Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 1, Problem 88QRT
Interpretation Introduction
Interpretation:
Ten elements
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 1 Solutions
Chemistry: The Molecular Science
Ch. 1.4 - Temperature
Determine which temperature is higher,...Ch. 1.4 - Prob. 1.2CECh. 1.4 - Identify each physical property and physical...Ch. 1.5 - SI Units and Prefixes
Show mathematically that 1...Ch. 1.5 - Prob. 1.5ECh. 1.5 - Calculate the volume occupied by a 4.33-g sample...Ch. 1.6 - Identify the chemical and physical changes that...Ch. 1.8 - Prob. 1.2PSPCh. 1.8 - Prob. 1.7ECh. 1.9 - Prob. 1.8CE
Ch. 1.11 - Draw a nanoscale representation and a symbolic...Ch. 1.13 - Prob. 1.9ECh. 1.13 - Prob. 1.10ECh. 1.13 - Prob. 1.11ECh. 1.13 - Prob. 1.12ECh. 1.14 - Prob. 1.13ECh. 1 - Prob. 1QRTCh. 1 - Choose an object in your room, such as a cell...Ch. 1 - Prob. 3QRTCh. 1 - Prob. 4QRTCh. 1 - Prob. 5QRTCh. 1 - Prob. 6QRTCh. 1 - Which of these statements are qualitative? Which...Ch. 1 - Which of the these statements are qualitative?...Ch. 1 - The elements sulfur and bromine are shown in the...Ch. 1 - In the accompanying photo, you see a crystal of...Ch. 1 - Prob. 13QRTCh. 1 - Prob. 14QRTCh. 1 - Prob. 15QRTCh. 1 - Suppose a room is 18 m long, 15 m wide, and the...Ch. 1 - Prob. 17QRTCh. 1 - Prob. 18QRTCh. 1 - Prob. 19QRTCh. 1 - Prob. 20QRTCh. 1 - Perform these calculations and express the result...Ch. 1 - Prob. 22QRTCh. 1 - A 105.5-g sample of a metal was placed into water...Ch. 1 - Prob. 24QRTCh. 1 - An unknown sample of a metal is 1.0 cm thick, 2.0...Ch. 1 - Calculate the volume of a 23.4-g sample of...Ch. 1 - Calculate the mass of a sodium chloride crystal if...Ch. 1 - Calculate the volume occupied by a 4.33-g sample...Ch. 1 - In each case, identify the italicized property as...Ch. 1 - Prob. 30QRTCh. 1 - In each case, describe the change as a chemical or...Ch. 1 - In each case, describe the change as a chemical or...Ch. 1 - Prob. 33QRTCh. 1 - Prob. 34QRTCh. 1 - Prob. 35QRTCh. 1 - Identify each of these as a homogeneous or a...Ch. 1 - Devise and describe an experiment to (a) Separate...Ch. 1 - Prob. 38QRTCh. 1 - For each of the changes described, decide whether...Ch. 1 - For each of the changes described, decide whether...Ch. 1 - Classify each of these as an element, a compound,...Ch. 1 - Prob. 42QRTCh. 1 - Prob. 43QRTCh. 1 - Prob. 44QRTCh. 1 - Prob. 45QRTCh. 1 - Prob. 46QRTCh. 1 - Prob. 47QRTCh. 1 - Prob. 48QRTCh. 1 - Prob. 49QRTCh. 1 - Prob. 50QRTCh. 1 - Prob. 51QRTCh. 1 - Prob. 52QRTCh. 1 - Prob. 53QRTCh. 1 - Prob. 54QRTCh. 1 - Write a chemical formula for each substance, and...Ch. 1 - Prob. 56QRTCh. 1 - Prob. 57QRTCh. 1 - Prob. 58QRTCh. 1 - Prob. 59QRTCh. 1 - Prob. 60QRTCh. 1 - Prob. 61QRTCh. 1 - Prob. 62QRTCh. 1 - Name and give symbols for three transition metals...Ch. 1 - Name two halogens. Look up each of your choices in...Ch. 1 - Prob. 65QRTCh. 1 - Prob. 66QRTCh. 1 - Prob. 67QRTCh. 1 - Prob. 68QRTCh. 1 - Prob. 69QRTCh. 1 - Prob. 70QRTCh. 1 - Prob. 71QRTCh. 1 - Prob. 72QRTCh. 1 - Prob. 73QRTCh. 1 - Prob. 74QRTCh. 1 - Prob. 75QRTCh. 1 - Prob. 76QRTCh. 1 - The label on a bale of mulch indicates a volume of...Ch. 1 - Prob. 78QRTCh. 1 - Prob. 79QRTCh. 1 - The cancer drug cisplatin contains 65.0% platinum....Ch. 1 - Prob. 81QRTCh. 1 - The density of gaseous helium at 25 C and normal...Ch. 1 - Prob. 83QRTCh. 1 - Prob. 84QRTCh. 1 - Prob. 85QRTCh. 1 - You can figure out whether a substance floats or...Ch. 1 - Prob. 87QRTCh. 1 - Prob. 88QRTCh. 1 - Prob. 89QRTCh. 1 - Prob. 90QRTCh. 1 - Prob. 91QRTCh. 1 - Which two elements from this list exhibit the...Ch. 1 - Prob. 93QRTCh. 1 - Prob. 94QRTCh. 1 - Prob. 95QRTCh. 1 - Prob. 96QRTCh. 1 - Prob. 97QRTCh. 1 - Prob. 98QRTCh. 1 - Prob. 99QRTCh. 1 - Using Table 1.1, but without using your...Ch. 1 - Prob. 101QRTCh. 1 - At 25 C the density of water is 0.997 g/mL,...Ch. 1 - Prob. 103QRTCh. 1 - Prob. 104QRTCh. 1 - Prob. 105QRTCh. 1 - Prob. 106QRTCh. 1 - Answer these questions using figures (a) through...Ch. 1 - Prob. 108QRTCh. 1 - Prob. 109QRTCh. 1 - Prob. 110QRTCh. 1 - Prob. 111QRTCh. 1 - Prob. 112QRTCh. 1 - Prob. 113QRTCh. 1 - Prob. 114QRTCh. 1 - Prob. 115QRTCh. 1 - Prob. 116QRTCh. 1 - Prob. 118QRTCh. 1 - Prob. 119QRTCh. 1 - Prob. 120QRTCh. 1 - Prob. 121QRTCh. 1 - Prob. 122QRTCh. 1 - The element magnesium reacts with the element...Ch. 1 - Prob. 124QRTCh. 1 - Prob. 125QRTCh. 1 - When 12.6 g calcium carbonate (the principal...Ch. 1 - Prob. 127QRTCh. 1 - Suppose you are trying to get lemon juice and you...Ch. 1 - Prob. 1.BCPCh. 1 - Prob. 1.CCPCh. 1 - Prob. 1.DCPCh. 1 - Prob. 1.ECPCh. 1 - Some scientists think there are living things...Ch. 1 - Prob. 1.GCPCh. 1 - Prob. 1.HCP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
- Part V. Choose which isomer would give the 1H-NMR spectrum below. Justify your reasoning by assigning important signals to the Corresponding protons of the correct molecule. A D on of of of H H 88 2 90 7.8 7.6 7.4 80 5 6 [ppm] 7.2 6.8 6.6 6.4 ō [ppm]arrow_forwardShow work with explanation. don't give Ai generated solutionarrow_forwardQ7. a. Draw the line-bond structure of the major product for the following reaction, if a reaction occurs, assume monohalogenation. b. Calculate the product ratios using the following information (hint: use the number of hydrogens in each category present to calculate the ratios). Chlorination: 1° Reactivity=1 2° Reactivity=4 Heat + Cl2 3° Reactivity=5arrow_forward
- Please correct answer and don't use hand rating and don't use Ai solutionarrow_forwardQ10: Alkane halogenation a. Give the name and structures of the five isomeric hexanes. Page 4 of 5 Chem 0310 Organic Chemistry 1 Recitations b. For each isomer, give all the free radical monochlorination and monobromination products that are structurally isomeric.arrow_forwardQ9. The insecticide DDT (in the box below) is useful in controlling mosquito populations and has low toxicity to humans, but is dangerous to birds and fish. Hoping to alleviate the dangers, little Johnny Whizbang, an aspiring chemist, proposes a new version of DDT ("Bromo-DDT") and shows his synthesis to his boss. Will Johnny Whizbang's synthesis work? Or will he be fired? Assume there is an excess of bromine and polybrominated products can be separated. Explain why. CH3 Br2, light CBR3 ok-ok Br Br Br Br CI "Bromo-DDT" CCl 3 DDT (dichlorodiphenyltrichloroethane) CIarrow_forward
- Differentiate the terms Monotectic, Eutectic, Eutectoid, Peritectic, Peritectoid.arrow_forwardQ5. Predict the organic product(s) for the following transformations. If no reaction will take place (or the reaction is not synthetically useful), write "N.R.". Determine what type of transition state is present for each reaction (think Hammond Postulate). I Br₂ CH3 F2, light CH3 Heat CH3 F₂ Heat Br2, light 12, light CH3 Cl2, lightarrow_forwarda. For the following indicated bonds, rank them in order of decreasing AH° for homolytic cleavage. Based on your answer, which bond would be most likely to break homolytically? (a) (c) H3C CH3 .CH3 CH3 CH3 (b) Page 1 of 5 Chem 0310 Organic Chemistry 1 Recitations b. Draw all the possible radical products for 2-methylbutane, and determine which bond is most likely to be broken.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
- Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Types of Matter: Elements, Compounds and Mixtures; Author: Professor Dave Explains;https://www.youtube.com/watch?v=dggHWvFJ8Xs;License: Standard YouTube License, CC-BY