Solutions Manual For Chemistry: Structure And Properties
2nd Edition
ISBN: 9780134460697
Author: Tro
Publisher: PEARSON
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Chapter 10, Problem 59E
A sample of gas has a mass of 38.8 mg. Its volume is 224 mL at a temperature of 55 0C and a pressure of 886 torr. Find the molar mass of the gas.
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Synthesis of Ibuprofen-Part 2:
1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure
of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how
to make naproxen from the compound below. Show all intermediates and reagents in your synthesis.
Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction
steps would need to change/add?
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Acid Catalyzed Aromatization of Carvone:
1. Starting with the ketone, below, draw a mechanism for the reaction to give the phenol as shown.
H2SO4
HO-
H₂O
2. Why do we use CDCl instead of CHCl, for acquiring our NMR spectra?
3. Why does it not matter which enantiomer of carvone is used for this reaction?
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material?
What other impurities are present in your product and how do you know?
Assign this H NMR
Chapter 10 Solutions
Solutions Manual For Chemistry: Structure And Properties
Ch. 10 - Prob. 1ECh. 10 - Prob. 2ECh. 10 - Prob. 3ECh. 10 - Prob. 4ECh. 10 - Prob. 5ECh. 10 - Prob. 6ECh. 10 - Prob. 7ECh. 10 - Prob. 8ECh. 10 - Prob. 9ECh. 10 - Prob. 10E
Ch. 10 - Prob. 11ECh. 10 - Prob. 12ECh. 10 - Prob. 13ECh. 10 - Prob. 14ECh. 10 - Prob. 15ECh. 10 - Prob. 16ECh. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - Prob. 19ECh. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - If a reaction occurs in the gas phase at STP, the...Ch. 10 - Prob. 24ECh. 10 - Prob. 25ECh. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - A 48.3-mL sample of gas in a cylinder is warmed...Ch. 10 - A syringe containing 1.55 mL of oxygen gas is...Ch. 10 - A balloon contains 0.158 mol of gas and has a...Ch. 10 - Prob. 36ECh. 10 - Prob. 37ECh. 10 - Prob. 38ECh. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - Prob. 44ECh. 10 - Prob. 45ECh. 10 - Prob. 46ECh. 10 - A wine-dispensing system uses argon canisters to...Ch. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Aerosol cans carry clear warnings against...Ch. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Use the molar volume of a gas at STP to calculate...Ch. 10 - What is the density (in g/L) of hydrogen gas at...Ch. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - A 113-mL gas sample has a mass of 0.171 g at a...Ch. 10 - A sample of gas has a mass of 38.8 mg. Its volume...Ch. 10 - Prob. 60ECh. 10 - A gas mixture contains each of these gases at the...Ch. 10 - A gas mixture with a total pressure of 745 mmHg...Ch. 10 - We add a 1.20-g sample of dry ice to a 755-mL...Ch. 10 - A 275-mL flask contains pure helium at a pressure...Ch. 10 - A gas mixture contains 1.25 g N2 and 0.85 g O2 in...Ch. 10 - Prob. 66ECh. 10 - The hydrogen gas formed in a chemical reaction is...Ch. 10 - Prob. 68ECh. 10 - Prob. 69ECh. 10 - Prob. 70ECh. 10 - Prob. 71ECh. 10 - Prob. 72ECh. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - Prob. 75ECh. 10 - Prob. 76ECh. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - Prob. 79ECh. 10 - Prob. 80ECh. 10 - Prob. 81ECh. 10 - Prob. 82ECh. 10 - CH3OH can be synthesized by the reaction:...Ch. 10 - Oxygen gas reacts with powered aluminum according...Ch. 10 - Automobile airbags inflate following serious...Ch. 10 - Lithium reacts with nitrogen gas according to the...Ch. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Prob. 89ECh. 10 - Carbon monoxide gas reacts with hydrogen gas to...Ch. 10 - Prob. 91ECh. 10 - Prob. 92ECh. 10 - Prob. 93ECh. 10 - Use the vander Waals equation and the ideal gas...Ch. 10 - Pennies that are currently being minted are...Ch. 10 - A 2.85 g sample of an unknown chlorofluorocarbon...Ch. 10 - Prob. 97ECh. 10 - A 118 mL flask is evacuated and found to have a...Ch. 10 - Prob. 99ECh. 10 - A gaseous hydrogen- and carbon-containing compound...Ch. 10 - Prob. 101ECh. 10 - Consider the reaction: 2Ag2O(s)4Ag(s)+O2(g) If...Ch. 10 - When hydrochloric acid is poured over potassium...Ch. 10 - Consider the reaction: 2SO2(g)+O2(g)2SO(g)3 If...Ch. 10 - Ammonium carbonate decomposes upon heating...Ch. 10 - Ammonium nitrate decomposes explosively upon...Ch. 10 - Prob. 107ECh. 10 - Prob. 108ECh. 10 - Gaseous ammonia is injected into the exhaust...Ch. 10 - Prob. 110ECh. 10 - Prob. 111ECh. 10 - Prob. 112ECh. 10 - Prob. 113ECh. 10 - Prob. 114ECh. 10 - Prob. 115ECh. 10 - Prob. 116ECh. 10 - Prob. 117ECh. 10 - Prob. 118ECh. 10 - Prob. 119ECh. 10 - Prob. 120ECh. 10 - Prob. 121ECh. 10 - Prob. 122ECh. 10 - Prob. 123ECh. 10 - Prob. 124ECh. 10 - Prob. 125ECh. 10 - Prob. 126ECh. 10 - When 0.583 g of neon is added to an 800-cm3bulb...Ch. 10 - A gas mixture composed of helium and argon has a...Ch. 10 - Prob. 129ECh. 10 - Prob. 130ECh. 10 - Prob. 131ECh. 10 - Prob. 132ECh. 10 - Prob. 133ECh. 10 - Prob. 134ECh. 10 - The atmosphere slowly oxidizes hydrocarbons in a...Ch. 10 - Prob. 136ECh. 10 - Prob. 137ECh. 10 - Prob. 138ECh. 10 - Prob. 139ECh. 10 - Prob. 140ECh. 10 - Prob. 141ECh. 10 - Prob. 142ECh. 10 - Prob. 143ECh. 10 - Which gas would you expect to deviate most from...Ch. 10 - Prob. 145ECh. 10 - Prob. 146ECh. 10 - Prob. 147ECh. 10 - Prob. 148ECh. 10 - Prob. 149ECh. 10 - Prob. 150ECh. 10 - Prob. 151ECh. 10 - Calculate the pressure exerted by 1 mol of an...Ch. 10 - Prob. 153ECh. 10 - Prob. 1SAQCh. 10 - Prob. 2SAQCh. 10 - Prob. 3SAQCh. 10 - Prob. 4SAQCh. 10 - Prob. 5SAQCh. 10 - Prob. 6SAQCh. 10 - Prob. 7SAQCh. 10 - A gas mixture is a 1.55-L container at 298 K...Ch. 10 - Prob. 9SAQCh. 10 - Prob. 10SAQCh. 10 - Prob. 11SAQCh. 10 - Prob. 12SAQCh. 10 - Prob. 13SAQCh. 10 - Prob. 14SAQCh. 10 - Prob. 15SAQ
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