EBK INTRODUCTORY CHEMISTRY
8th Edition
ISBN: 8220100480485
Author: DECOSTE
Publisher: CENGAGE L
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Chapter 10, Problem 4QAP
Interpretation Introduction
Interpretation:
To determine the given statement and fill in the correct answer in the given blank.
Concept Introduction:
The law of
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2. (3 pts) Consider the unit cell for the spinel compound,
CrFe204. How many total particles are in the unit cell?
Also, show how the number of particles and their
positions are consistent with the CrFe204
stoichiometry - this may or may not be reflected by the
particle colors in the diagram. (HINT: In the diagram,
the blue particle is in an interior position while each red
particle is either in a corner or face position.)
From the following potentials, calculate the activity of Cl- in saturated KCl.
E0 (calomel electrode)= 0.268 V
E (calomel electrode, saturated KCl)= 0.241 V
Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
AgCl(s) + e- = Ag(s) + Cl- E0= 0.222 V
2H+ + 2e- = H2 E0= 0.000 V
Chapter 10 Solutions
EBK INTRODUCTORY CHEMISTRY
Ch. 10.1 - at if energy were not conserved? How would this...Ch. 10.4 - u are calculating in a chemistry problem. What if...Ch. 10.5 - ercise 10.1 How many calories of energy correspond...Ch. 10.5 - ercise 10.2 Calculate the joules of energy...Ch. 10.5 - ercise 10.3 A 5.63-g sample of solid gold is...Ch. 10.5 - ercise 10.4 A 2.8-g sample of pure metal requires...Ch. 10.6 - Prob. 10.5SCCh. 10.7 - at if Hess’s law were not true? What are some...Ch. 10.7 - Prob. 10.6SCCh. 10.9 - Prob. 1CT
Ch. 10.10 - at if the first law of thermodynamics was true,...Ch. 10 - Prob. 1ALQCh. 10 - friend of yours reads that the process of water...Ch. 10 - ou place hot metal into a beaker of cold water. ol...Ch. 10 - Prob. 4ALQCh. 10 - Prob. 5ALQCh. 10 - xplain why aluminum cans make good storage...Ch. 10 - n Section 10.7, two characteristics of enthalpy...Ch. 10 - Prob. 8ALQCh. 10 - hat is meant by the term driving forces? Why are...Ch. 10 - Prob. 10ALQCh. 10 - Explain in your own words what is meant by the...Ch. 10 - Prob. 12ALQCh. 10 - What if energy was not conserved? How would this...Ch. 10 - The internal energy of a system is said to be the...Ch. 10 - Hydrogen gas and oxygen gas react violently to...Ch. 10 - Consider four 100.0-g samples of water, each in a...Ch. 10 - For each of the following situations ac. use the...Ch. 10 - Prob. 18ALQCh. 10 - Does the entropy of the system increase or...Ch. 10 - Prob. 20ALQCh. 10 - Prob. 1QAPCh. 10 - Prob. 2QAPCh. 10 - Prob. 3QAPCh. 10 - Prob. 4QAPCh. 10 - Prob. 5QAPCh. 10 - n Fig. 10.1, what kind of energy does ball A...Ch. 10 - Prob. 7QAPCh. 10 - f you spilled a cup of freshly brewed hot tea on...Ch. 10 - Prob. 9QAPCh. 10 - Prob. 10QAPCh. 10 - In studying heat flows for chemical processes,...Ch. 10 - When a chemical system evolves energy, where does...Ch. 10 - The combustion of methane, is an exothermic...Ch. 10 - Are the following processes exothermic or...Ch. 10 - What do we mean by thermodynamics? What is the...Ch. 10 - Prob. 16QAPCh. 10 - Calculate A£ for each of the following cases q =...Ch. 10 - If q for a process is a positive number, then the...Ch. 10 - For an endothermic process, q will have a...Ch. 10 - A system releases 125 kJ of heat and 104 kJ of...Ch. 10 - Prob. 21QAPCh. 10 - Prob. 22QAPCh. 10 - If 8.40 kJ of heat is needed to raise the...Ch. 10 - If it takes 654 J of energy to warm a 5.51-g...Ch. 10 - Prob. 25QAPCh. 10 - Prob. 26QAPCh. 10 - Covert the following numbers of kilojoules into...Ch. 10 - Prob. 28QAPCh. 10 - Prob. 29QAPCh. 10 - Prob. 30QAPCh. 10 - .5 kJ of heat is applied to a 1012-g block of...Ch. 10 - What quantity of heat energy must have en applied...Ch. 10 - If 125 J of heat energy is applied to a block of...Ch. 10 - If 100. J of heat energy is applied to a 25-g...Ch. 10 - What quantity of heat is required to raise the...Ch. 10 - Prob. 36QAPCh. 10 - The “Chemistry in Focus” segment Nature Has Hot...Ch. 10 - In the “Chemistry in Focus” segment Firewalking:...Ch. 10 - Prob. 39QAPCh. 10 - A _________ is a device used to determine the heat...Ch. 10 - The enthalpy change for the reaction of hydrogen...Ch. 10 - For the reaction kJ per mole of formed. Calculate...Ch. 10 - Prob. 43QAPCh. 10 - When ethanol (grain alcohol, is burned in oxygen,...Ch. 10 - Prob. 45QAPCh. 10 - Prob. 46QAPCh. 10 - Prob. 47QAPCh. 10 - Prob. 48QAPCh. 10 - Prob. 49QAPCh. 10 - Prob. 50QAPCh. 10 - Prob. 51QAPCh. 10 - Prob. 52QAPCh. 10 - Prob. 53QAPCh. 