
(a)
Interpretation:
To find which two compounds are constitutional isomers of the given three structures
Concept introduction:
Constitutional isomers are the compounds which have same molecular formula but differ in connectivity between the atoms present in it.
The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound. This mixing of hybrid orbitals is known as hybridization. The hybridization determines the geometry of the particular atom in the compound. Shortly to say
trigonal pyramidal(if one lone pair of electron is present)
bent geometry (if two lone pair of electrons are present)
To find:
Constitutional isomers in the given three compounds.
(b)
Interpretation:
To find which compound has nitrogen in trigonal pyramidal geometry
Concept introduction:
A bond is formed by sharing of valence electrons. A
To identify: Which compound has nitrogen atom with trigonal pyramidal geometry.
(c)
Interpretation:
To find which two compounds are constitutional isomers of the given three structures
Concept introduction:
A bond is formed by sharing of valence electrons. A
To identify: Which compound has larger number of
(d)
Interpretation:
To find which two compounds are constitutional isomers of the given three structures
Concept introduction:
A bond is formed by sharing of valence electrons. A
To identify: Which compound has lesser number of
(e)
Interpretation:
To find which two compounds are constitutional isomers of the given three structures
Concept introduction:
The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound. This mixing of hybrid orbitals is known as hybridization. The hybridization determines the geometry of the particular atom in the compound. Shortly to say
trigonal pyramidal(if one lone pair of electron is present)
bent geometry (if two lone pair of electrons are present)
To identify: Which compound has more number of
(f)
Interpretation:
To find which two compounds are constitutional isomers of the given three structures
Concept introduction:
The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound. This mixing of hybrid orbitals is known as hybridization. The hybridization determines the geometry of the particular atom in the compound. Shortly to say
trigonal pyramidal(if one lone pair of electron is present)
bent geometry (if two lone pair of electrons are present)
To identify: Which compound has carbon atom with
(g)
Interpretation:
To find which two compounds are constitutional isomers of the given three structures
Concept introduction:
Boiling point of a compound is the temperature at which the compound start to escape into vapor phase from liquid state when temperature is raised. The total number of carbon atoms determines the boiling point of the compound.
To identify: Which compound has all atoms with
(h)
Interpretation:
To find which two compounds are constitutional isomers of the given three structures
To identify: Which compound has high boiling point.

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Chapter 1 Solutions
Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
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