ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
12th Edition
ISBN: 9781119304241
Author: Solomons
Publisher: WILEY C
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Chapter 10, Problem 34P
Interpretation Introduction

Interpretation:

The products of the given reaction including the sequence of steps are to be determined.

Concept introduction:

▸ Dehydrogenation is a reaction in which the hydrogens are removed from an organic molecule using various reagents. It is the reverse of hydrogenation.

▸ The hydroboration-oxidation reaction is a two-step organic reaction that converts an alkene, an unsaturated hydrocarbon into alcohol via the addition of water across the double bond. The hydrogen and hydroxyl group are attached in syn addition that leads to cis stereochemistry.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
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