
Introductory Chemistry (6th Edition)
6th Edition
ISBN: 9780134302386
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 10, Problem 101E
Interpretation Introduction
Interpretation: The reaction is to be written where each of the reactants and products are shown with their Lewis structures.
Concept introduction: A Lewis structure is used to represent the valence electrons and the bonds present in a molecule.
In the Lewis structure, dots represent the valence electrons surrounding the
Total number of electrons for Lewis structure can be calculated by summing the valence electrons of each atom in the molecule.
Ionic bond is formed by the transfer of electrons whereas covalent bond is formed by the equal sharing of electrons between atoms.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 10 Solutions
Introductory Chemistry (6th Edition)
Ch. 10 - Q1. Which pair of elements has the most similar...Ch. 10 - What is the Lewis structure for the compound that...Ch. 10 - Prob. 3SAQCh. 10 - Q4. What is the correct Lewis structure for?
a....Ch. 10 - Q5. How many electron dots are in the Lewis...Ch. 10 - Prob. 6SAQCh. 10 - What is the molecular geometry of PBr3 ? a. Bent...Ch. 10 - What is the molecular geometry of N2O ? (Nitrogen...Ch. 10 - Prob. 9SAQCh. 10 - Q10. Which molecular is polar?
a.
b.
c.
d.
Ch. 10 - Prob. 1ECh. 10 - Write the election configuration for Ne and Ar....Ch. 10 - In the Lewis model, what is an octet? What is a...Ch. 10 - 4. What is the different between ionic bonding and...Ch. 10 - Prob. 5ECh. 10 - Prob. 6ECh. 10 - 7. How are double and triple bonds physically...Ch. 10 - What is the procedure for writing a covalent Lewis...Ch. 10 - 9. How do you determine the number of electrons...Ch. 10 - How do you determine the number of electrons that...Ch. 10 - Prob. 11ECh. 10 - What are resonance structures? Why are they...Ch. 10 - Prob. 13ECh. 10 - 14. If all of the election group around a central...Ch. 10 - Prob. 15ECh. 10 - What is the difference between electron geometry...Ch. 10 - Prob. 17ECh. 10 - 18. What is the most electronegative element on...Ch. 10 - Prob. 19ECh. 10 - What is a dipole moment?Ch. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - Write an electron configuration for each element...Ch. 10 - 24. Write an electron configuration for each...Ch. 10 - Write the Lewis structure for each element. a. I...Ch. 10 - Write the Lewis structure for each element. a. Kr...Ch. 10 - Write a generic Lewis structure for the halogens....Ch. 10 - Write a generic Lewis structure for the alkali...Ch. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - 32. Write the Lewis structure for each ion.
a.
b....Ch. 10 - Indicate the noble gas that has the same Lewis...Ch. 10 - 34. Indicate the noble gas that has the same Lewis...Ch. 10 - Lewis structure for lonic compounds
35. Is each...Ch. 10 - Is each compound best represented by an ionic or a...Ch. 10 - Write the Lewis structure for each ionic compound....Ch. 10 - Write the Lewis structure for each ionic compound....Ch. 10 - Use the Lewis model to determine the formula for...Ch. 10 - 40. Use the Lewis model to determine the formula...Ch. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - Determine what is wrong with each ionic Lewis...Ch. 10 - Use the Lewis model to explain why each element...Ch. 10 - Use the Lewis model to explain why the compound...Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - 48. Write the Lewis structure for each...Ch. 10 - 49. Write the Lewis structure for each...Ch. 10 - 50. Write the Lewis structure for each...Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - 53. Determine what is wrong with each Lewis...Ch. 10 - 54. Determine what is wrong with each Lewis...Ch. 10 - 55. Write the Lewis structure for each molecule or...Ch. 10 - Write the Lewis structure for each molecule or...Ch. 10 - 57. Write the Lewis structure for each ion....Ch. 10 - Prob. 58ECh. 10 - Write the Lewis structure for each molecule. These...Ch. 10 - Write the Lewis structure for each molecule. These...Ch. 10 - 61. Determine the number of electron groups around...Ch. 10 - 62. Determine the number of electron groups around...Ch. 10 - 63. Determine the number of bonding groups and the...Ch. 10 - Determine the number of bonding groups and the...Ch. 10 - 65. Determine the molecular geometry of each...Ch. 10 - Determine the molecular geometry of each molecule....Ch. 10 - ...Ch. 10 - 66. Determine the molecular geometry of each...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - 71. Determine the bond angles for each molecule in...Ch. 10 - 72. Determine the bond angles for each molecule in...Ch. 10 - Determine the electron and molecular geometry of...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - Determine the molecular geometry of each...Ch. 10 - 76. Determine the molecular geometry of each...Ch. 10 - Refer to Figure10.2 to determine the...Ch. 10 - Refer to figure 10.2 to determine the...Ch. 10 - List these elements in order of decreasing...Ch. 10 - 80. List these elements in order of increasing...Ch. 10 - 81. Refer to figure10.2 to find the...Ch. 10 - Refer to figure 10.2 to find the electronegativity...Ch. 10 - Arrange these diatomic molecules in order of...Ch. 10 - Arrange these diatomic molecules in order of...Ch. 10 - Classify each diatomic molecule as polar or...Ch. 10 - 86. Classify each diatomic molecule as polar or...Ch. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Classify each molecule as polar nonpolar. a. CS2...Ch. 10 - 90. Classify each molecule as polar or...Ch. 10 - 91. Classify each molecule as polar nonpolar.
a....Ch. 10 - Classify each molecule as polar or nonpolar. a....Ch. 10 - Prob. 93ECh. 10 - Prob. 94ECh. 10 - 95. Determine whether each compound is ionic or...Ch. 10 - Determine whether each compound is ionic or...Ch. 10 - Write the Lewis structure for OCCI2 (carbon is...Ch. 10 - Prob. 98ECh. 10 - Prob. 99ECh. 10 - Prob. 100ECh. 10 - Prob. 101ECh. 10 - 102. Consider the precipitation reaction.
Write...Ch. 10 - Prob. 103ECh. 10 - Prob. 104ECh. 10 - 105. Each compound listed contains both ionic and...Ch. 10 - Prob. 106ECh. 10 - 107. Each molecule listed contains an expanded...Ch. 10 - Prob. 108ECh. 10 - Formic acid is responsible for the sting you feel...Ch. 10 - Diazomethane has the following composition by...Ch. 10 - Free radicals are molecules that contain an odd...Ch. 10 - Prob. 112ECh. 10 - Prob. 113ECh. 10 - Prob. 114ECh. 10 - Prob. 115ECh. 10 - Prob. 116QGWCh. 10 - Draft a list stepbystep instructions for writing a...Ch. 10 - for each of the following molecules:...Ch. 10 - The VSEPR model is useful in predicting bond for...
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