ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
12th Edition
ISBN: 9781119304241
Author: Solomons
Publisher: WILEY C
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Chapter 10, Problem 16PP
Interpretation Introduction

Interpretation:

The method of synthesis for the given polymers is to be outlined, and the monomers used for the polymerization reaction are to be determined.

Concept introduction:

An outline of the synthesisof polymersusing radical polymerization is as follows:

An alkyl radical is produced that initiates the radical reaction with the monomer. The monomer is repeatedly bonded with the radical chain to form a large molecule. When all the monomers are consumed ortwo radical chains react with each other to terminate the polymerization, the termination ends via combination where two radical chains react with each other to form a big chain, or via disproportionation, where a hydrogen molecule is split into 2 radicals, and each radical chain reacts with a hydrogen radical to form 2 different chains.

Monomers are the small, repetitive building blocks that are bonded together to form a large molecule.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
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