
Bundle: Chemistry, 9th, Loose-Leaf + OWLv2 24-Months Printed Access Card
9th Edition
ISBN: 9781305367760
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
Chapter 10, Problem 14Q
Interpretation Introduction
Interpretation:
- The atoms other than hydrogen that are necessary for the formation of hydrogen bond should be mentioned.
- The role of hydrogen on the can contribution to the strength of dipole-dipole forces should be discussed.
Concept introduction:
- Dipole-dipole interactions are the intermolecular forces exist in polar molecules. These interactions do operate and have significance only if the molecules do exist nearby with each other. It does readily become weak if the molecules move apart. So this interaction cannot always be permanent.
- Hydrogen bonding can be termed as a kind of polar covalent formed between hydrogen and high electronegative atoms like N, O, and F when both these atoms are present in the same compound.
- The dipole-dipole interactions are stronger in hydrogen bond due to the high polar nature of the bond. As a result hydrogen bonds are not as weak as usual dipole-dipole interactions. Hence they are special type of dipole-dipole forces.
Expert Solution & Answer

Trending nowThis is a popular solution!

Students have asked these similar questions
Draw the Fischer projection of D-fructose.
Click and drag to start drawing a
structure.
Skip Part
Check
AP
14
tv
SC
F1
F2
80
F3
a
F4
!
2
#
3
CF
F5
75
Ax
MacBook Air
894
$
5olo
%
Λ
6 >
W
F6
K
F7
&
Consider this step in a radical reaction:
Y
What type of step is this? Check all that apply.
Draw the products of the step on the right-hand side of the drawing area
below. If more than one set of products is possible, draw any set.
Also, draw the mechanism arrows on the left-hand side of the drawing
area to show how this happens.
ionization
propagation
initialization
passivation
none of the above
22.16 The following groups are ortho-para directors.
(a)
-C=CH₂
H
(d)
-Br
(b)
-NH2
(c)
-OCHS
Draw a contributing structure for the resonance-stabilized cation formed during elec-
trophilic aromatic substitution that shows the role of each group in stabilizing the
intermediate by further delocalizing its positive charge.
22.17 Predict the major product or products from treatment of each compound with
Cl₁/FeCl₂-
OH
(b)
NO2
CHO
22.18 How do you account for the fact that phenyl acetate is less reactive toward electro-
philic aromatic substitution than anisole?
Phenyl acetate
Anisole
CH
(d)
Chapter 10 Solutions
Bundle: Chemistry, 9th, Loose-Leaf + OWLv2 24-Months Printed Access Card
Ch. 10 - What are intermolecular forces? How do they differ...Ch. 10 - Define the following terms and describe how each...Ch. 10 - Compare and contrast solids, liquids, and gases.Ch. 10 - Prob. 4RQCh. 10 - What is a lattice? What is a unit cell? Describe a...Ch. 10 - What is closest packing? What is the difference...Ch. 10 - Describe, in general, the structures of ionic...Ch. 10 - Prob. 9RQCh. 10 - Prob. 10RQCh. 10 - Compare and contrast the phase diagrams of water...
Ch. 10 - It is possible to balance a paper clip on the...Ch. 10 - Consider a sealed container half-filled with...Ch. 10 - Explain the following: You add 100 mL water to a...Ch. 10 - Prob. 4ALQCh. 10 - Prob. 5ALQCh. 10 - Why do liquids have a vapor pressure? Do all...Ch. 10 - Prob. 7ALQCh. 10 - What is the vapor pressure of water at 100C? How...Ch. 10 - Prob. 9ALQCh. 10 - Prob. 10ALQCh. 10 - Prob. 11ALQCh. 10 - In the diagram below, which lines represent the...Ch. 10 - Prob. 14QCh. 10 - Atoms are assumed to touch in closest packed...Ch. 10 - Define critical temperature and critical pressure....Ch. 10 - Use the kinetic molecular theory to explain why a...Ch. 10 - Prob. 18QCh. 10 - Prob. 19QCh. 10 - Describe what is meant by a dynamic equilibrium in...Ch. 10 - Prob. 21QCh. 10 - Prob. 22QCh. 10 - Prob. 23QCh. 10 - Prob. 24QCh. 10 - When wet laundry is hung on a clothesline on a...Ch. 10 - You have three covalent compounds with three very...Ch. 10 - Prob. 28QCh. 10 - Compare and contrast the structures of the...Ch. 10 - Silicon carbide (SiC) is an extremely hard...Ch. 10 - How could you tell experimentally if TiO2 is an...Ch. 10 - A common prank on college campuses is to switch...Ch. 10 - A plot of In (Pvap) versus 1/T (K) is linear with...Ch. 10 - Prob. 34QCh. 10 - Identify the most important types of interparticle...Ch. 10 - Prob. 36ECh. 10 - Predict which substance in each of the following...Ch. 10 - Consider the compounds CI2, HCI. F2, NaF, and HF....Ch. 10 - Prob. 39ECh. 10 - Consider the following electrostatic potential...Ch. 10 - In each of the following groups of substances,...Ch. 10 - Prob. 42ECh. 10 - The shape of the meniscus of water in a glass tube...Ch. 10 - Prob. 44ECh. 10 - Hydrogen peroxide (H2O2) is a syrupy liquid with a...Ch. 10 - Carbon diselenide (CSe2) is a liquid at room...Ch. 10 - X rays from a copper X-ray tube ( = 154 pm) were...Ch. 10 - The second-order diffraction (n = 2) for a gold...Ch. 10 - A topaz crystal has an interplanar spacing (d) of...Ch. 10 - X rays of wavelength 2.63 were used to analyze a...Ch. 10 - Calcium has a cubic closest packed structure as a...Ch. 10 - Nickel has a face-centered cubic unit cell. The...Ch. 10 - A certain form of lead has a cubic closest packed...Ch. 10 - Prob. 54ECh. 10 - You are given a small bar of an unknown metal X....Ch. 10 - A metallic solid with atoms in a face-centered...Ch. 10 - Titanium metal has a body-centered cubic unit...Ch. 10 - Barium has a body-centered cubic structure. If the...Ch. 10 - The radius of gold is 144 pm, and the density is...Ch. 10 - The radius of tungsten is 137 pm and the density...Ch. 10 - What fraction of the total volume of a cubic...Ch. 10 - Iron has a density of 7.86 g/cm3 and crystallizes...Ch. 10 - Prob. 63ECh. 10 - Prob. 64ECh. 10 - Selenium is a semiconductor used in photocopying...Ch. 10 - Prob. 66ECh. 10 - Prob. 67ECh. 10 - Prob. 68ECh. 10 - The structures of some common crystalline...Ch. 10 - The unit cell for nickel arsenide is shown below....Ch. 10 - Cobalt fluoride crystallizes in a closest packed...Ch. 10 - The compounds Na2O, CdS, and ZrI4. all can be...Ch. 10 - What is the formula for the compound that...Ch. 10 - Prob. 74ECh. 10 - A certain metal fluoride crystallizes in such a...Ch. 10 - Prob. 76ECh. 10 - The unit cell of MgO is shown below l Does MgO...Ch. 10 - In solid KCl the smallest distance between the...Ch. 10 - The CsCl structure is a simple cubic array of...Ch. 10 - MnO has either the NaCI type structure or the CsCI...Ch. 10 - What type of solid will each of the following...Ch. 10 - What type of solid will each of the following...Ch. 10 - The memory metal, nitinol, is an alloy of nickel...Ch. 10 - Superalloys have been made of nickel and aluminum....Ch. 10 - Perovskite is a mineral containing calcium,...Ch. 10 - A mineral crystallizes in a cubic closest packed...Ch. 10 - Materials containing the elements Y, Ba, Cu, and O...Ch. 10 - The structures of another class of ceramic,...Ch. 10 - Plot the following data and determine Hvap for...Ch. 10 - From the following data for liquid nitric acid,...Ch. 10 - In Breckenridge, Colorado, the typical atmospheric...Ch. 10 - The temperature inside a pressure cooker is 115C....Ch. 10 - Carbon tetrachloride, CCl4, has a vapor pressure...Ch. 10 - Diethyl ether (CH3CH2OCH2CH3) was one of the first...Ch. 10 - A substance, X, has the following properties:...Ch. 10 - Use the heating-cooling curve below to answer the...Ch. 10 - The molar heat of fusion of sodium metal is 2.60...Ch. 10 - Prob. 98ECh. 10 - What quantity of energy does it take to convert...Ch. 10 - Consider a 75.0-g sample of H2O(g) at 125C. What...Ch. 10 - An ice cube tray contains enough water at 22.0C to...Ch. 10 - A 0.250-g chunk of sodium metal is cautiously...Ch. 10 - Prob. 103ECh. 10 - Prob. 104ECh. 10 - Prob. 105ECh. 10 - Prob. 106ECh. 10 - Prob. 107ECh. 10 - Consider the following data for xenon: Triple...Ch. 10 - Some of the physical properties of H2O and D2O are...Ch. 10 - Rationalize the following boiling points:Ch. 10 - Consider the following vapor pressure versus...Ch. 10 - Consider the following enthalpy changes:...Ch. 10 - Prob. 113AECh. 10 - Boron nitride (BN) exists in two forms. The first...Ch. 10 - Prob. 115AECh. 10 - Argon has a cubic closest packed structure as a...Ch. 10 - Prob. 117AECh. 10 - A 20.0-g sample of ice at 10.0C is mixed with...Ch. 10 - In regions with dry climates, evaporative coolers...Ch. 10 - Which of the following compound(s) exhibit only...Ch. 10 - Which of the following statements about...Ch. 10 - Prob. 123CWPCh. 