Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Textbook Question
Chapter 10, Problem 10.52P
What
addition reaction?
a.
b. 
c. 
d. 
e. 
f.
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73. O-hydroxybenzoic acid.is a major product formed with phenol and which other reactant/s?
I-primary alcohol
Il-sodium hydroxide
Ill-water
IV-carbon dioxide
A. I and III
B. I and IV
C. II and III
D. II and IV
74. How many substitution product/s is/are formed when metabromo anisole is treated with ammonia?
A. 0 no reaction
B. 1
C. 2
D. 3
75. Butan-1-ol is formed from which of the following reactant-reaction pair?
A. Butanal-reduction reaction
B. Butanone - reduction reaction
C. Butanoic acid oxidation reaction
D. Butene- dehydration reaction
76. Dienone phenol rearrangement reaction belongs to which type of reaction?
A. Neutral
B. Acid-catalyzed reaction
C. Base catalyzed reaction
D. Neither of the given choices
77. Evaluate the given statements: In SNI the first step involves the formation of a carbocation. Afterward, the carbocation
is attacked by an electrophile.
A. Only the first statement is correct.
B. Only the second statement is correct.
C. Both statements are correct.
Synthesize each compound from benzene.
Which is the major organic product of this reaction?
A.
B.
4
ОА
O
OB
O C
COD
AICI3
benzene
C.
D.
Chapter 10 Solutions
Organic Chemistry
Ch. 10 - Prob. 10.1PCh. 10 - Problem 10.2 How many degrees of unsaturation are...Ch. 10 - Give an example of a compound with molecular...Ch. 10 - Give the IUPAC name for each alkene.Ch. 10 - Give the IUPAC name for each polyfunctional...Ch. 10 - Prob. 10.6PCh. 10 - Prob. 10.7PCh. 10 - Prob. 10.8PCh. 10 - Prob. 10.9PCh. 10 - Problem 10.10 Rank the following isomers in order...
Ch. 10 - Linolenic acidTable 10.2 and stearidonic acid are...Ch. 10 - Prob. 10.12PCh. 10 - Prob. 10.13PCh. 10 - Prob. 10.14PCh. 10 - Prob. 10.15PCh. 10 - Prob. 10.16PCh. 10 - Prob. 10.17PCh. 10 - Prob. 10.18PCh. 10 - Prob. 10.19PCh. 10 - Which compounds A-D in Figure 10.12 are formed by...Ch. 10 - What two alkenes give rise to each alcohol as the...Ch. 10 - Prob. 10.22PCh. 10 - Problem 10.23 Draw the products of each reaction,...Ch. 10 - Problem 10.24 Draw all stereoisomers formed in...Ch. 10 - Prob. 10.25PCh. 10 - Prob. 10.26PCh. 10 - Borane is sold for laboratory use as a complex...Ch. 10 - What alkylborane is formed from hydroboration of...Ch. 10 - Draw the products formed when each alkene is...Ch. 10 - What alkene can be used to prepare each alcohol as...Ch. 10 - Prob. 10.31PCh. 10 - Draw the products of each reaction using the two...Ch. 10 - Problem 10.31 Devise a synthesis of each compound...Ch. 10 - Give the IUPAC name for each compound. a.b.Ch. 10 - a Label the carbon-carbon double bond in A as E or...Ch. 10 - Prob. 10.36PCh. 10 - Calculate the number of degrees of unsaturation f...Ch. 10 - Prob. 10.38PCh. 10 - The fertility drug clomiphene trade name Clomid is...Ch. 10 - Give the IUPAC name for each compound. a....Ch. 10 - Give the structure corresponding to each name. a....Ch. 10 - 10.40 (a) Draw all possible stereoisomers of, and...Ch. 10 - Prob. 10.43PCh. 10 - 10.42 Now that you have learned how to name...Ch. 10 - Prob. 10.45PCh. 10 - Prob. 10.46PCh. 10 - Prob. 10.47PCh. 10 - Prob. 10.48PCh. 10 - By using the bond dissociation energies in...Ch. 10 - Prob. 10.50PCh. 10 - Repeat Problem 10.50 with CH32C=CH2 as the...Ch. 10 - What alkene can be used to prepare each alkyl...Ch. 10 - Prob. 10.53PCh. 10 - Draw the constitutional isomer formed in each...Ch. 10 - Prob. 10.55PCh. 10 - Draw all stereoisomers formed in each reaction....Ch. 10 - Prob. 10.57PCh. 10 - Prob. 10.58PCh. 10 - Prob. 10.59PCh. 10 - Draw a stepwise mechanism for the following...Ch. 10 - Draw a stepwise mechanism for each reaction. a.b.Ch. 10 - Draw a stepwise mechanism that shows how all three...Ch. 10 - Less stable alkenes can be isomerized to more...Ch. 10 - Prob. 10.64PCh. 10 - Prob. 10.65PCh. 10 - Bromoetherification, the addition of the elements...Ch. 10 - Devise a synthesis of each product from the given...Ch. 10 - Prob. 10.68PCh. 10 - Prob. 10.69PCh. 10 - Prob. 10.70PCh. 10 - 10.66 Explain why A is a stable compound but B is...Ch. 10 - Prob. 10.72PCh. 10 - Prob. 10.73PCh. 10 - 10.69 Lactones, cyclic esters such as compound A,...Ch. 10 - 10.70 Draw a stepwise mechanism for the following...Ch. 10 - 10.71 Like other electrophiles, carbocations add...Ch. 10 - 10.72 Draw a stepwise mechanism for the...
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- Synthesize each compound from benzonitrile (C6H5CN) as the only organic starting material; that is, every carbon in the product must originate in benzonitrile.arrow_forwarda. 5. Draw the product(s) of each addition reaction b. d. دھ HBr H2SO4, H₂O Bra, H2O a. 9-BBN b. H2O2, NaOHarrow_forwardWhat alkane is needed to make each alkyl halide by radical halogenation?arrow_forward
- Which alcohols can be prepared as a single product by hydroboration– oxidation of an alkene? Which alcohols can be prepared as a single product by the acid-catalyzed addition of H2O to an alkene?arrow_forwardDoes the equilibrium favor the reactants or products in each substitution reaction? a. CH;CH2-NH2 Br CH;CH2-Br + "NH2 b. "CN CN + I-arrow_forward70. What are the products of each aromatic substitution reaction? H „H + Cl2 FeCh H. a. H. H CH3 Alch b. + CH,-C-CI CH,arrow_forward
- Synthesize each compound from acetylene. You may use any other organic or inorganic reagents. C. CH,CH,CH,CH, CHO d. CH3CH, CHỖ CHarrow_forwardWhat alkene can be used to prepare each alkyl halide or dihalide as the exclusive or major product of an addition reaction?arrow_forwardFor each of the following alkenes, draw the structure of two different alkyl halides that yield the given alkene as the only product of dehydrohalogenation.arrow_forward
- 1. What is it's type of reaction (Sn1, Sn2, E1, E2, Nucleophilic Addition, Nucleophilic Acyl Substition or Redox reaction) 2. What is it's major product.arrow_forward10. Which of the following alkenes has the highest molar heat of hydrogenation (ie, releases the most heat upon hydrogenation)? d A. B. C. D.arrow_forwardSynthesize each compound from benzene. a. SO₂H 19일 g b. 00 이 Harrow_forward
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