LCPO CHEMISTRY W/MODIFIED MASTERING
8th Edition
ISBN: 9780135214756
Author: Robinson
Publisher: PEARSON
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Chapter 10, Problem 10.52SP
Interpretation Introduction
Interpretation:
The volume of oxygen gas that is kept at
Concept introduction:
The combination of all the
Where,
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Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of ZybanⓇ:
1. Write a mechanism for the bromination of m-chloropropiophenone.
Br₂
CH2Cl2
Cl
Br
2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks).
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 10 Solutions
LCPO CHEMISTRY W/MODIFIED MASTERING
Ch. 10 - Hurricane Irma (2017) had a central pressure of...Ch. 10 - Prob. 10.2ACh. 10 - Prob. 10.3PCh. 10 - Prob. 10.4ACh. 10 - Conceptual PRACTICE 10.5 Show the approximate...Ch. 10 - Conceptual APPLY 10.6 Show the approximate level...Ch. 10 - How many moles of methane gas, CH4, are in a...Ch. 10 - APPLY 10.8 An aerosol spray can with a volume of...Ch. 10 - Prob. 10.9PCh. 10 - APPLY 10.10 A weather balloon has a volume of 45.0...
Ch. 10 - Prob. 10.11PCh. 10 - Prob. 10.12ACh. 10 - Prob. 10.13PCh. 10 - APPLY 10.14 The image shows carbon dioxide gas...Ch. 10 - Prob. 10.15PCh. 10 - Prob. 10.16ACh. 10 - Prob. 10.17PCh. 10 - Prob. 10.18ACh. 10 - Prob. 10.19PCh. 10 - Prob. 10.20PCh. 10 - Prob. 10.21PCh. 10 - Prob. 10.22PCh. 10 - Prob. 10.23CPCh. 10 - Prob. 10.24CPCh. 10 - Prob. 10.25CPCh. 10 - Prob. 10.26CPCh. 10 - Prob. 10.27CPCh. 10 - Prob. 10.28CPCh. 10 - Prob. 10.29CPCh. 10 - Prob. 10.30CPCh. 10 - Prob. 10.31CPCh. 10 - Prob. 10.32CPCh. 10 - Prob. 10.33CPCh. 10 - Prob. 10.34SPCh. 10 - If the density of water is 1.00 g/mL and the...Ch. 10 - Prob. 10.36SPCh. 10 - Prob. 10.37SPCh. 10 - Prob. 10.38SPCh. 10 - Carry out the following conversions: (a) 352 torr...Ch. 10 - What is the pressure in millimeters of mercury...Ch. 10 - What is the pressure in atmospheres inside a...Ch. 10 - Assume that you have an open-end manometer filled...Ch. 10 - Prob. 10.43SPCh. 10 - Prob. 10.44SPCh. 10 - Prob. 10.45SPCh. 10 - Prob. 10.46SPCh. 10 - Prob. 10.47SPCh. 10 - Prob. 10.48SPCh. 10 - Prob. 10.49SPCh. 10 - Prob. 10.50SPCh. 10 - Prob. 10.51SPCh. 10 - Prob. 10.52SPCh. 10 - A compressed air tank carried by scuba divers has...Ch. 10 - Prob. 10.54SPCh. 10 - Prob. 10.55SPCh. 10 - Prob. 10.56SPCh. 10 - Prob. 10.57SPCh. 10 - Prob. 10.58SPCh. 10 - Prob. 10.59SPCh. 10 - Prob. 10.60SPCh. 10 - Prob. 10.61SPCh. 10 - Prob. 10.62SPCh. 10 - Prob. 10.63SPCh. 10 - Prob. 10.64SPCh. 10 - Prob. 10.65SPCh. 10 - Prob. 10.66SPCh. 10 - What is the