Chemistry for Changing Times
Chemistry for Changing Times
14th Edition
ISBN: 9780134212777
Author: John W. Hill; Terry W. McCreary
Publisher: Pearson Education (US)
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Chapter 1, Problem 3CGP
Interpretation Introduction

Interpretation:

Compare the word in the last column with that in the first column. Discuss any differences in the two definitions. If the word in the last column differs from that in the first column, determine what went wrong in the process.

  1. Hypothesis
  2. Theory
  3. Mixture
  4. Substance.

    Text Entry
    Student 1
    Student 2
    Student 3
    Student 4
    Word
    Definition
    Word
    Definition
    Word
     
     
     
     

Concept Introduction:

A tentative explanation of observed data is known as a hypothesis.
The theory is a set of principles that predict and explain phenomena.
A material system made up of two or more different substances which are mixed but are not combined chemically is said to be a mixture.
Substances are those that can't be broken down into simpler substances.

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2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**
11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

Chapter 1 Solutions

Chemistry for Changing Times

Ch. 1 - Prob. 11RQCh. 1 - Identify the following work as either applied...Ch. 1 - Penicillin kills bacteria, thus saving the lives...Ch. 1 - Prob. 14PCh. 1 - Prob. 15PCh. 1 - X-rays are widely used in medicine and dentistry....Ch. 1 - Prob. 17PCh. 1 - The virus called HIV causes AIDS, a devastating...Ch. 1 - Which are realistic masses for a cellular...Ch. 1 - In Europe, A2 sized paper measures 594 mm 420 mm,...Ch. 1 - Which one(s) of the following are likely to be...Ch. 1 - Sample X on the moon has exactly the same mass as...Ch. 1 - Which of the following is a reasonable volume for...Ch. 1 - Which of the following is a reasonable...Ch. 1 - Earth's oceans contain 3.501 0 8 mi3 of water and...Ch. 1 - What is the area of Earth's oceans in square...Ch. 1 - Consider the two tubes shown below. The aluminum...Ch. 1 - Which one(s) of the following could be the inside...Ch. 1 - Identify the following as physical or chemical...Ch. 1 - Identify the following as physical or chemical...Ch. 1 - Identify the following changes as physical or...Ch. 1 - Identify the following changes as physical or...Ch. 1 - Identify each of the following as a substance or a...Ch. 1 - Identify each of the following as a substance or a...Ch. 1 - Which of the following mixtures are homogeneous,...Ch. 1 - Which of the following mixtures are homogeneous,...Ch. 1 - Every sample of the sugar glucose (no matter where...Ch. 1 - An advertisement for shampoo says, "Pure shampoo,...Ch. 1 - Which of the following represent elements, and...Ch. 1 - Prob. 40PCh. 1 - Prob. 41PCh. 1 - Without consulting tables, write a symbol for each...Ch. 1 - In his 1739 textbook, Traite elementaire de...Ch. 1 - In 1774 Joseph Priestley isolated a gas that he...Ch. 1 - Change the unit for each of the following...Ch. 1 - Convert each of the following measurements to the...Ch. 1 - Carry out the following conversions. a. 5.52104 mL...Ch. 1 - Carry out the following conversions. a. 546 mm to...Ch. 1 - Indicate which is the larger unit in each pair. a....Ch. 1 - There are about...Ch. 1 - Express the length of a 31 -cm ruler in (a) mm,...Ch. 1 - What is the volume in liters of (a) a 352-mL soft...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - Prob. 61PCh. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - Liquid nitrogen, used for freezing sperm samples,...Ch. 1 - Normal body temperature is about 37 °C. What is...Ch. 1 - Prob. 67PCh. 1 - Prob. 68PCh. 1 - A certain chemistry class is 1.00 microcentury ( ...Ch. 1 - 70. A unit of beauty, a helen, thought to have...Ch. 1 - 71. English chemist William Henry studied the...Ch. 1 - Prob. 72APCh. 1 - Prob. 73APCh. 1 - For Problems 74 and 75t, classify each of the...Ch. 1 - For Problems 74 and 75, classify each of the...Ch. 1 - Prob. 76APCh. 1 - Prob. 77APCh. 1 - Prob. 78APCh. 1 - Prob. 79APCh. 1 - Prob. 80APCh. 1 - Prob. 81APCh. 1 - Prob. 82APCh. 1 - Prob. 83APCh. 1 - Prob. 84APCh. 1 - Prob. 85APCh. 1 - Prob. 86APCh. 1 - The density of a planet can be approximated from...Ch. 1 - The extrasolar planet HAT-P-i orbits a star 450...Ch. 1 - Prob. 89APCh. 1 - Prob. 90APCh. 1 - Prob. 91APCh. 1 - Prob. 92APCh. 1 - Prob. 1.1CTECh. 1 - Prob. 1.2CTECh. 1 - Prob. 1.3CTECh. 1 - Prob. 1.4CTECh. 1 - Prob. 1.5CTECh. 1 - Prob. 1.6CTECh. 1 - Prob. 1CGPCh. 1 - Prob. 2CGPCh. 1 - Prob. 3CGPCh. 1 - Materials Needed: • 1/4 cup dark corn syrup • 1/4...Ch. 1 - Materials Needed: • 1/4 cup dark corn syrup • 1/4...Ch. 1 - Prob. 3CHQCh. 1 - Prob. 4CHQCh. 1 - Materials Needed: • 1/4 cup dark corn syrup • 1/4...
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