Organic Chemistry
Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Chapter 10, Problem 10.37P

Calculate the number of degrees of unsaturation f or each molecular formula.

a. C 3 H 4 c. C 40 H 56 e. C 10 H 16 O 2 g. C 8 H 9 ClO i. C 7 H 11 N

b. C 6 H 8 d. C 8 H 8 O f. C 8 H 9 Br h. C 7 H 9 Br j. C 4 H 8 BrN

Expert Solution
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Interpretation Introduction

(a)

Interpretation: The number of degree of unsaturation for the given molecular formula is to be calculated.

Concept introduction: The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Answer to Problem 10.37P

The number of degree of unsaturation for C3H4 is 2.

Explanation of Solution

The given molecular formula is C3H4.

The number of carbon and hydrogen atoms present in C3H4 are three and four.

The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

n is the number of carbon atom given in molecular formula.

x is the number of hydrogen atom given in molecular formula.

Substitute all the values in the given formula.

Degreeofunsaturation=2NC+2+NNNXNH2=2(3)+2+0+042=842=2

Therefore, the number of degree of unsaturation for C3H4 is 2.

Conclusion

The number of degree of unsaturation for C3H4 is 2.

Expert Solution
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Interpretation Introduction

(b)

Interpretation: The number of degree of unsaturation for the given molecular formula is to be calculated.

Concept introduction: The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Answer to Problem 10.37P

The number of degree of unsaturation for C6H8 is 3.

Explanation of Solution

The given molecular formula is C6H8.

The number of carbon and hydrogen atoms present in C6H8 are six and eight.

The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Substitute all the values in the given formula.

Degreeofunsaturation=2NC+2+NNNXNH2=2(6)+2+0082=1482=3

Therefore, the number of degree of unsaturation for C6H8 is 3.

Conclusion

The number of degree of unsaturation for C6H8 is 3.

Expert Solution
Check Mark
Interpretation Introduction

(c)

Interpretation: The number of degree of unsaturation for the given molecular formula is to be calculated.

Concept introduction: The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Answer to Problem 10.37P

The number of degree of unsaturation for C40H56 is 13.

Explanation of Solution

The given molecular formula is C40H56.

The number of carbon and hydrogen atoms present in C40H56 are 40 and 56.

The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Substitute all the values in the given formula.

Degreeofunsaturation=2NC+2+NNNXNH2=2(40)+2+00562=82562=13

Therefore, the number of degree of unsaturation for C40H56 is 13.

Conclusion

The number of degree of unsaturation for C40H56 is 13.

Expert Solution
Check Mark
Interpretation Introduction

(d)

Interpretation: The number of degree of unsaturation for the given molecular formula is to be calculated.

Concept introduction: The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Answer to Problem 10.37P

The number of degree of unsaturation for C8H8O is 5.

Explanation of Solution

The given molecular formula is C8H8O.

The number of carbon and hydrogen atoms present in C8H8O are 8 and 8.

The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

n is the number of carbon atom given in molecular formula.

x is the number of hydrogen atom given in molecular formula.

Substitute all the values in the given formula.

Degreeofunsaturation=2NC+2+NNNXNH2=2(8)+2+0+082=1882=5

Therefore, the number of degree of unsaturation for C8H8O is 5.

Conclusion

The number of degree of unsaturation for C8H8O is 5.

Expert Solution
Check Mark
Interpretation Introduction

(e)

Interpretation: The number of degree of unsaturation for the given molecular formula is to be calculated.

Concept introduction: The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Answer to Problem 10.37P

The number of degree of unsaturation for C10H16O2 is 3.

Explanation of Solution

The given molecular formula is C10H16O2.

The number of carbon and hydrogen atoms present in C10H16O2 are 10 and 16.

The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Substitute all the values in the given formula.

Degreeofunsaturation=2NC+2+NNNXNH2=2(10)+2+0+0162=22162=3

Therefore, the number of degree of unsaturation for C10H16O2 is 3.

Conclusion

The number of degree of unsaturation for C10H16O2 is 3.