density in g/L of a gas mixture that...Ch. 10 - An unknown gas is placed in a 1.500-L bulb at a...Ch. 10 - What are the molecular weights of the gases with...Ch. 10 - Prob. 10.70SPCh. 10 - Prob. 10.71SPCh. 10 - Hydrogen gas can be prepared by reaction of zinc...Ch. 10 - Ammonium nitrate can decompose explosively when...Ch. 10 - Prob. 10.74SPCh. 10 - Titanium(III) chloride, a substance used in...Ch. 10 - A typical high-pressure tire on a bicycle might...Ch. 10 - Prob. 10.77SPCh. 10 - Prob. 10.78SPCh. 10 - Prob. 10.79SPCh. 10 - Prob. 10.80SPCh. 10 - Prob. 10.81SPCh. 10 - A special gas mixture used in bacterial growth...Ch. 10 - A gas mixture for use in some lasers contains...Ch. 10 - Prob. 10.84SPCh. 10 - A mixture of Ar and N2 gases has a density of...Ch. 10 - A mixture of 14.2 g of H2 and 36.7 g of Ar is...Ch. 10 - A 20.0-L flask contains 0.776 g of He and 3.61 g...Ch. 10 - Prob. 10.88SPCh. 10 - Prob. 10.89SPCh. 10 - Prob. 10.90SPCh. 10 - Gaseous compound Q contains only xenon and oxygen....Ch. 10 - Prob. 10.92SPCh. 10 - Prob. 10.93SPCh. 10 - Prob. 10.94SPCh. 10 - Prob. 10.95SPCh. 10 - Prob. 10.96SPCh. 10 - Prob. 10.97SPCh. 10 - Prob. 10.98SPCh. 10 - Prob. 10.99SPCh. 10 - Prob. 10.100SPCh. 10 - Prob. 10.101SPCh. 10 - Prob. 10.102SPCh. 10 - Prob. 10.103SPCh. 10 - Prob. 10.104SPCh. 10 - Prob. 10.105SPCh. 10 - Prob. 10.106SPCh. 10 - Prob. 10.107SPCh. 10 - Prob. 10.108SPCh. 10 - Prob. 10.109SPCh. 10 - Prob. 10.110SPCh. 10 - Prob. 10.111SPCh. 10 - Prob. 10.112SPCh. 10 - Assume that you have 15.00 mol ofN2in a volume of...Ch. 10 - Uranium hexafluoride, a molecular solid used for...Ch. 10 - Use both the ideal gas law and the van der Waals...Ch. 10 - Prob. 10.116SPCh. 10 - Prob. 10.117SPCh. 10 - Prob. 10.118SPCh. 10 - Prob. 10.119SPCh. 10 - Prob. 10.120SPCh. 10 - Prob. 10.121SPCh. 10 - Prob. 10.122SPCh. 10 - Prob. 10.123SPCh. 10 - Prob. 10.124SPCh. 10 - Prob. 10.125SPCh. 10 - Prob. 10.126SPCh. 10 - Prob. 10.127SPCh. 10 - Prob. 10.128SPCh. 10 - Prob. 10.129SPCh. 10 - Prob. 10.130SPCh. 10 - Prob. 10.131SPCh. 10 - Prob. 10.132SPCh. 10 - Prob. 10.133SPCh. 10 - Prob. 10.134MPCh. 10 - Prob. 10.135MPCh. 10 - Prob. 10.136MPCh. 10 - Prob. 10.137MPCh. 10 - Prob. 10.138MPCh. 10 - Prob. 10.139MPCh. 10 - Prob. 10.140MPCh. 10 - Prob. 10.141MPCh. 10 - Prob. 10.142MPCh. 10 - Prob. 10.143MPCh. 10 - Prob. 10.144MPCh. 10 - An empty 4.00-Lsteel vesselis filled with 1.00 atm...Ch. 10 - When a gaseous compound X containing only C, H,...Ch. 10 - Isooctane, C8H18, is the component of gasoline...Ch. 10 - Prob. 10.148MPCh. 10 - Prob. 10.149MPCh. 10 - Prob. 10.150MP
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