10 - Prob. 54QAPCh. 10 - Prob. 55QAPCh. 10 - Prob. 56QAPCh. 10 - Prob. 57QAPCh. 10 - Prob. 58QAPCh. 10 - Prob. 59QAPCh. 10 - Prob. 60QAPCh. 10 - If a reaction occurs readily but has an...Ch. 10 - Prob. 62QAPCh. 10 - Prob. 63QAPCh. 10 - Prob. 64QAPCh. 10 - Prob. 65APCh. 10 - Calculate the enthalpy change when 1.0(1 g of...Ch. 10 - Prob. 67APCh. 10 - Calculate the amount of energy required (in...Ch. 10 - If takes 1.25 kJ of energy to heat a certain...Ch. 10 - What quantity of heat energy would have to be...Ch. 10 - The specific heat capacity of gold is 0.13 J/g °C....Ch. 10 - Calculate the amount of energy required (in...Ch. 10 - If 10. J of heat is applied to 5.0-g samples of...Ch. 10 - A 50.1)-g sample of water at 100. °C is poured...Ch. 10 - A 25.0-g sample of pure iron at 85 °C is dropped...Ch. 10 - If 7.24 kJ of heat is applied to a 952-g block of...Ch. 10 - For each of the substances listed in Table 10.1,...Ch. 10 - A system releases 213 kJ of heat and has a...Ch. 10 - Prob. 79APCh. 10 - Calculate the enthalpy change when 5.00 g of...Ch. 10 - Prob. 81APCh. 10 - Prob. 82APCh. 10 - It has been determined that the body can generate...Ch. 10 - Prob. 84APCh. 10 - Prob. 85CPCh. 10 - The specific heat capacity of graphite is 0.71 J/g...Ch. 10 - A swimming pool, 10.0 in by 4.0 m, is filled with...Ch. 10 - Prob. 88CPCh. 10 - Prob. 89CP
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- A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol). a) Write a balanced net reaction that can occur between species in this solution. b) Calculate deltaG0 and K for the reaction. c) Calculate E and deltaG for the conditions given. Ce4+ + e- = Ce3+ E0= 1.70 V MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 Varrow_forward1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in the following reaction. Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is a weak base used to neutralize strong acid (pKa < 0) produced by the reaction. Redraw the product to show the configuration(s) that form at C-2 and C-4. Br2 OH CH2Cl2 Na* HCO3 Br HO OH + Na Br +arrow_forward2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); H₂O2/HO (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI + enant OH Solvent Reagent(s) Solvent Reagent(s)arrow_forward
- Germanium (Ge) is a semiconductor with a bandgap of 2.2 eV. How could you dope Ge to make it a p-type semiconductor with a larger bandgap? Group of answer choices It is impossible to dope Ge and have this result in a larger bandgap. Dope the Ge with silicon (Si) Dope the Ge with gallium (Ga) Dope the Ge with phosphorus (P)arrow_forwardWhich of the following semiconductors would you choose to have photons with the longest possible wavelengths be able to promote electrons to the semiconductor's conduction band? Group of answer choices Si Ge InSb CdSarrow_forwardWhich of the following metals is the only one with all of its bands completely full? Group of answer choices K Na Ca Alarrow_forward
- 2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); Reagents: H₂O (B); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI OH - α-α Br + enant Solvent Reagent(s) Solvent Reagent(s)arrow_forwardBased on concepts from Lecture 3-5, which of the following ionic compounds should be most soluble in water? Group of answer choices MgO BeO CaO BaOarrow_forwardFrom an energy standpoint, which two process - in the correct order - are involved in the dissolving of an ionic compound crystal? Group of answer choices Water coordination to the ions followed by sublimation into the gas phase Sublimation of the crystal into gas-phase ions followed by water coordination to the ions Ion dissociation from the crystal followed by water coordination to the ions Water coordination to the ions followed by ion dissociation from the crystalarrow_forward
- For which Group 2 metal (M), is this process the most exothermic? M2+(g) + O2−(g) + CO2(g) → MO(s) + CO2(g) Group of answer choices M = Sr M = Mg M = Ca M = Baarrow_forward2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); R₂BH (6); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI Solvent Reagent(s) Solvent Reagent(s) HO OHarrow_forwardFor which of the following ionic compounds would you expect the smallest difference between its theoretical and experimental lattice enthalpies? (You may assume these all have the same unit cell structure.) Electronegativities: Ca (1.0), Fe (1.8), Mg (1.2), O (3.5), S (2.5), Zn (1.6) Group of answer choices ZnO MgS CaO FeSarrow_forward
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