(a) Interpretation: The diastereomers of oct − 4 − ene that yields a mixture of two enantiomers on reaction with Br 2 is to be stated. Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

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Answer 1

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Chapter 10, Problem 10.54P

Interpretation Introduction

(a)

Interpretation: The diastereomers of oct−4−ene that yields a mixture of two enantiomers on reaction with Br2 is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

Interpretation Introduction

(b)

Interpretation: The diastereomers of oct−4−ene that yields a single meso compound, (4R,5S)−4,5−dibromooctane is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

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Answer 2

Question

Chapter 10, Problem 10.54P

Interpretation Introduction

(a)

Interpretation: The diastereomers of oct−4−ene that yields a mixture of two enantiomers on reaction with Br2 is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

Interpretation Introduction

(b)

Interpretation: The diastereomers of oct−4−ene that yields a single meso compound, (4R,5S)−4,5−dibromooctane is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

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Answer 3

Question

Chapter 10, Problem 10.54P

Interpretation Introduction

(a)

Interpretation: The diastereomers of oct−4−ene that yields a mixture of two enantiomers on reaction with Br2 is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

Interpretation Introduction

(b)

Interpretation: The diastereomers of oct−4−ene that yields a single meso compound, (4R,5S)−4,5−dibromooctane is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

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Answer 4

Question

Chapter 10, Problem 10.54P

Interpretation Introduction

(a)

Interpretation: The diastereomers of oct−4−ene that yields a mixture of two enantiomers on reaction with Br2 is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

Interpretation Introduction

(b)

Interpretation: The diastereomers of oct−4−ene that yields a single meso compound, (4R,5S)−4,5−dibromooctane is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

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Answer 5

Chapter 10, Problem 10.54P

Interpretation Introduction

(a)

Interpretation: The diastereomers of oct−4−ene that yields a mixture of two enantiomers on reaction with Br2 is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

Interpretation Introduction

(b)

Interpretation: The diastereomers of oct−4−ene that yields a single meso compound, (4R,5S)−4,5−dibromooctane is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

Answer 6

Chapter 10, Problem 10.54P

Interpretation Introduction

(a)

Interpretation: The diastereomers of oct−4−ene that yields a mixture of two enantiomers on reaction with Br2 is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

Answer 7

Chapter 10, Problem 10.54P

Interpretation Introduction

(a)

Interpretation: The diastereomers of oct−4−ene that yields a mixture of two enantiomers on reaction with Br2 is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

Answer 8

Interpretation Introduction

(b)

Interpretation: The diastereomers of oct−4−ene that yields a single meso compound, (4R,5S)−4,5−dibromooctane is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

Answer 9

Interpretation Introduction

(b)

Interpretation: The diastereomers of oct−4−ene that yields a single meso compound, (4R,5S)−4,5−dibromooctane is to be stated.

Concept introduction: The addition of Halogens to alkenes is a stereospecific reaction. The resultant product is meso compound, if alkene is cis and addition of halogen is syn addition. If addition of halogen is anti, then the resultant products are racemic mixture. In case of trans alkene, the resultant product is meso, if addition of halogen is anti. The resultant products are racemic mixture, if the addition of halogen is syn.

Answer 10

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Answer 13

Ch. 10 - Prob. 10.1P Ch. 10 - Problem 10.2 How many degrees of unsaturation are...Ch. 10 - Problem 10.3 How many degrees of unsaturation...Ch. 10 - Give the IUPAC name for each alkene. abcde Ch. 10 - Give the IUPAC name for each polyfunctional...Ch. 10 - Problem 10.6 Label each C-C double bond as E or Z....Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Problem 10.10 Rank the following isomers in order...

Solution Summary: The author explains that the addition of Halogens to alkenes is a stereospecific reaction.

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