Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 1, Problem 67P
Interpretation Introduction
Interpretation: The specific gravity of urine needs to be determined. It is to be explained if it is considered normal or not.
Concept Introduction: The specific gravity is defined as the ration of density of a substance to density of water.
The density is calculated as follows:
Here, m is mass and V is volume.
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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10
Consider the following reaction:
CH3OH(g)
CO(g) + 2H2(g)
(Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.)
Part A
Calculate AG for this reaction at 25 °C under the following conditions:
PCH₂OH
Pco
PH2
0.815 atm
=
0.140 atm
0.170 atm
Express your answer in kilojoules to three significant figures.
Ο ΑΣΦ
AG = -150
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kJ
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Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship:
AGrxn = AGrxn + RTInQ,
AGxn+RTInQ,
where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a
is the reaction quotient.
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Chapter 1 Solutions
Introduction to General, Organic and Biochemistry
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Ch. 1 - 1-15 In a newspaper, you read that Dr. X claimed...Ch. 1 - Prob. 4PCh. 1 - 1-17 Write in exponential notation: (a) 0.351 (b)...Ch. 1 - 1-18 Write out in full: (a) 4.03 × l05 (b) 3.2 ×...Ch. 1 - 1-19 Multiply: (a) (2.16 × 105) (3.08 × 1012) (b)...Ch. 1 - Prob. 8PCh. 1 - Prob. 9PCh. 1 - Prob. 10PCh. 1 - Prob. 11PCh. 1 - Prob. 12PCh. 1 - 1-25 How many significant figures are in the...Ch. 1 - 1-26 How many significant figures are in the...Ch. 1 - 1-27 Round off to two significant figures: (a)...Ch. 1 - 1-28 Multiply these numbers, using the correct...Ch. 1 - 1.29 Divide these numbers, using the correct...Ch. 1 - 1-30 Add these groups of measured numbers using...Ch. 1 - 1-31 In the SI system, the second is the base unit...Ch. 1 - 1-32 How many grams are in the following? (a)1 kg...Ch. 1 - 1-33 Estimate without actually calculating which...Ch. 1 - Prob. 22PCh. 1 - 1-35 You are taken for a helicopter ride in Hawaii...Ch. 1 - Prob. 24PCh. 1 - Prob. 25PCh. 1 - 1-38 Make the following conversions (conversion...Ch. 1 - 1.39 Make the following metric conversions: (a)964...Ch. 1 - There are two bottles of cough syrup available on...Ch. 1 - 1-41 A humidifier located at a nursing station...Ch. 1 - 1-42 You drive in Canada where the distances are...Ch. 1 - 1-43 The speed limit in some European cities is 80...Ch. 1 - 1-44 Your car gets 25.00 miles on a gallon of gas....Ch. 1 - 145 Children’s Chewable Tylenol contains 80. mg of...Ch. 1 - 1-46 A patient weighs 186 lbs. She must receive an...Ch. 1 - 1-47 The doctor orders administration of a drug at...Ch. 1 - 1-48 The recommended pediatric dosage of Velosef...Ch. 1 - 1-49 A critical care physician prescribes an IV of...Ch. 1 - 1-50 If an IV is mixed so that each 150 mL...Ch. 1 - 1-51 A nurse practitioner orders isotonic sodium...Ch. 1 - 1-52 An order for a patient reads Give 40. mg of...Ch. 1 - Prob. 41PCh. 1 - Prob. 42PCh. 1 - 1-55 Does the chemical nature of a substance...Ch. 1 - 1-56 The volume of a rock weighing 1.075 kg is...Ch. 1 - 1-57 The density of manganese is 7.21 g/mL, that...Ch. 1 - 1.58 The density of titanium is 4.54 g/mL. What is...Ch. 1 - 1-59 An injection of 4 mg of Valium has been...Ch. 1 - 1-60 The density of methanol at 20oC is 0.791...Ch. 1 - 1-61 The density of dichloromethane, a liquid...Ch. 1 - 1-62 A sample of 10.00 g of oxygen has a volume of...Ch. 1 - Prob. 51PCh. 1 - Prob. 52PCh. 1 - 1-65 While you drive your car, your battery is...Ch. 1 - Prob. 54PCh. 1 - 1-70 (Chemical Connections IA) The average lethal...Ch. 1 - Prob. 56PCh. 1 - 1-75 A brain weighing 1.0 lb occupies a volume of...Ch. 1 - 1-76 If the density of air is 1.25 10-3 g/cc,...Ch. 1 - 1-77 Classify these as kinetic or potential...Ch. 1 - 1-78 The kinetic energy possessed by an object...Ch. 1 - 1-79 A European car advertises an efficiency of 22...Ch. 1 - Prob. 62PCh. 1 - Prob. 63PCh. 1 - Prob. 64PCh. 1 - Prob. 65PCh. 1 - Prob. 66PCh. 1 - Prob. 67PCh. 1 - Prob. 68PCh. 1 - 1-82 When the astronauts walked on the Moon, they...Ch. 1 - 1-83 Which of the following is the largest mass...Ch. 1 - 1-84 Which quantity is bigger in each of the...Ch. 1 - 1-85 In Japan, high-speed “bullet trains” move...Ch. 1 - 1-88 One quart of milk costs 80 cents and one...Ch. 1 - 1-89 Consider butter, density 0.860 g/mL, and...Ch. 1 - 1-90 Which speed is the fastest? (a) 70 mi/h (b)...Ch. 1 - 1-95 You receive an order for 60. mg of meperidine...Ch. 1 - Prob. 77PCh. 1 - Prob. 78PCh. 1 - Prob. 79PCh. 1 - Prob. 80PCh. 1 - Prob. 81PCh. 1 - Prob. 82PCh. 1 - Prob. 83PCh. 1 - Prob. 84PCh. 1 - 1-111 In the hospital, your doctor orders 100. mg...Ch. 1 - 1-112 A febrile, pediatric patient weighs 42...
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