Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 10, Problem 47E
Rationalize the trend in water solubility for the following simple alcohols:
Alcohol | Solubility (g/100 g H2O at 20°C) |
Methanol, CH3OH | Soluble in all proportions |
Ethanol, CH3CH2OH | Soluble in all proportions |
Propanol, CH3CH2CH2OH | Soluble in all proportions |
Butanol, CH3(CH2)2CH2OH | 8.14 |
Pentanol. CH3(CH2)3CH2OH | 2.64 |
Hexanol, CH3(CH2)4CH2OH | 0.59 |
Heptanol, CH3(CH2)5CH2OH | 0.09 |
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Osmotic pressure may be used to determine the molecular weight of pure substances. It is an especially useful technique because low concentrations of solute produce
relatively large osmotic pressures. Although more sophisticated techniques are
now available to determine molecular weight, osmotic pressure is still used
occasionally because of its simplicity. Determine the molecular weight of
myoglobin (an oxygen storage protein that gives muscle its red color). The
osmotic pressure of a 1.0-mL water solution containing 1.5 x 10
~3 g of the protein
was measured at 2.06 x 10
~3 atm at 25°C.
Toluene, C6H5CH3, is a liquid compound similar to Benzene, C6H6. It is the starting material for other substances, including Trinitrotoluene.
Find the molality of Toluene in a solution that contains 35.6g of Toluene in 125g of Benzene.
Part 2: (+)-Carvone (C10H14O) is a principal component of caraway and dill seed and is used as a food flavoring agent.Calculate the molality of a solution that contains 1.73 g carvone in 13.4 mL of ethanol (density 0.7893 g/mL). Assume that carvone is nonvolatile at the normal boiling point of ethanol and that it is a nonelectrolyte.Molality = ...................... m
Chapter 10 Solutions
Chemistry: An Atoms First Approach
Ch. 10 - Prob. 1RQCh. 10 - Using KF as an example, write equations that refer...Ch. 10 - Prob. 3RQCh. 10 - Prob. 4RQCh. 10 - Define the terms in Raoults law. Figure 10-9...Ch. 10 - In terms of Raoults law, distinguish between an...Ch. 10 - Prob. 7RQCh. 10 - Prob. 8RQCh. 10 - Prob. 9RQCh. 10 - Prob. 10RQ
Ch. 10 - Prob. 1ALQCh. 10 - Prob. 2ALQCh. 10 - Prob. 3ALQCh. 10 - Prob. 4ALQCh. 10 - You have read that adding a solute to a solvent...Ch. 10 - Prob. 6ALQCh. 10 - Prob. 7ALQCh. 10 - Prob. 8ALQCh. 10 - Prob. 9ALQCh. 10 - Prob. 10ALQCh. 10 - Rubbing alcohol contains 585 g isopropanol...Ch. 10 - Prob. 12SRCh. 10 - Prob. 13SRCh. 10 - Prob. 14SRCh. 10 - Calculate the sodium ion concentration when 70.0...Ch. 10 - Write equations showing the ions present after the...Ch. 10 - Prob. 17QCh. 10 - The weak electrolyte NH3(g) does not obey Henrys...Ch. 10 - The two beakers in the sealed container...Ch. 10 - The following plot shows the vapor pressure of...Ch. 10 - Prob. 21QCh. 10 - Prob. 22QCh. 10 - Prob. 23QCh. 10 - Prob. 24QCh. 10 - Prob. 25QCh. 10 - Prob. 26QCh. 10 - Explain the terms isotonic solution, crenation,...Ch. 10 - Prob. 28QCh. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Common commercial acids and bases are aqueous...Ch. 10 - In lab you need to prepare at least 100 mL of each...Ch. 10 - Prob. 33ECh. 10 - Prob. 34ECh. 10 - Prob. 35ECh. 10 - Calculate the molarity and mole fraction of...Ch. 10 - Prob. 37ECh. 10 - Prob. 38ECh. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Although Al(OH)3 is insoluble in water, NaOH is...Ch. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - Prob. 44ECh. 10 - Prob. 45ECh. 10 - Which ion in each of the following pairs would you...Ch. 10 - Rationalize the trend in water solubility for the...Ch. 10 - Prob. 48ECh. 10 - The solubility of nitrogen in water is 8.21 104...Ch. 10 - Calculate the solubility of O2 in water at a...Ch. 10 - Glycerin, C3H8O3, is a nonvolatile liquid. What is...Ch. 10 - Prob. 52ECh. 10 - The normal boiling point of diethyl ether is...Ch. 10 - At a certain temperature, the vapor pressure of...Ch. 10 - A solution is made by dissolving 25.8 g urea...Ch. 10 - A solution of sodium chloride in water has a vapor...Ch. 10 - Prob. 57ECh. 10 - A solution is prepared by mixing 0.0300 mole of...Ch. 10 - What is the composition of a methanol...Ch. 10 - Benzene and toluene form an ideal solution....Ch. 10 - Which of the following will have the lowest total...Ch. 10 - Prob. 62ECh. 10 - Match the vapor pressure diagrams with the...Ch. 10 - The vapor pressures of several solutions of...Ch. 10 - A solution is prepared by dissolving 27.0 g urea,...Ch. 10 - A 2.00-g sample of a large biomolecule was...Ch. 10 - What mass of glycerin (C3H8O3), a nonelectrolyte,...Ch. 10 - The freezing point of 1-butanol is 25.50C and Kf...Ch. 10 - Prob. 69ECh. 10 - What volume of ethylene glycol (C2H6O2), a...Ch. 10 - Reserpine is a natural product isolated from the...Ch. 10 - A solution contains 3.75 g of a nonvolatile pure...Ch. 10 - a. Calculate the freezing-point depression and...Ch. 10 - Erythrocytes are red blood cells containing...Ch. 10 - Prob. 75ECh. 10 - Prob. 76ECh. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - Consider the following solutions: 0.010 m Na3PO4...Ch. 10 - From the following: pure water solution of...Ch. 10 - Prob. 81ECh. 10 - Prob. 82ECh. 10 - Prob. 83ECh. 10 - Consider the following representations of an ionic...Ch. 10 - Prob. 85ECh. 10 - Prob. 86ECh. 10 - Use the following data for three aqueous solutions...Ch. 10 - The freezing-point depression of a 0.091-m...Ch. 10 - Prob. 89ECh. 10 - A 0.500-g sample of a compound is dissolved in...Ch. 10 - The solubility of benzoic acid (HC7H5O2), is 0.34...Ch. 10 - Prob. 92AECh. 10 - Prob. 94AECh. 10 - Explain the following on the basis of the behavior...Ch. 10 - Prob. 96AECh. 10 - Prob. 97AECh. 10 - Prob. 98AECh. 10 - A solution is made by mixing 50.0 g acetone...Ch. 10 - Prob. 100AECh. 10 - Prob. 101AECh. 10 - Prob. 102AECh. 10 - An unknown compound contains only carbon,...Ch. 10 - Prob. 104AECh. 10 - Prob. 105AECh. 10 - Prob. 106AECh. 10 - Prob. 107AECh. 10 - Prob. 108AECh. 10 - Patients undergoing an upper gastrointestinal...Ch. 10 - Prob. 110CWPCh. 10 - Prob. 111CWPCh. 10 - For each of the following pairs, predict which...Ch. 10 - The normal boiling point of methanol is 64.7C. A...Ch. 10 - A solution is prepared by mixing 1.000 mole of...Ch. 10 - Prob. 115CWPCh. 10 - A 4.7 102 mg sample of a protein is dissolved in...Ch. 10 - Prob. 117CWPCh. 10 - The vapor pressure of pure benzene is 750.0 torr...Ch. 10 - Prob. 119CPCh. 10 - Plants that thrive in salt water must have...Ch. 10 - You make 20.0 g of a sucrose (C12H22O11) and NaCl...Ch. 10 - Prob. 122CPCh. 10 - The vapor in equilibrium with a pentane-hexane...Ch. 10 - Prob. 124CPCh. 10 - Prob. 125CPCh. 10 - Prob. 126CPCh. 10 - Prob. 127CPCh. 10 - You have a solution of two volatile liquids, A and...Ch. 10 - In some regions of the southwest United States,...Ch. 10 - Prob. 130IPCh. 10 - An aqueous solution containing 0.250 mole of Q, a...Ch. 10 - Anthraquinone contains only carbon, hydrogen, and...