Expert Solution
Check Mark
Interpretation Introduction

(f)

Interpretation: The number of degree of unsaturation for the given molecular formula is to be calculated.

Concept introduction: The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Answer to Problem 10.37P

The number of degree of unsaturation for C8H9Br is 4.

Explanation of Solution

The given molecular formula is C8H9Br.

The number of carbon and hydrogen atoms present in C8H9Br are 8 and 9. If halogen atom is present in molecular formula than replace halogen and add hydrogen. Therefore, the molecular formula becomes C8H10.

The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Substitute all the values in the given formula.

Degreeofunsaturation=2NC+2+NNNXNH2=2(8)+2+0192=18102=4

Therefore, the number of degree of unsaturation for C8H9Br is 4.

Conclusion

The number of degree of unsaturation for C8H9Br is 4.

Expert Solution
Check Mark
Interpretation Introduction

(g)

Interpretation: The number of degree of unsaturation for the given molecular formula is to be calculated.

Concept introduction: The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Answer to Problem 10.37P

The number of degree of unsaturation for C8H9ClO is 4.

Explanation of Solution

The given molecular formula is C8H9ClO.

The number of carbon and hydrogen atoms present in C8H9ClO are 8 and 9.

The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Substitute all the values in the given formula.

Degreeofunsaturation=2NC+2+NNNXNH2=2(8)+2+0192=18102=4

Therefore, the number of degree of unsaturation for C8H9ClO is 4.

Conclusion

The number of degree of unsaturation for C8H9ClO is 4.

Expert Solution
Check Mark
Interpretation Introduction

(h)

Interpretation: The number of degree of unsaturation for given molecular formula is to be calculated.

Concept introduction: The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Answer to Problem 10.37P

The number of degree of unsaturation for C7H9Br is 3.

Explanation of Solution

The given molecular formula is C7H9Br.

The number of carbon and hydrogen atoms present in C7H9Br are 7 and 9. If halogen atom is present in molecular formula than replace halogen and add hydrogen. Therefore, the molecular formula becomes C7H10.

The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Substitute all the values in the given formula.

Degreeofunsaturation=2NC+2+NNNXNH2=2(7)+2+0192=16102=3

Therefore, the number of degree of unsaturation for C7H9Br is 3.

Conclusion

The number of degree of unsaturation for C7H9Br is 3.

Expert Solution
Check Mark
Interpretation Introduction

(i)

Interpretation: The number of degree of unsaturation for given molecular formula is to be calculated.

Concept introduction: The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Answer to Problem 10.37P

The number of degree of unsaturation for C7H11N is 3.

Explanation of Solution

The given molecular formula is C7H11N.

The number of carbon and hydrogen atoms present in C7H11N are 7 and 11.

The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Substitute all the values in the given formula.

Degreeofunsaturation=2NC+2+NNNXNH2=2(7)+2+1112=16102=3

Therefore, the number of degree of unsaturation for C7H11N is 3.

Conclusion

The number of degree of unsaturation for C7H11N is 3.

Expert Solution
Check Mark
Interpretation Introduction

(j)

Interpretation: The number of degree of unsaturation for given molecular formula is to be calculated.

Concept introduction: The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Answer to Problem 10.37P

The number of degree of unsaturation for C4H8BrN is 1.

Explanation of Solution

The given molecular formula is C4H8BrN.

The number of carbon and hydrogen atoms present in C4H8BrN are 4 and 8.

The formula to calculate the number of degree of unsaturation is,

Degreeofunsaturation=2NC+2+NNNXNH2

Where,

NC is the number of carbon atoms.

NN is the number of nitrogen atoms.

NX is the number of halogen atoms.

NH is the number of hydrogen atoms.

Substitute all the values in the given formula.

Degreeofunsaturation=2NC+2+NNNXNH2=2(4)+2+1182=1082=1

Therefore, the number of degree of unsaturation for C4H8BrN is 1.

Conclusion

The number of degree of unsaturation for C4H8BrN is 1.

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Chapter 10 Solutions

Organic Chemistry

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