(a) Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H 2 O to an alkene is to be predicted. Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule. The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Question

Q2: Resonance Forms a) Draw all resonance forms of the molecules. Include curved arrow notation. Label major resonance contributor. SO2 NO3 Page 3 of 4 Chem 0310 Organic Chemistry 1 HW Problem Sets CH3NSO (Thionitromethane, skeleton on the right) H N H3C S

Answer 1

Question

Chapter 10, Problem 10.48P

Interpretation Introduction

(a)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(b)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(c)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(d)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

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Q2: Resonance Forms a) Draw all resonance forms of the molecules. Include curved arrow notation. Label major resonance contributor. SO2 NO3 Page 3 of 4 Chem 0310 Organic Chemistry 1 HW Problem Sets CH3NSO (Thionitromethane, skeleton on the right) H N H3C S

A 10.00-mL pipet was filled to the mark with distilled water at the lab temperature of 22 oC. The water, delivered to a tared weighing bottle was found to weigh 9.973 g. The density of water at 22 oC is 0.99780 g/mL. Calculate the volume of the pipet in mL. (disregard air displacement for this calculation and record your answer to the proper number of significant digits.)

Resonance Formsa) Draw all resonance forms of the molecules. Include curved arrow notation. Label majorresonance contributor.

Answer 2

Question

Chapter 10, Problem 10.48P

Interpretation Introduction

(a)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(b)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(c)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(d)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

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Answer 3

Question

Chapter 10, Problem 10.48P

Interpretation Introduction

(a)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(b)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(c)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(d)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

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Answer 4

Question

Chapter 10, Problem 10.48P

Interpretation Introduction

(a)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(b)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(c)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(d)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

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Answer 5

Chapter 10, Problem 10.48P

Interpretation Introduction

(a)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(b)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(c)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Interpretation Introduction

(d)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Answer 6

Chapter 10, Problem 10.48P

Interpretation Introduction

(a)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Answer 7

Chapter 10, Problem 10.48P

Interpretation Introduction

(a)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Answer 8

Interpretation Introduction

(b)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Answer 9

Interpretation Introduction

(b)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Answer 10

Interpretation Introduction

(c)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Answer 11

Interpretation Introduction

(c)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Answer 12

Interpretation Introduction

(d)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Answer 13

Interpretation Introduction

(d)

Interpretation: Whether the given alcohol can be prepared as a single product by hydroboration-oxidation of an alkene or by the acid-catalyzed addition of H2O to an alkene is to be predicted.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

The basic difference between hydroboration-oxidation and acid catalyzed reaction is that in hydroboration-oxidation reactions, the attack of hydroxyl group is on the less substituted carbon, whereas in acid catalyzed reaction, the attack of hydroxyl group is on the more substituted carbon.

Answer 14

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Ch. 10 - Prob. 10.1P Ch. 10 - Problem 10.2 How many degrees of unsaturation are...Ch. 10 - Problem 10.3 How many degrees of unsaturation...Ch. 10 - Give the IUPAC name for each alkene. abcde Ch. 10 - Give the IUPAC name for each polyfunctional...Ch. 10 - Problem 10.6 Label each C-C double bond as E or Z....Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Problem 10.10 Rank the following isomers in order...

Solution Summary: The author explains the basic difference between hydroboration-oxidation and acid catalyzed reaction, which involves conversion of alkene into alcohol.

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