LCPO CHEMISTRY W/MODIFIED MASTERING
8th Edition
ISBN: 9780135214756
Author: Robinson
Publisher: PEARSON
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Chapter 10, Problem 10.142MP
Interpretation Introduction
Interpretation:
The final pressure in the vessel is to be calculated.
Concept introduction:
The expression to determine number of moles is as follows:
The formula to calculate pressure as per ideal gas equation is as follows:
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The acid-base indicator HX undergoes the following reaction in a dilute aqueous solution:
HX (color 1) H+ + X- (color 2).
The following absorbance data were obtained for a 0.00035 M solution of HX in 0.1 M NaOH
and 0.1 M HCI. Measurements were made at wavelengths of 450 nm and 620 nm using a 1.0
cm glass cuvette.
450
620
A(460 nm) A(630 nm)
0.1 M NaOH
0.1 M HCI
0.065
0.435
0.895
0.150
In the 0.1M NaOH solution, the indicator will be almost 100% in the X- form, while in 0.1M HCI,
the indicator will be nearly 100% protonated (HX). Calculate the acid dissociation constant for
the indicator if a pH=5 buffer solution containing a very small amount of indicator exhibits an
absorbance of 0.567 at 450 nm and 0.395 at 620 nm (measured in a 1 cm glass cuvette).
Chapter 10 Solutions
LCPO CHEMISTRY W/MODIFIED MASTERING
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