Introductory Chemistry (6th Edition)
6th Edition
ISBN: 9780134302386
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 10, Problem 10SAQ
Which molecular is polar?
a.
b.
c.
d.
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6. The equilibrium constant for the reaction
2 HBr (g)
→ H2(g) + Br2(g)
Can be expressed by the empirical formula
11790 K
In K-6.375 + 0.6415 In(T K-¹)
-
T
Use this formula to determine A,H as a function of temperature. Calculate A,-H at 25 °C and at
100 °C.
3. Nitrosyl chloride, NOCI, decomposes according to
2 NOCI (g) → 2 NO(g)
+ Cl2(g)
Assuming that we start with no moles of NOCl (g) and no NO(g) or Cl2(g), derive an expression
for Kp in terms of the equilibrium value of the extent of reaction, Seq, and the pressure, P.
Given that K₂ = 2.00 × 10-4, calculate Seq/
of
29/no when P = 0.080 bar. What is the new value
по
ƒª/ at equilibrium when P = 0.160 bar? Is this result in accord with Le Châtelier's
Principle?
Consider the following chemical equilibrium:
2SO2(g) + O2(g) = 2SO3(g)
•
Write the equilibrium constant expression for this reaction.
Now compare it to the equilibrium constant expression for the related reaction:
•
.
1
SO2(g) + O2(g) = SO3(g)
2
How do these two equilibrium expressions differ?
What important principle about the dependence of equilibrium constants on the stoichiometry of a
reaction can you learn from this comparison?
Chapter 10 Solutions
Introductory Chemistry (6th Edition)
Ch. 10 - Q1. Which pair of elements has the most similar...Ch. 10 - What is the Lewis structure for the compound that...Ch. 10 - Prob. 3SAQCh. 10 - Q4. What is the correct Lewis structure for?
a....Ch. 10 - Q5. How many electron dots are in the Lewis...Ch. 10 - Prob. 6SAQCh. 10 - What is the molecular geometry of PBr3 ? a. Bent...Ch. 10 - What is the molecular geometry of N2O ? (Nitrogen...Ch. 10 - Prob. 9SAQCh. 10 - Q10. Which molecular is polar?
a.
b.
c.
d.
Ch. 10 - Prob. 1ECh. 10 - Write the election configuration for Ne and Ar....Ch. 10 - In the Lewis model, what is an octet? What is a...Ch. 10 - 4. What is the different between ionic bonding and...Ch. 10 - Prob. 5ECh. 10 - Prob. 6ECh. 10 - 7. How are double and triple bonds physically...Ch. 10 - What is the procedure for writing a covalent Lewis...Ch. 10 - 9. How do you determine the number of electrons...Ch. 10 - How do you determine the number of electrons that...Ch. 10 - Prob. 11ECh. 10 - What are resonance structures? Why are they...Ch. 10 - Prob. 13ECh. 10 - 14. If all of the election group around a central...Ch. 10 - Prob. 15ECh. 10 - What is the difference between electron geometry...Ch. 10 - Prob. 17ECh. 10 - 18. What is the most electronegative element on...Ch. 10 - Prob. 19ECh. 10 - What is a dipole moment?Ch. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - Write an electron configuration for each element...Ch. 10 - 24. Write an electron configuration for each...Ch. 10 - Write the Lewis structure for each element. a. I...Ch. 10 - Write the Lewis structure for each element. a. Kr...Ch. 10 - Write a generic Lewis structure for the halogens....Ch. 10 - Write a generic Lewis structure for the alkali...Ch. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - 32. Write the Lewis structure for each ion.
a.