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Predict the relative solubility of each compound in the two solvents, on the basis of intermolecular attractions. (a) Is NaCl more soluble in water or in carbon tetrachloride? (b) Is I2 more soluble in water or in toluene (C6H5CH3)? (c) Is ethanol (C2H5OH) more soluble in hexane or in water? (d) Is ethylene glycol (HOCH2CH2OH) more soluble in ethanol or in benzene (C6H6)?arrow_forwardPredict the relative solubility of each compound in the two solvents, on the basis of intermolecular attractions. (a) Is Br2 more soluble in water or in carbon tetrachloride? (b) Is CaCl2 more soluble in water or in benzene (C6H6)? (c) Is chloroform (CHCl3) more soluble in water or in diethyl ether [(C2H5)2O]? (d) Is ethylene glycol (HOCH2CH2OH) more soluble in water or in benzene (C6H6)?arrow_forwardRationalize the trend in water solubility for the following simple alcohols: Alcohol Solubility (g/100 g H2O at 20C) Methanol, CH3OH Soluble in all proportions Ethanol, CH3CH2OH Soluble in all proportions Propanol, CH3CH2CH2OH Soluble in all proportions Butanol, CH3(CH2)2CH2OH 8.14 Pentanol. CH3(CH2)3CH2OH 2.64 Hexanol, CH3(CH2)4CH2OH 0.59 Heptanol, CH3(CH2)5CH2OH 0.09arrow_forward
- How could the data in Table 13.2 be used to predict the solubility in water of 1-octanol or 1-decanol? Table 13.2 Solubilities of Alcohols in Water, 20°Carrow_forwardStarch contains CC, CH, CO, and OH bonds. Hydrocarbons have only CC and CH bonds. Both starch and hydrocarbons can form colloidal dispersions in water. Which dispersion is classified as hydrophobic? Which is hydrophilic? Explain briefly.arrow_forwardA gaseous solute dissolves in water. The solution process has H=15 kJ. Its solubility at 22C and 6.00 atm is 0.0300 M. Would you expect the solubility to be greater or less at (a) 22C and 1 atm? (a) 18C and 6 atm? (a) 15C and 10 atm? (a) 35C and 3 atm?arrow_forward
- Acetone, CH3COCH3, is quite soluble in water. Explain why this should be so.arrow_forwarda. Use the following data to calculate the enthalpy of hydration for calcium chloride and calcium iodide. Lattice Energy Hsoln CaCl2(s) 2247kj/mol 46kj/mol Cal2(s) 2059kj/mol 104kj/mol b. Based on your answers to part a, which ion, Cl or I, is more strongly attracted to water?arrow_forwardIn a police forensics lab, you examine a package that may contain heroin. However, you find the white powder is not pure heroin but a mixture of heroin (C12H23O5N) and lactose (C12H22O11). To determine the amount of heroin in the mixture, you dissolve 1.00 g of the white powdery mixture in water in a 100.0-mL volumetric flask. You find that the solution has an osmotic pressure of 539 mm Hg at 25 C. What is the composition of the mixture?arrow_forward
- A forensic chemist is given a white solid that is suspected of being pure cocaine (C17H21NO4, molar mass = 303.35 g/mol). She dissolves 1.22 0.01 g of the solid in 15.60 0.01 g benzene. The freezing point is lowered by 1.32 0.04C. a. What is the molar mass of the substance? Assuming that the percent uncertainty in the calculated molar mass is the same as the percent uncertainty in the temperature change, calculate the uncertainty in the molar mass. b. Could the chemist unequivocally state that the substance is cocaine? For example, is the uncertainty small enough to distinguish cocaine from codeine (C18H21NO3, molar mass = 299.36 g/mol)? c. Assuming that the absolute uncertainties in the measurements of temperature and mass remain unchanged, how could the chemist improve the precision of her results?arrow_forwardA natural gas mixture consists of 88.0 mole percent CH4 (methane) and 12.0 mole percent C2 H6 (ethane). Suppose water is saturated with the gas mixture at 20C and 1.00 atm total pressure, and the gas is then expelled from the water by heating. What is the composition in mole fractions of the gas mixture that is expelled? The solubilities of CH4 and C2 H6 at 20C and 1.00 atm are 0.023 g/L H2O and 0.059 g/L H2O, respectively.arrow_forwardIndicate which of the following is more soluble in ethanol, C2H5OH: acetic acid, CH3COOH, or stearic acid, C17H35COOH.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY