The Lewis structure of the given amino acid is to be drawn and also atoms with nonzero formal charge is to be identified. Concept introduction: The steps to draw the Lewis structure of the molecule there are as follows: Step 1: Find the central atom and place the other atoms around it. The atom in a compound which has the lowest group number or lowest electronegativity considered as the central atom. Step 2: Calculate the total number of valence electrons. Step 3: Connect the other atoms around the central atoms to the central atom with a single bond and lower the value of valence electrons by 2 of every single bond. Step 4: Allocate the remaining electrons in pairs so that each atom can get 8 electrons. Formula to calculate the formal charge of the atom is as follows: Formal charge = ( number of valence electrons ) − ( ( number of non-bonding electrons ) + ( 1 2 ) ( number of bonding electrons ) ) (1)
The Lewis structure of the given amino acid is to be drawn and also atoms with nonzero formal charge is to be identified. Concept introduction: The steps to draw the Lewis structure of the molecule there are as follows: Step 1: Find the central atom and place the other atoms around it. The atom in a compound which has the lowest group number or lowest electronegativity considered as the central atom. Step 2: Calculate the total number of valence electrons. Step 3: Connect the other atoms around the central atoms to the central atom with a single bond and lower the value of valence electrons by 2 of every single bond. Step 4: Allocate the remaining electrons in pairs so that each atom can get 8 electrons. Formula to calculate the formal charge of the atom is as follows: Formal charge = ( number of valence electrons ) − ( ( number of non-bonding electrons ) + ( 1 2 ) ( number of bonding electrons ) ) (1)
The Lewis structure of the given amino acid is to be drawn and also atoms with nonzero formal charge is to be identified.
Concept introduction:
The steps to draw the Lewis structure of the molecule there are as follows:
Step 1: Find the central atom and place the other atoms around it. The atom in a compound which has the lowest group number or lowest electronegativity considered as the central atom.
Step 2: Calculate the total number of valence electrons.
Step 3: Connect the other atoms around the central atoms to the central atom with a single bond and lower the value of valence electrons by 2 of every single bond.
Step 4: Allocate the remaining electrons in pairs so that each atom can get 8 electrons.
Formula to calculate the formal charge of the atom is as follows:
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
16. The proton NMR spectral information shown in this problem is for a compound with formula
CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec-
tral results, including DEPT-135 and DEPT-90 results, are tabulated:
7
J
Normal Carbon
DEPT-135
DEPT-90
19 ppm
Positive
No peak
122
Positive
Positive
cus
и
124
Positive
Positive
126
Positive
Positive
128
No peak
No peak
4°
129
Positive
Positive
130
Positive
Positive
(144
No peak
No peak
148
No peak
No peak
150
Positive
Positive
してし
3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing
mechanism below, but make sure to draw the product of each proposed step (3 points).
+ En
CN
CN
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