b....Ch. 10 - Indicate the noble gas that has the same Lewis...Ch. 10 - 34. Indicate the noble gas that has the same Lewis...Ch. 10 - Lewis structure for lonic compounds
35. Is each...Ch. 10 - Is each compound best represented by an ionic or a...Ch. 10 - Write the Lewis structure for each ionic compound....Ch. 10 - Write the Lewis structure for each ionic compound....Ch. 10 - Use the Lewis model to determine the formula for...Ch. 10 - 40. Use the Lewis model to determine the formula...Ch. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - Determine what is wrong with each ionic Lewis...Ch. 10 - Use the Lewis model to explain why each element...Ch. 10 - Use the Lewis model to explain why the compound...Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - 48. Write the Lewis structure for each...Ch. 10 - 49. Write the Lewis structure for each...Ch. 10 - 50. Write the Lewis structure for each...Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - 53. Determine what is wrong with each Lewis...Ch. 10 - 54. Determine what is wrong with each Lewis...Ch. 10 - 55. Write the Lewis structure for each molecule or...Ch. 10 - Write the Lewis structure for each molecule or...Ch. 10 - 57. Write the Lewis structure for each ion....Ch. 10 - Prob. 58ECh. 10 - Write the Lewis structure for each molecule. These...Ch. 10 - Write the Lewis structure for each molecule. These...Ch. 10 - 61. Determine the number of electron groups around...Ch. 10 - 62. Determine the number of electron groups around...Ch. 10 - 63. Determine the number of bonding groups and the...Ch. 10 - Determine the number of bonding groups and the...Ch. 10 - 65. Determine the molecular geometry of each...Ch. 10 - Determine the molecular geometry of each molecule....Ch. 10 - ...Ch. 10 - 66. Determine the molecular geometry of each...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - 71. Determine the bond angles for each molecule in...Ch. 10 - 72. Determine the bond angles for each molecule in...Ch. 10 - Determine the electron and molecular geometry of...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - Determine the molecular geometry of each...Ch. 10 - 76. Determine the molecular geometry of each...Ch. 10 - Refer to Figure10.2 to determine the...Ch. 10 - Refer to figure 10.2 to determine the...Ch. 10 - List these elements in order of decreasing...Ch. 10 - 80. List these elements in order of increasing...Ch. 10 - 81. Refer to figure10.2 to find the...Ch. 10 - Refer to figure 10.2 to find the electronegativity...Ch. 10 - Arrange these diatomic molecules in order of...Ch. 10 - Arrange these diatomic molecules in order of...Ch. 10 - Classify each diatomic molecule as polar or...Ch. 10 - 86. Classify each diatomic molecule as polar or...Ch. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Classify each molecule as polar nonpolar. a. CS2...Ch. 10 - 90. Classify each molecule as polar or...Ch. 10 - 91. Classify each molecule as polar nonpolar.
a....Ch. 10 - Classify each molecule as polar or nonpolar. a....Ch. 10 - Prob. 93ECh. 10 - Prob. 94ECh. 10 - 95. Determine whether each compound is ionic or...Ch. 10 - Determine whether each compound is ionic or...Ch. 10 - Write the Lewis structure for OCCI2 (carbon is...Ch. 10 - Prob. 98ECh. 10 - Prob. 99ECh. 10 - Prob. 100ECh. 10 - Prob. 101ECh. 10 - 102. Consider the precipitation reaction.
Write...Ch. 10 - Prob. 103ECh. 10 - Prob. 104ECh. 10 - 105. Each compound listed contains both ionic and...Ch. 10 - Prob. 106ECh. 10 - 107. Each molecule listed contains an expanded...Ch. 10 - Prob. 108ECh. 10 - Formic acid is responsible for the sting you feel...Ch. 10 - Diazomethane has the following composition by...Ch. 10 - Free radicals are molecules that contain an odd...Ch. 10 - Prob. 112ECh. 10 - Prob. 113ECh. 10 - Prob. 114ECh. 10 - Prob. 115ECh. 10 - Prob. 116QGWCh. 10 - Draft a list stepbystep instructions for writing a...Ch. 10 - for each of the following molecules:...Ch. 10 - The VSEPR model is useful in predicting bond for...
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- Given Kp for 2 reactions. Find the Kp for the following reaction: BrCl(g)+ 1/2 I2(g) ->IBr(g) + 1/2 Cl2(g)arrow_forwardFor a certain gas-phase reaction at constant pressure, the equilibrium constant Kp is observed to double when the temperature increases from 300 K to 400 K. Calculate the enthalpy change of the reaction, Ah, using this information.arrow_forwardHydrogen bonding in water plays a key role in its physical properties. Assume that the energy required to break a hydrogen bond is approximately 8 kJ/mol. Consider a simplified two-state model where a "formed" hydrogen bond is in the ground state and a "broken" bond is in the excited state. Using this model: • Calculate the fraction of broken hydrogen bonds at T = 300 K, and also at T = 273 K and T = 373 K. • At what temperature would approximately 50% of the hydrogen bonds be broken? • What does your result imply about the accuracy or limitations of the two-state model in describing hydrogen bonding in water? Finally, applying your understanding: • Would you expect it to be easier or harder to vaporize water at higher temperatures? Why? If you were to hang wet laundry outside, would it dry more quickly on a warm summer day or on a cold winter day, assuming humidity is constant?arrow_forward
- (3 pts) Use the Kapustinskii equation to calculate the lattice enthalpy for MgBr2 anddiscuss any differences between this result and that from #4.arrow_forward(3 pts) Silver metal adopts a fcc unit cell structure and has an atomic radius of 144 pm. Fromthis information, calculate the density of silver. Show all work.arrow_forward4. (3 pts) From the information below, determine the lattice enthalpy for MgBr2. Show all work. AH/(kJ mol-¹) Sublimation of Mg(s) +148 lonization of Mg(g) +2187 to Mg2+(g) Vaporization of Br₂(1) +31 Dissociation of Br,(g) +193 Electron gain by Br(g) -331 Formation of MgBr₂(s) -524arrow_forward
- 1. (4 pts-2 pts each part) Consider the crystal structures of NaCl, ZnS, and CsCl (not necessarily shown in this order). a. For one of the three compounds, justify that the unit cell is consistent with stoichiometry of the compound. b. In each of the crystal structures, the cations reside in certain holes in the anions' packing structures. For each compound, what type of holes are occupied by the cations and explain why those particular types of holes are preferred.arrow_forward(2 pts) What do you expect to happen in a Na2O crystal if a Cl− ion replaces one of the O2−ions in the lattice?arrow_forward(2 pts) WSe2 is an ionic compound semiconductor that can be made to be p-type or n-type.What must happen to the chemical composition for it to be p-type? What must happen tothe chemical composition for it to be n-type?arrow_forward
- 8. (2 pts) Silicon semiconductors have a bandgap of 1.11 eV. What is the longest photon wavelength that can promote an electron from the valence band to the conduction band in a silicon-based photovoltaic solar cell? Show all work. E = hv = hc/λ h = 6.626 x 10-34 Js c = 3.00 x 108 m/s 1 eV 1.602 x 10-19 Jarrow_forwardA solution containing 100.0 mL of 0.155 M EDTA buffered to pH 10.00 was titrated with 100.0 mL of 0.0152 M Hg(ClO4)2 in a cell: calomel electrode (saturated)//titration solution/Hg(l) Given the formation constant of Hg(EDTA)2-, logKf= 21.5, and alphaY4-=0.30, find out the cell voltage E. Hg2+(aq) + 2e- = Hg(l) E0= 0.852 V E' (calomel electrode, saturated KCl) = 0.241 Varrow_forwardFrom the following reduction potentials I2 (s) + 2e- = 2I- (aq) E0= 0.535 V I2 (aq) + 2e- = 2I- (aq) E0= 0.620 V I3- (aq) + 2e- = 3I- (aq) E0= 0.535 V a) Calculate the equilibrium constant for I2 (aq) + I- (aq) = I3- (aq). b) Calculate the equilibrium constant for I2 (s) + I- (aq) = I3- (aq). c) Calculate the solubility of I2 (s) in water.arrow_forward
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