Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 1, Problem 4QRT
Interpretation Introduction
Interpretation:
The way in which scientific theory differs from law has to be explained. Also, the relation between model and theories has to be given.
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6. The equilibrium constant for the reaction
2 HBr (g)
→ H2(g) + Br2(g)
Can be expressed by the empirical formula
11790 K
In K-6.375 + 0.6415 In(T K-¹)
-
T
Use this formula to determine A,H as a function of temperature. Calculate A,-H at 25 °C and at
100 °C.
3. Nitrosyl chloride, NOCI, decomposes according to
2 NOCI (g) → 2 NO(g)
+ Cl2(g)
Assuming that we start with no moles of NOCl (g) and no NO(g) or Cl2(g), derive an expression
for Kp in terms of the equilibrium value of the extent of reaction, Seq, and the pressure, P.
Given that K₂ = 2.00 × 10-4, calculate Seq/
of
29/no when P = 0.080 bar. What is the new value
по
ƒª/ at equilibrium when P = 0.160 bar? Is this result in accord with Le Châtelier's
Principle?
Consider the following chemical equilibrium:
2SO2(g) + O2(g) = 2SO3(g)
•
Write the equilibrium constant expression for this reaction.
Now compare it to the equilibrium constant expression for the related reaction:
•
.
1
SO2(g) + O2(g) = SO3(g)
2
How do these two equilibrium expressions differ?
What important principle about the dependence of equilibrium constants on the stoichiometry of a
reaction can you learn from this comparison?
Chapter 1 Solutions
Chemistry: The Molecular Science
Ch. 1.4 - Temperature
Determine which temperature is higher,...Ch. 1.4 - Prob. 1.2CECh. 1.4 - Identify each physical property and physical...Ch. 1.5 - SI Units and Prefixes
Show mathematically that 1...Ch. 1.5 - Prob. 1.5ECh. 1.5 - Calculate the volume occupied by a 4.33-g sample...Ch. 1.6 - Identify the chemical and physical changes that...Ch. 1.8 - Prob. 1.2PSPCh. 1.8 - Prob. 1.7ECh. 1.9 - Prob. 1.8CE
Ch. 1.11 - Draw a nanoscale representation and a symbolic...Ch. 1.13 - Prob. 1.9ECh. 1.13 - Prob. 1.10ECh. 1.13 - Prob. 1.11ECh. 1.13 - Prob. 1.12ECh. 1.14 - Prob. 1.13ECh. 1 - Prob. 1QRTCh. 1 - Choose an object in your room, such as a cell...Ch. 1 - Prob. 3QRTCh. 1 - Prob. 4QRTCh. 1 - Prob. 5QRTCh. 1 - Prob. 6QRTCh. 1 - Which of these statements are qualitative? Which...Ch. 1 - Which of the these statements are qualitative?...Ch. 1 - The elements sulfur and bromine are shown in the...Ch. 1 - In the accompanying photo, you see a crystal of...Ch. 1 - Prob. 13QRTCh. 1 - Prob. 14QRTCh. 1 - Prob. 15QRTCh. 1 - Suppose a room is 18 m long, 15 m wide, and the...Ch. 1 - Prob. 17QRTCh. 1 - Prob. 18QRTCh. 1 - Prob. 19QRTCh. 1 - Prob. 20QRTCh. 1 - Perform these calculations and express the result...Ch. 1 - Prob. 22QRTCh. 1 - A 105.5-g sample of a metal was placed into water...Ch. 1 - Prob. 24QRTCh. 1 - An unknown sample of a metal is 1.0 cm thick, 2.0...Ch. 1 - Calculate the volume of a 23.4-g sample of...Ch. 1 - Calculate the mass of a sodium chloride crystal if...Ch. 1 - Calculate the volume occupied by a 4.33-g sample...Ch. 1 - In each case, identify the italicized property as...Ch. 1 - Prob. 30QRTCh. 