10 - Aluminum has an atomic radius of 143 pm and forms...Ch. 10 - Pyrolusite is a mineral containing manganese ions...Ch. 10 - The structure of the compound K2O is best...Ch. 10 - Prob. 127CWPCh. 10 - Some ice cubes at 0c with a total mass of 403 g...Ch. 10 - The enthalpy of vaporization for acetone is 32.0...Ch. 10 - Prob. 130CWPCh. 10 - When I mole of benzene is vaporized at a constant...Ch. 10 - You and a friend each synthesize a compound with...Ch. 10 - Prob. 133CPCh. 10 - Prob. 134CPCh. 10 - Consider two different organic compounds, each...Ch. 10 - Rationalize the differences in physical properties...Ch. 10 - Prob. 137CPCh. 10 - Some ionic compounds contain a mixture of...Ch. 10 - Some ionic compounds contain a mixture of...Ch. 10 - Spinel is a mineral that contains 37.9% aluminum,...Ch. 10 - Mn crystallizes in the same type of cubic unit...Ch. 10 - You are asked to help set up a historical display...Ch. 10 - Some water is placed in a sealed glass container...Ch. 10 - The molar enthalpy of vaporization of water at 373...Ch. 10 - Prob. 145CPCh. 10 - Rubidium chloride has the sodium chloride...Ch. 10 - Prob. 147IPCh. 10 - A metal burns in air at 600c under high pressure...Ch. 10 - Prob. 149IPCh. 10 - General Zod has sold Lex Luthor what Zod claims to...
Knowledge Booster
Similar questions
- Show how to convert ethyl benzene to (a) 2,5-dichlorobenzoic acid and (b) 2,4-dichlorobenzoic acid.arrow_forwardHelp me solve this problem. Thank you in advance.arrow_forward22.7 Predict the monoalkylated products of the following reactions with benzene. (a) AlCl3 Ya (b) AlCl3 (c) H3PO4 (d) 22.8 Think-Pair-Share AICI3 The reaction below is a common electrophilic aromatic substitution. SO3 H₂SO4 SO₂H (a) Draw the reaction mechanism for this reaction using HSO,+ as the electrophile. (b) Sketch the reaction coordinate diagram, where the product is lower in energy than the starting reactant. (c) Which step in the reaction mechanism is highest in energy? Explain. (d) Which of the following reaction conditions could be used in an electrophilic aro- matic substitution with benzene to provide substituted phenyl derivatives? (i) AICI3 HNO3 H₂SO4 K2Cr2O7 (iii) H₂SO4 (iv) H₂PO₁arrow_forward
- Is an acid-base reaction the only type of reaction that would cause leavening products to rise?arrow_forwardHelp me understand this! Thank you in advance.arrow_forward22.22 For each compound, indicate which group on the ring is more strongly activating and then draw a structural formula of the major product formed by nitration of the compound. Br CHO (a) CH3 (b) (c) CHO CH3 SO₂H (d) ☑ OCHS NO₂ (e) (f) CO₂H NHCOCH3 NHCOCH, (h) CHS 22.23 The following molecules each contain two aromatic rings. (b) 000-100- H3C (a) (c) Which ring in each undergoes electrophilic aromatic substitution more readily? Draw the major product formed on nitration.arrow_forward
- V Consider this step in a radical reaction: Br: ? What type of step is this? Check all that apply. Draw the products of the step on the right-hand side of the drawing area below. If more than one set of products is possible, draw any set. Also, draw the mechanism arrows on the left-hand side of the drawing area to show how this happens. ⚫ionization termination initialization neutralization none of the abc Explanation Check 80 Ο F3 F1 F2 2 F4 01 % do5 $ 94 #3 X 5 C MacBook Air 25 F5 F6 66 ©2025 ˇ F7 29 & 7 8arrow_forwardShow how to convert ethyl benzene to (a) 2,5-dichlorobenzoic acid and (b) 2,4-dichlorobenzoic acid.arrow_forwardno aiarrow_forward
- Polymers may be composed of thousands of monomers. Draw three repeat units (trimer) of the polymer formed in this reaction. Assume there are hydrogen atoms there are hydrogen atoms on the two ends of the trimer. Ignore inorganic byproducts.arrow_forwardDraw a tetramer if this alternating copolymer pleasearrow_forwardDraw the monomers required to synthesize this condensation polymer.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningIntroductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning

World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning

Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co

Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning

Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning

Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning