(a) Interpretation: With the help of curved arrows the conversion of structure (a) to (b) should be drawn. Concept Introduction: ?-bond of double bond gets shifted in resonance.

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Answer 1

Question

Chapter 10, Problem 53P

Interpretation Introduction

(a)

Interpretation:

With the help of curved arrows the conversion of structure (a) to (b) should be drawn.

Concept Introduction:

?-bond of double bond gets shifted in resonance.

Interpretation Introduction

(b)

Interpretation:

Comparison of Lewis structure of oxygen between structure (b) and hydroxyl group is to be determined.

Concept Introduction:

In the hydroxide ion there is negative charge or on oxygen atom and there is also negative charge in given structure (b).

Interpretation Introduction

(c)

Interpretation:

Lewis dot structure of ammonium ion and nitrogen in the structure (b) is to be compared.

Concept Introduction:

Nitrogen can donates it lone pair to form coordinate bond.

Interpretation Introduction

(d)

Interpretation:

H-N-H bond angle in structure (a) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Interpretation Introduction

(e)

Interpretation:

Bond angle of H-N-H in structure (b) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Interpretation Introduction

(f)

Interpretation:

Relative importance of the resonance hybrid on the basis of given information is to be written.

Concept Introduction:

Proteins can be described as polyamides. In amide group carbonyl group is attached to −NH₂ group.

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(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):

(c) SOCI Best Lewis Structure 2 e group arrangement: shape/molecular geometry:_ (d) PCls Best Lewis Structure polarity: e group geometry:_ shape/molecular geometry:_ (e) Ba(BrO2): Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

Answer 2

Question

Chapter 10, Problem 53P

Interpretation Introduction

(a)

Interpretation:

With the help of curved arrows the conversion of structure (a) to (b) should be drawn.

Concept Introduction:

?-bond of double bond gets shifted in resonance.

Interpretation Introduction

(b)

Interpretation:

Comparison of Lewis structure of oxygen between structure (b) and hydroxyl group is to be determined.

Concept Introduction:

In the hydroxide ion there is negative charge or on oxygen atom and there is also negative charge in given structure (b).

Interpretation Introduction

(c)

Interpretation:

Lewis dot structure of ammonium ion and nitrogen in the structure (b) is to be compared.

Concept Introduction:

Nitrogen can donates it lone pair to form coordinate bond.

Interpretation Introduction

(d)

Interpretation:

H-N-H bond angle in structure (a) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Interpretation Introduction

(e)

Interpretation:

Bond angle of H-N-H in structure (b) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Interpretation Introduction

(f)

Interpretation:

Relative importance of the resonance hybrid on the basis of given information is to be written.

Concept Introduction:

Proteins can be described as polyamides. In amide group carbonyl group is attached to −NH₂ group.

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Answer 3

Question

Chapter 10, Problem 53P

Interpretation Introduction

(a)

Interpretation:

With the help of curved arrows the conversion of structure (a) to (b) should be drawn.

Concept Introduction:

?-bond of double bond gets shifted in resonance.

Interpretation Introduction

(b)

Interpretation:

Comparison of Lewis structure of oxygen between structure (b) and hydroxyl group is to be determined.

Concept Introduction:

In the hydroxide ion there is negative charge or on oxygen atom and there is also negative charge in given structure (b).

Interpretation Introduction

(c)

Interpretation:

Lewis dot structure of ammonium ion and nitrogen in the structure (b) is to be compared.

Concept Introduction:

Nitrogen can donates it lone pair to form coordinate bond.

Interpretation Introduction

(d)

Interpretation:

H-N-H bond angle in structure (a) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Interpretation Introduction

(e)

Interpretation:

Bond angle of H-N-H in structure (b) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Interpretation Introduction

(f)

Interpretation:

Relative importance of the resonance hybrid on the basis of given information is to be written.

Concept Introduction:

Proteins can be described as polyamides. In amide group carbonyl group is attached to −NH₂ group.

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Answer 4

Question

Chapter 10, Problem 53P

Interpretation Introduction

(a)

Interpretation:

With the help of curved arrows the conversion of structure (a) to (b) should be drawn.

Concept Introduction:

?-bond of double bond gets shifted in resonance.

Interpretation Introduction

(b)

Interpretation:

Comparison of Lewis structure of oxygen between structure (b) and hydroxyl group is to be determined.

Concept Introduction:

In the hydroxide ion there is negative charge or on oxygen atom and there is also negative charge in given structure (b).

Interpretation Introduction

(c)

Interpretation:

Lewis dot structure of ammonium ion and nitrogen in the structure (b) is to be compared.

Concept Introduction:

Nitrogen can donates it lone pair to form coordinate bond.

Interpretation Introduction

(d)

Interpretation:

H-N-H bond angle in structure (a) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Interpretation Introduction

(e)

Interpretation:

Bond angle of H-N-H in structure (b) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Interpretation Introduction

(f)

Interpretation:

Relative importance of the resonance hybrid on the basis of given information is to be written.

Concept Introduction:

Proteins can be described as polyamides. In amide group carbonyl group is attached to −NH₂ group.

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Answer 5

Chapter 10, Problem 53P

Interpretation Introduction

(a)

Interpretation:

With the help of curved arrows the conversion of structure (a) to (b) should be drawn.

Concept Introduction:

?-bond of double bond gets shifted in resonance.

Interpretation Introduction

(b)

Interpretation:

Comparison of Lewis structure of oxygen between structure (b) and hydroxyl group is to be determined.

Concept Introduction:

In the hydroxide ion there is negative charge or on oxygen atom and there is also negative charge in given structure (b).

Interpretation Introduction

(c)

Interpretation:

Lewis dot structure of ammonium ion and nitrogen in the structure (b) is to be compared.