1 - In each case, describe the change as a chemical or...Ch. 1 - In each case, describe the change as a chemical or...Ch. 1 - Prob. 33QRTCh. 1 - Prob. 34QRTCh. 1 - Prob. 35QRTCh. 1 - Identify each of these as a homogeneous or a...Ch. 1 - Devise and describe an experiment to (a) Separate...Ch. 1 - Prob. 38QRTCh. 1 - For each of the changes described, decide whether...Ch. 1 - For each of the changes described, decide whether...Ch. 1 - Classify each of these as an element, a compound,...Ch. 1 - Prob. 42QRTCh. 1 - Prob. 43QRTCh. 1 - Prob. 44QRTCh. 1 - Prob. 45QRTCh. 1 - Prob. 46QRTCh. 1 - Prob. 47QRTCh. 1 - Prob. 48QRTCh. 1 - Prob. 49QRTCh. 1 - Prob. 50QRTCh. 1 - Prob. 51QRTCh. 1 - Prob. 52QRTCh. 1 - Prob. 53QRTCh. 1 - Prob. 54QRTCh. 1 - Write a chemical formula for each substance, and...Ch. 1 - Prob. 56QRTCh. 1 - Prob. 57QRTCh. 1 - Prob. 58QRTCh. 1 - Prob. 59QRTCh. 1 - Prob. 60QRTCh. 1 - Prob. 61QRTCh. 1 - Prob. 62QRTCh. 1 - Name and give symbols for three transition metals...Ch. 1 - Name two halogens. Look up each of your choices in...Ch. 1 - Prob. 65QRTCh. 1 - Prob. 66QRTCh. 1 - Prob. 67QRTCh. 1 - Prob. 68QRTCh. 1 - Prob. 69QRTCh. 1 - Prob. 70QRTCh. 1 - Prob. 71QRTCh. 1 - Prob. 72QRTCh. 1 - Prob. 73QRTCh. 1 - Prob. 74QRTCh. 1 - Prob. 75QRTCh. 1 - Prob. 76QRTCh. 1 - The label on a bale of mulch indicates a volume of...Ch. 1 - Prob. 78QRTCh. 1 - Prob. 79QRTCh. 1 - The cancer drug cisplatin contains 65.0% platinum....Ch. 1 - Prob. 81QRTCh. 1 - The density of gaseous helium at 25 C and normal...Ch. 1 - Prob. 83QRTCh. 1 - Prob. 84QRTCh. 1 - Prob. 85QRTCh. 1 - You can figure out whether a substance floats or...Ch. 1 - Prob. 87QRTCh. 1 - Prob. 88QRTCh. 1 - Prob. 89QRTCh. 1 - Prob. 90QRTCh. 1 - Prob. 91QRTCh. 1 - Which two elements from this list exhibit the...Ch. 1 - Prob. 93QRTCh. 1 - Prob. 94QRTCh. 1 - Prob. 95QRTCh. 1 - Prob. 96QRTCh. 1 - Prob. 97QRTCh. 1 - Prob. 98QRTCh. 1 - Prob. 99QRTCh. 1 - Using Table 1.1, but without using your...Ch. 1 - Prob. 101QRTCh. 1 - At 25 C the density of water is 0.997 g/mL,...Ch. 1 - Prob. 103QRTCh. 1 - Prob. 104QRTCh. 1 - Prob. 105QRTCh. 1 - Prob. 106QRTCh. 1 - Answer these questions using figures (a) through...Ch. 1 - Prob. 108QRTCh. 1 - Prob. 109QRTCh. 1 - Prob. 110QRTCh. 1 - Prob. 111QRTCh. 1 - Prob. 112QRTCh. 1 - Prob. 113QRTCh. 1 - Prob. 114QRTCh. 1 - Prob. 115QRTCh. 1 - Prob. 116QRTCh. 1 - Prob. 118QRTCh. 1 - Prob. 119QRTCh. 1 - Prob. 120QRTCh. 1 - Prob. 121QRTCh. 1 - Prob. 122QRTCh. 1 - The element magnesium reacts with the element...Ch. 1 - Prob. 124QRTCh. 1 - Prob. 125QRTCh. 1 - When 12.6 g calcium carbonate (the principal...Ch. 1 - Prob. 127QRTCh. 1 - Suppose you are trying to get lemon juice and you...Ch. 1 - Prob. 1.BCPCh. 1 - Prob. 1.CCPCh. 1 - Prob. 1.DCPCh. 1 - Prob. 1.ECPCh. 1 - Some scientists think there are living things...Ch. 1 - Prob. 1.GCPCh. 1 - Prob. 1.HCP
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