Chemistry: The Central Science (13th Edition)
13th Edition
ISBN: 9780321910417
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 10, Problem 91E
(a)
Interpretation Introduction
To determine:
The experimental conditions under which gases deviate from ideal behavior.
(b)
Interpretation Introduction
To determine:
The reasons for the gases to deviate from
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 10 Solutions
Chemistry: The Central Science (13th Edition)
Ch. 10.2 - Classify each of the following as a pure substance...Ch. 10.2 - Classify each of the following as a pure substance...Ch. 10.2 - 1.15 Give the chemical symbol or name for the...Ch. 10.2 - 1.16 Give the chemical symbol or name for each of...Ch. 10.3 - A solid white substance A is heated strongly in...Ch. 10.3 - 1.18 You are hiking in the mountains and find a...Ch. 10.4 - 1.19 In the process of attempting to characterize...Ch. 10.4 - 1.20
Read the following description of the element...Ch. 10.4 - Prob. 10.5.1PECh. 10.4 - A match is lit and held under a cold piece of...
Ch. 10.4 - Which separation method is better suited for...Ch. 10.4 - Two beakers contain clear, colorless liquids. When...Ch. 10.5 - Prob. 10.7.1PECh. 10.5 - Prob. 10.7.2PECh. 10.5 - Prob. 10.8.1PECh. 10.5 - Prob. 10.8.2PECh. 10.5 - Prob. 10.9.1PECh. 10.5 - Prob. 10.9.2PECh. 10.6 - Prob. 10.10.1PECh. 10.6 - Prob. 10.10.2PECh. 10.6 - Musical instruments like trumpets and trombones...Ch. 10.6 - Consider the two spheres shown here, one made of...Ch. 10.7 - Is the separation method used in brewing a cup of...Ch. 10.7 - Identify each of the following as measurements of...Ch. 10.8 - Three spheres of equal size are composed of...Ch. 10.8 - The three targets from a rifle range shown below...Ch. 10.8 - What is the length of the pencil in the following...Ch. 10.8 - How many significant figures should be reported...Ch. 10.9 - Consider the jar of jelly beans in the photo. To...Ch. 10.9 - The photo below shows a picture of an agate stone....Ch. 10 - SO Two students deterrmne the percen.ge of lead in...Ch. 10 - 1.70
Is Om use of significant figures in ea. of...Ch. 10 - Water has a density of 0.997 g/cm3 at 25C ; ice...Ch. 10 - Prob. 3ECh. 10 - Practice Exercise 1 A biochemist who is studying...Ch. 10 - Practice Exercise 2
Write the empirical formula...Ch. 10 - Prob. 6ECh. 10 - Hydrogen sulfide is composed of two elements:...Ch. 10 - Consider an atom of "B. a. How many protons,...Ch. 10 - 2.34
a. What is the mass in amu of a carbon-12...Ch. 10 - Prob. 10ECh. 10 - You have a graduated cylinder that contains a...Ch. 10 - The density of air at ordinary atmospheric...Ch. 10 - Prob. 13ECh. 10 - Prob. 14ECh. 10 - Prob. 15ECh. 10 - 165 Classify ea. al the folbwing as a pure...Ch. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - Prob. 19ECh. 10 - What type of quantity (for example, length,...Ch. 10 - 1.72 Give the derived SI units for each of the...Ch. 10 - 1.73 The distance from Earth to the Moon is...Ch. 10 - 1.74 Which of the following would you characterize...Ch. 10 -
1.75 The U.S. quarter has a mass of 5.67 g and is...Ch. 10 -
1.76 In the United States, water used for...Ch. 10 -
1.77 By using estimation techniques, determine...Ch. 10 - Suppose you decide to define your own temperature...Ch. 10 -
1.79 The liquid substances mercury (density =...Ch. 10 -
