PEARSON
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Question
Chapter 10, Problem 98APP
Interpretation Introduction
Interpretation:
The reason of spraying water on the fruits near freezing needs to be explained.
Concept Introduction:
The heat required for vaporization process in which water changes from liquid state to vapor state is known as heat of vaporization and when it changes from solid to liquid, the heat required is known as heat of fusion. The heat is required in changing the phase of water from solid to liquid or from liquid to vapor. Thus, when the water changes its state from vapor to liquid the heat is released, and the value is negative to that of heat of vaporization.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 10 Solutions
Basic Chemistry Plus Mastering Chemistry With Pearson Etext -- Access Card Package (6th Edition)
Ch. 10.1 - Determine the total number of valence electrons...Ch. 10.1 - Determine the total number of valence electrons...Ch. 10.1 - Prob. 3PPCh. 10.1 - If the available number of valence electrons for a...Ch. 10.1 - Draw the Lewis structures for each of the...Ch. 10.1 - Draw the Lewis structures for each of the...Ch. 10.1 - Draw the Lewis structures for each of the...Ch. 10.1 - Draw the Lewis structures for each of the...Ch. 10.2 - Prob. 9PPCh. 10.2 - When does a molecular compound have resonance?
Ch. 10.2 - Draw two resonance structures for each of the...Ch. 10.2 - Draw two resonance structures for each of the...Ch. 10.3 - Prob. 13PPCh. 10.3 - Choose the shape (1 to 6) that matches each of the...Ch. 10.3 - Prob. 15PPCh. 10.3 - Prob. 16PPCh. 10.3 - Prob. 17PPCh. 10.3 - Prob. 18PPCh. 10.3 - Use VSEPR theory to predict the shape of each of...Ch. 10.3 - Prob. 20PPCh. 10.3 - Prob. 21PPCh. 10.3 - Draw the Lewis structure and predict the shape for...Ch. 10.4 - Describe the trend in electronegativity as...Ch. 10.4 - Describe the trend in electronegativity as...Ch. 10.4 - Prob. 25PPCh. 10.4 - Which electronegativity difference (a, b, or c)...Ch. 10.4 - Using the periodic table, arrange the atoms in...Ch. 10.4 - Using the periodic table, arrange the atoms in...Ch. 10.4 - Predict whether the bond between each of the...Ch. 10.4 - Predict whether the bond between each of the...Ch. 10.4 - For the bond between each of the following pairs...Ch. 10.4 - For the bond between each of the following pairs...Ch. 10.5 - Why is F2 a nonpolar molecule, but HF is a polar...Ch. 10.5 - Why is CCl4 a nonpolar molecule, but PCl3 is a...Ch. 10.5 - Identify each of the following molecules as polar...Ch. 10.5 - Identify each of the following molecules as polar...Ch. 10.5 - Prob. 37PPCh. 10.5 - Prob. 38PPCh. 10.6 - Prob. 39PPCh. 10.6 - Prob. 40PPCh. 10.6 - Identify the strongest intermolecular forces...Ch. 10.6 - Identify the strongest intermolecular forces...Ch. 10.6 - Prob. 43PPCh. 10.6 - Prob. 44PPCh. 10.7 - Using Figure 10.6, calculate the heat change...Ch. 10.7 - Using Figure 10.6, calculate the heat change...Ch. 10.7 - Prob. 47PPCh. 10.7 - Using Figure 10.6, calculate the heat change...Ch. 10.7 - Using Figure 10.6 and the specific heat of water,...Ch. 10.7 - Using Figure 10.6 and the specific heat of water,...Ch. 10.7 - An ice bag containing 275 g of ice at 0 °C was...Ch. 10.7 - Prob. 52PPCh. 10.7 - Prob. 53PPCh. 10.7 - In the preparation of liquid nitrogen, how many...Ch. 10.7 - Using the electronegativity values in Figure 10.2,...Ch. 10.7 - Prob. 56PPCh. 10.7 - Prob. 57PPCh. 10.7 - a. Draw two resonance structures for bicarbonate...Ch. 10 - State the number of valence electrons, bonding...Ch. 10 - State the number of valence electrons, bonding...Ch. 10 - Prob. 61UTCCh. 10 - Prob. 62UTCCh. 10 - Consider the following bonds: Ca and O, C and O, K...Ch. 10 - Consider the following bonds: F and Cl, Cl and Cl,...Ch. 10 - Identify the major intermolecular forces between...Ch. 10 - Prob. 66UTCCh. 10 - Prob. 67UTCCh. 10 - Prob. 68UTCCh. 10 - Prob. 69UTCCh. 10 - Prob. 70UTCCh. 10 - Prob. 71UTCCh. 10 - Prob. 72UTCCh. 10 - Prob. 73APPCh. 10 - Determine the total number of valence electrons in...Ch. 10 - Draw the Lewis structures for each of the...Ch. 10 - Draw the Lewis structures for each of the...Ch. 10 - Draw resonance structures for each of the...Ch. 10 - Prob. 78APPCh. 10 - Use the periodic table to arrange the following...Ch. 10 - Use the periodic table to arrange the following...Ch. 10 - Select the more polar bond in each of the...Ch. 10 - Select the more polar bond in each of the...Ch. 10 - Show the dipole arrow for each of the following...Ch. 10 - Show the dipole arrow for each of the following...Ch. 10 - Calculate the electronegativity difference and...Ch. 10 - Calculate the electronegativity difference and...Ch. 10 - Prob. 87APPCh. 10 - For each of the following, draw the Lewis...Ch. 10 - For each of the following, draw the Lewis...Ch. 10 - For each of the following, draw the Lewis...Ch. 10 - Prob. 91APPCh. 10 - Predict the shape and polarity of each of the...Ch. 10 - Prob. 93APPCh. 10 - Prob. 94APPCh. 10 - Prob. 95APPCh. 10 - Indicate the major type of intermolecular...Ch. 10 - When it rains or snows, the air temperature seems...Ch. 10 - Prob. 98APPCh. 10 - Using Figure 10.6, calculate the grams of ice that...Ch. 10 - Using Figure 10.6, calculate the grams of ethanol...Ch. 10 - Prob. 101APPCh. 10 - Using Figure 10.6, calculate the grams of benzene...Ch. 10 - Prob. 103CPCh. 10 - Prob. 104CPCh. 10 - Prob. 105CPCh. 10 - Prob. 106CPCh. 10 - Prob. 107CPCh. 10 - The melting point of benzene is 5.5 °C, and its...Ch. 10 - A 45.0-g piece of ice at 0.0 °C is added to a...Ch. 10 - An ice cube at 0 °C with a mass of 115 g is added...Ch. 10 - Prob. 111CPCh. 10 - Prob. 112CPCh. 10 - Prob. 13CICh. 10 - Prob. 14CICh. 10 - Prob. 15CICh. 10 - Ethanol, C2H6O , is obtained from renewable crops...Ch. 10 - Chloral hydrate, a sedative and hypnotic, was the...Ch. 10 - Ethylene glycol, C2H6O2 , used as a coolant and...Ch. 10 - Prob. 19CICh. 10 - Prob. 20CI
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