EBK CHEMISTRY: AN ATOMS FIRST APPROACH
2nd Edition
ISBN: 9780100552234
Author: ZUMDAHL
Publisher: YUZU
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Question
Chapter 10, Problem 96AE
Interpretation Introduction
Interpretation: The given molarity of Ethanol has to be calculated.
Concept Introduction:
Concentration can be defined in terms of molarity as moles of solute per volume of solution in litres. It can be given by the expression,
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redraw the flowchart with boxes and molecules written in them
Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Chapter 10 Solutions
EBK CHEMISTRY: AN ATOMS FIRST APPROACH
Ch. 10 - Prob. 1RQCh. 10 - Using KF as an example, write equations that refer...Ch. 10 - Prob. 3RQCh. 10 - Prob. 4RQCh. 10 - Define the terms in Raoults law. Figure 10-9...Ch. 10 - In terms of Raoults law, distinguish between an...Ch. 10 - Prob. 7RQCh. 10 - Prob. 8RQCh. 10 - Prob. 9RQCh. 10 - Prob. 10RQ
Ch. 10 - Prob. 1ALQCh. 10 - Prob. 2ALQCh. 10 - Prob. 3ALQCh. 10 - Prob. 4ALQCh. 10 - You have read that adding a solute to a solvent...Ch. 10 - Prob. 6ALQCh. 10 - Prob. 7ALQCh. 10 - Prob. 8ALQCh. 10 - Prob. 9ALQCh. 10 - Prob. 10ALQCh. 10 - Rubbing alcohol contains 585 g isopropanol...Ch. 10 - Prob. 12SRCh. 10 - Prob. 13SRCh. 10 - Prob. 14SRCh. 10 - Calculate the sodium ion concentration when 70.0...Ch. 10 - Write equations showing the ions present after the...Ch. 10 - Prob. 17QCh. 10 - The weak electrolyte NH3(g) does not obey Henrys...Ch. 10 - The two beakers in the sealed container...Ch. 10 - The following plot shows the vapor pressure of...Ch. 10 - Prob. 21QCh. 10 - Prob. 22QCh. 10 - Prob. 23QCh. 10 - Prob. 24QCh. 10 - Prob. 25QCh. 10 - Prob. 26QCh. 10 - Explain the terms isotonic solution, crenation,...Ch. 10 - Prob. 28QCh. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Common commercial acids and bases are aqueous...Ch. 10 - In lab you need to prepare at least 100 mL of each...Ch. 10 - Prob. 33ECh. 10 - Prob. 34ECh. 10 - Prob. 35ECh. 10 - Calculate the molarity and mole fraction of...Ch. 10 - Prob. 37ECh. 10 - Prob. 38ECh. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Although Al(OH)3 is insoluble in water, NaOH is...Ch. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - Prob. 44ECh. 10 - Prob. 45ECh. 10 - Which ion in each of the following pairs would you...Ch. 10 - Rationalize the trend in water solubility for the...Ch. 10 - Prob. 48ECh. 10 - The solubility of nitrogen in water is 8.21 104...Ch. 10 - Calculate the solubility of O2 in water at a...Ch. 10 - Glycerin, C3H8O3, is a nonvolatile liquid. What is...Ch. 10 - Prob. 52ECh. 10 - The normal boiling point of diethyl ether is...Ch. 10 - At a certain temperature, the vapor pressure of...Ch. 10 - A solution is made by dissolving 25.8 g urea...Ch. 10 - A solution of sodium chloride in water has a vapor...Ch. 10 - Prob. 57ECh. 10 - A solution is prepared by mixing 0.0300 mole of...Ch. 10 - What is the composition of a methanol...Ch. 10 - Benzene and toluene form an ideal solution....Ch. 10 - Which of the following will have the lowest total...Ch. 10 - Prob. 62ECh. 10 - Match the vapor pressure diagrams with the...Ch. 10 - The vapor pressures of several solutions of...Ch. 10 - A solution is prepared by dissolving 27.0 g urea,...Ch. 10 - A 2.00-g sample of a large biomolecule was...Ch. 10 - What mass of glycerin (C3H8O3), a nonelectrolyte,...Ch. 10 - The freezing point of 1-butanol is 25.50C and Kf...Ch. 10 - Prob. 69ECh. 10 - What volume of ethylene glycol (C2H6O2), a...Ch. 10 - Reserpine is a natural product isolated from the...Ch. 10 - A solution contains 3.75 g of a nonvolatile pure...Ch. 10 - a. Calculate the freezing-point depression and...Ch. 10 - Erythrocytes are red blood cells containing...Ch. 10 - Prob. 75ECh. 10 - Prob. 76ECh. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - Consider the following solutions: 0.010 m Na3PO4...Ch. 10 - From the following: pure water solution of...Ch. 10 - Prob. 81ECh. 10 - Prob. 82ECh. 10 - Prob. 83ECh. 10 - Consider the following representations of an ionic...Ch. 10 - Prob. 85ECh. 10 - Prob. 86ECh. 10 - Use the following data for three aqueous solutions...Ch. 10 - The freezing-point depression of a 0.091-m...Ch. 10 - Prob. 89ECh. 10 - A 0.500-g sample of a compound is dissolved in...Ch. 10 - The solubility of benzoic acid (HC7H5O2), is 0.34...Ch. 10 - Prob. 92AECh. 10 - Prob. 94AECh. 10 - Explain the following on the basis of the behavior...Ch. 10 - Prob. 96AECh. 10 - Prob. 97AECh. 10 - Prob. 98AECh. 10 - A solution is made by mixing 50.0 g acetone...Ch. 10 - Prob. 100AECh. 10 - Prob. 101AECh. 10 - Prob. 102AECh. 10 - An unknown compound contains only carbon,...Ch. 10 - Prob. 104AECh. 10 - Prob. 105AECh. 10 - Prob. 106AECh. 10 - Prob. 107AECh. 10 - Prob. 108AECh. 10 - Patients undergoing an upper gastrointestinal...Ch. 10 - Prob. 110CWPCh. 10 - Prob. 111CWPCh. 10 - For each of the following pairs, predict which...Ch. 10 - The normal boiling point of methanol is 64.7C. A...Ch. 10 - A solution is prepared by mixing 1.000 mole of...Ch. 10 - Prob. 115CWPCh. 10 - A 4.7 102 mg sample of a protein is dissolved in...Ch. 10 - Prob. 117CWPCh. 10 - The vapor pressure of pure benzene is 750.0 torr...Ch. 10 - Prob. 119CPCh. 10 - Plants that thrive in salt water must have...Ch. 10 - You make 20.0 g of a sucrose (C12H22O11) and NaCl...Ch. 10 - Prob. 122CPCh. 10 - The vapor in equilibrium with a pentane-hexane...Ch. 10 - Prob. 124CPCh. 10 - Prob. 125CPCh. 10 - Prob. 126CPCh. 10 - Prob. 127CPCh. 10 - You have a solution of two volatile liquids, A and...Ch. 10 - In some regions of the southwest United States,...Ch. 10 - Prob. 130IPCh. 10 - An aqueous solution containing 0.250 mole of Q, a...Ch. 10 - Anthraquinone contains only carbon, hydrogen, and...
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- What is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forwardNonearrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY