ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
12th Edition
ISBN: 9781119664635
Author: Solomons
Publisher: WILEY
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Chapter 1, Problem 7LGP
Interpretation Introduction
Interpretation: Abond line formula for the given compound is to be drawn.
Concept Introduction:
For drawing bond line formulae, the following rules are followed:
A bond is represented by a line.
Each bends in a line indicate carbon atoms, unless any other group is shown specifically.
The number of hydrogen atoms bonded to each carbon is equal to the remaining valency of carbon.
Any element other than carbon or hydrogen is indicated by its symbol.
The hydrogen atoms bonded to elements other than carbon are shown by writing the symbol.
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Draw a bond line structure for this condensed structure
(CH3)3CCH2CH(OH)CH2CONH2
I have given you a condensed structure. You need to convert it to an accurate bond-line
structure.
CH3
CH3-CH-CH2-CH-CH₂-C-H
12-CH-CH2₂-C-1
CI
Draw (as bond-line structures) isomers of this compound where you only move the chlorine
atom.
Draw four isomers of the original compound that would have a five carbon chain as the longest
chain. [Note: there would be many isomers that will satisfy this. Find any four.]
Using the original molecule (and looking at the carbon next to the aldehyde carbonyl) what
would be the charge on that carbon if I removed an H atom and left behind the pair of electrons?
Circle the best answer
Positive
Negative
Neutral
In the space below, draw that structure (from the sentence above) as a bond-line structure. Then,
draw a resonance structure for this ion and be sure to add curved arrows to show the movement
of electrons.
Structure and Bonding
Interpreting condensed chemical structures
Use this condensed chemical structure to complete the table below.
O
CH2=CH-C-H
The condensed chemical structure of acrolein
Some facts about the acrolein molecule:
number of carbon-carbon single (CC) bonds:
number of carbon-hydrogen single (CH) bonds:
number of lone pairs:
Chapter 1 Solutions
ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
Ch. 1 - Prob. 1PPCh. 1 - Prob. 2PPCh. 1 - Prob. 3PPCh. 1 - Prob. 4PPCh. 1 - Prob. 5PPCh. 1 - Prob. 6PPCh. 1 - Prob. 7PPCh. 1 - Prob. 8PPCh. 1 - Prob. 9PPCh. 1 - Prob. 10PP
Ch. 1 - Prob. 11PPCh. 1 - Prob. 12PPCh. 1 - Prob. 13PPCh. 1 - Prob. 14PPCh. 1 - Prob. 15PPCh. 1 - Prob. 16PPCh. 1 - Prob. 17PPCh. 1 - Prob. 18PPCh. 1 - Prob. 19PPCh. 1 - Prob. 20PPCh. 1 - Prob. 21PPCh. 1 - Practice Problem 1.22 Which of the following...Ch. 1 - Prob. 23PPCh. 1 - Prob. 24PPCh. 1 - Practice Problem 1.25
What do the bond angles of...Ch. 1 - Prob. 26PPCh. 1 - Practice Problem 1.27
Use VSEPR theory to predict...Ch. 1 - Practice Problem 1.28 Predict the bond angles of...Ch. 1 - 1.29 Which of the following ions possess the...Ch. 1 - 1.30 Write a Lewis structure for each of the...Ch. 1 - Prob. 31PCh. 1 - Add any unshared electrons to give each element an...Ch. 1 - Prob. 33PCh. 1 - What is the molecular formula for each of the...Ch. 1 - Prob. 35PCh. 1 - Prob. 36PCh. 1 - 1.37 Write bond-line formulas for all of the...Ch. 1 - Prob. 38PCh. 1 - Prob. 39PCh. 1 - Prob. 40PCh. 1 - Prob. 41PCh. 1 - (a) Cyanic acid (HOCN) and isocyanic acid (HN=C=O)...Ch. 1 - Consider a chemical species (either a molecule or...Ch. 1 - 1.44 Consider a chemical species like the one in...Ch. 1 - 1.45 Consider another chemical species like the...Ch. 1 - Draw a three-dimensional orbital representation...Ch. 1 - Ozone (O3) is found in the upper atmosphere where...Ch. 1 - Write resonance structures for the azide ion, N3....Ch. 1 - Write structural formulas of the type indicated:...Ch. 1 - Prob. 50PCh. 1 - 1.51 In Chapter 15 we shall learn how the...Ch. 1 - Prob. 52PCh. 1 - (a) Consider a carbon atom in its ground state....Ch. 1 - Open computer molecular models for dimethyl ether,...Ch. 1 - Boron is a group IIIA element. Open the molecular...Ch. 1 - 1.56 There are two contributing resonance...Ch. 1 - Prob. 1LGPCh. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Prob. 7LGPCh. 1 - Prob. 8LGP
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