Concept Introduction:

Nitrogen can donates it lone pair to form coordinate bond.

Interpretation Introduction

(d)

Interpretation:

H-N-H bond angle in structure (a) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Interpretation Introduction

(e)

Interpretation:

Bond angle of H-N-H in structure (b) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Interpretation Introduction

(f)

Interpretation:

Relative importance of the resonance hybrid on the basis of given information is to be written.

Concept Introduction:

Proteins can be described as polyamides. In amide group carbonyl group is attached to −NH₂ group.

Answer 6

Chapter 10, Problem 53P

Interpretation Introduction

(a)

Interpretation:

With the help of curved arrows the conversion of structure (a) to (b) should be drawn.

Concept Introduction:

?-bond of double bond gets shifted in resonance.

Answer 7

Chapter 10, Problem 53P

Interpretation Introduction

(a)

Interpretation:

With the help of curved arrows the conversion of structure (a) to (b) should be drawn.

Concept Introduction:

?-bond of double bond gets shifted in resonance.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Comparison of Lewis structure of oxygen between structure (b) and hydroxyl group is to be determined.

Concept Introduction:

In the hydroxide ion there is negative charge or on oxygen atom and there is also negative charge in given structure (b).

Answer 9

Interpretation Introduction

(b)

Interpretation:

Comparison of Lewis structure of oxygen between structure (b) and hydroxyl group is to be determined.

Concept Introduction:

In the hydroxide ion there is negative charge or on oxygen atom and there is also negative charge in given structure (b).

Answer 10

Interpretation Introduction

(c)

Interpretation:

Lewis dot structure of ammonium ion and nitrogen in the structure (b) is to be compared.

Concept Introduction:

Nitrogen can donates it lone pair to form coordinate bond.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Lewis dot structure of ammonium ion and nitrogen in the structure (b) is to be compared.

Concept Introduction:

Nitrogen can donates it lone pair to form coordinate bond.

Answer 12

Interpretation Introduction

(d)

Interpretation:

H-N-H bond angle in structure (a) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Answer 13

Interpretation Introduction

(d)

Interpretation:

H-N-H bond angle in structure (a) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Answer 14

Interpretation Introduction

(e)

Interpretation:

Bond angle of H-N-H in structure (b) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Answer 15

Interpretation Introduction

(e)

Interpretation:

Bond angle of H-N-H in structure (b) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

Answer 16

Interpretation Introduction

(f)

Interpretation:

Relative importance of the resonance hybrid on the basis of given information is to be written.

Concept Introduction:

Proteins can be described as polyamides. In amide group carbonyl group is attached to −NH₂ group.

Answer 17

Interpretation Introduction

(f)

Interpretation:

Relative importance of the resonance hybrid on the basis of given information is to be written.

Concept Introduction:

Proteins can be described as polyamides. In amide group carbonyl group is attached to −NH₂ group.

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 10.3 - Prob. 10.1QC Ch. 10.4 - Prob. 10.2QC Ch. 10.4 - Prob. 10.3QC Ch. 10.4 - Prob. 10.4QC Ch. 10.4 - Prob. 10.5QC Ch. 10.4 - Prob. 10.6QC Ch. 10 - Prob. 1P Ch. 10 - Prob. 2P Ch. 10 - 10-9 Is there any difference between vanillin made...Ch. 10 - Prob. 4P

(a) Interpretation: With the help of curved arrows the conversion of structure (a) to (b) should be drawn. Concept Introduction: ?-bond of double bond gets shifted in resonance.

(a) Interpretation: With the help of curved arrows the conversion of structure (a) to (b) should be drawn. Concept Introduction: ?-bond of double bond gets shifted in resonance.

(b) Interpretation: Comparison of Lewis structure of oxygen between structure (b) and hydroxyl group is to be determined. Concept Introduction: In the hydroxide ion there is negative charge or on oxygen atom and there is also negative charge in given structure (b).

(c) Interpretation: Lewis dot structure of ammonium ion and nitrogen in the structure (b) is to be compared. Concept Introduction: Nitrogen can donates it lone pair to form coordinate bond.

(d) Interpretation: H-N-H bond angle in structure (a) is to be determined. Concept Introduction: In amide group carbonyl group is attached to −NH2 group.

(e) Interpretation: Bond angle of H-N-H in structure (b) is to be determined. Concept Introduction: In amide group carbonyl group is attached to −NH2 group.

(f) Interpretation: Relative importance of the resonance hybrid on the basis of given information is to be written. Concept Introduction: Proteins can be described as polyamides. In amide group carbonyl group is attached to −NH2 group.

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Chapter 10 Solutions

(a)

Interpretation:

With the help of curved arrows the conversion of structure (a) to (b) should be drawn.

Concept Introduction:

?-bond of double bond gets shifted in resonance.

(b)

Interpretation:

Comparison of Lewis structure of oxygen between structure (b) and hydroxyl group is to be determined.

Concept Introduction:

In the hydroxide ion there is negative charge or on oxygen atom and there is also negative charge in given structure (b).

(c)

Interpretation:

Lewis dot structure of ammonium ion and nitrogen in the structure (b) is to be compared.

Concept Introduction:

Nitrogen can donates it lone pair to form coordinate bond.

(d)

Interpretation:

H-N-H bond angle in structure (a) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

(e)

Interpretation:

Bond angle of H-N-H in structure (b) is to be determined.

Concept Introduction:

In amide group carbonyl group is attached to −NH₂ group.

(f)

Interpretation:

Relative importance of the resonance hybrid on the basis of given information is to be written.

Concept Introduction:

Proteins can be described as polyamides. In amide group carbonyl group is attached to −NH₂ group.