1.80 Two spheres of equal volume are placed on...Ch. 10 - A 32.65-g sample of a solid is placed in a flask....Ch. 10 - A thief plans to steal a gold sphere with a radius...Ch. 10 - Automobile batteries contain sulfuric acid, which...Ch. 10 - A 40-lb container of peat moss measures 14 x 20 x...Ch. 10 - A package of aluminum foil contains 50 ft2of foil,...Ch. 10 - Prob. 35ECh. 10 -
1.88 In 2005, J. Robin Warren and Barry J....Ch. 10 -
1 89 A 25 0-cm.long cylindrical glass tube,...Ch. 10 -
1.90 Gold is alloyed (mixed) with other metals to...Ch. 10 -
1.91 Paper chromatography is a simple but...Ch. 10 -
1.93 You are assigned the task of separating a...Ch. 10 - Prob. 41ECh. 10 - Which of the following factors determines the size...Ch. 10 - Practice Exercise 2 The diameter of a cartoon atom...Ch. 10 - Practice Exercise 1 Which of these atoms has the...Ch. 10 - Practice Exercise 2
How many protons, neutrons,...Ch. 10 - Prob. 46ECh. 10 - Which is mode at 1.00 atm and 298K: CO2,,N2O,or...Ch. 10 - Practice Exercise 1 There are two stable isotopes...Ch. 10 - Practice Exercise 2
Three isotopes of silicon...Ch. 10 - Practice Exercise 2 Locate Na (sodium) and Br...Ch. 10 - Practice Exercise 1 Tetra carbon dioxide is an...Ch. 10 - Practice Exercise 2 Give the empirical formula for...Ch. 10 - Practice Exercise 1 In which of the following...Ch. 10 - Practice Exercise 2 How many protons, neutrons,...Ch. 10 - Practice Exercise 1
Although it is helpful to...Ch. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - Prob. 58ECh. 10 - Prob. 59ECh. 10 - Practice Exercise 1 Which of the follow-mg ox...Ch. 10 - Prob. 61ECh. 10 - Prob. 62ECh. 10 - Prob. 63ECh. 10 - Prob. 64ECh. 10 - Prob. 65ECh. 10 - Prob. 66ECh. 10 - Practice Exercise 2
Give the chemical fomi uias...Ch. 10 - Prob. 68ECh. 10 - Prob. 69ECh. 10 - The followmg diagram is a representation of 20...Ch. 10 - 2 3 Four of the boxes in the following periodic...Ch. 10 -
24 Does the following drawing represent a neutral...Ch. 10 - 2.5 Which of the following diagrams most likely...Ch. 10 - Write the chemical formula for the following...Ch. 10 - Prob. 75ECh. 10 - Prob. 76ECh. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - Prob. 79ECh. 10 - Prob. 80ECh. 10 - Prob. 81ECh. 10 - Prob. 82ECh. 10 - Prob. 83ECh. 10 - Prob. 84ECh. 10 - Explain the difference between effusion and...Ch. 10 - Prob. 86ECh. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Prob. 89ECh. 10 - Prob. 90ECh. 10 - Prob. 91ECh. 10 - Prob. 92ECh. 10 - Prob. 93ECh. 10 - Prob. 94ECh. 10 - In Sample Exercise 10.16, we found that one mole...Ch. 10 - Prob. 96ECh. 10 - Prob. 97ECh. 10 - Prob. 98ECh. 10 - Prob. 99AECh. 10 - Prob. 100AECh. 10 - Prob. 101AECh. 10 - Prob. 102AECh. 10 - Prob. 103AECh. 10 - Prob. 104AECh. 10 - Prob. 105AECh. 10 - Prob. 106AECh. 10 - Prob. 107AECh. 10 - Prob. 108AECh. 10 - Prob. 109AECh. 10 - Prob. 110AECh. 10 - Prob. 111AECh. 10 - Prob. 112AECh. 10 - Prob. 113AECh. 10 - Prob. 114AECh. 10 - Prob. 115AECh. 10 - Prob. 116AECh. 10 - Prob. 117AECh. 10 - Prob. 118AECh. 10 - Prob. 119IECh. 10 - Prob. 120IECh. 10 - Prob. 121IECh. 10 - Prob. 122IECh. 10 - Prob. 123IECh. 10 - Prob. 124IECh. 10 - Chlorine dioxide gas (ClO2) is used as a...Ch. 10 - Natural gas is very abundant us many Middle...Ch. 10 -
[10.127] Gaseous iodine pentafluoride. IF3 can be...Ch. 10 - [10.128]A 6.53-g sample of mixture of magnesium...
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