EBK BASIC CHEMISTRY
6th Edition
ISBN: 9780134987088
Author: Timberlake
Publisher: PEARSON CO
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Chapter 1, Problem 37UTC
Interpretation Introduction
Interpretation: Whether Sherlock Holmes used scientific method or not should be explained with reference to the statement “One must follow the rules of scientific inquiry, gathering, observing, and testing data, then formulating, modifying, and rejecting hypotheses, until only one remains”.
Concept Introduction:
The scientific method is a process of experimentation used to explore and verify observations and then answer questions related to them.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 1 Solutions
EBK BASIC CHEMISTRY
Ch. 1.1 - In every chapter. odd-numbered exercises in the...Ch. 1.1 - In every chapter. odd-numbered exercises in the...Ch. 1.1 - Prob. 3PPCh. 1.1 - Prob. 4PPCh. 1.1 - In every chapter. odd-numbered exercises in the...Ch. 1.1 - Prob. 6PPCh. 1.2 - Identify each activity, a to f, as an observation,...Ch. 1.2 - Identify each activity, a to f. as an observation,...Ch. 1.2 - Identify each of the following as an observation,...Ch. 1.2 - Identify each of the following as an observation,...
Ch. 1.3 - Prob. 11PPCh. 1.3 - What are four things that would make it difficult...Ch. 1.3 - Prob. 13PPCh. 1.3 - Prob. 14PPCh. 1.4 - What is the place value for the bold digit? a....Ch. 1.4 - What is the place value for the bold digit? a....Ch. 1.4 - Prob. 17PPCh. 1.4 - Prob. 18PPCh. 1.4 - Prob. 19PPCh. 1.4 - Prob. 20PPCh. 1.4 - Use the following graph for problems 1.21 and...Ch. 1.4 - Use the following graph for problems 1.21 and...Ch. 1.4 - a. A clinic had 25 patients on Friday morning....Ch. 1.4 - a. At a local hospital. 35 babies were born in...Ch. 1.4 - Prob. 25PPCh. 1.4 - Prob. 26PPCh. 1.5 - Prob. 27PPCh. 1.5 - Write each of the following in scientific...Ch. 1.5 - Prob. 29PPCh. 1.5 - Write each of the following as a standard number:...Ch. 1.5 - Prob. 31PPCh. 1.5 - Prob. 32PPCh. 1.5 - Prob. 33PPCh. 1.5 - Prob. 34PPCh. 1 - The chapter sections to review are shown in...Ch. 1 - Prob. 36UTCCh. 1 - Prob. 37UTCCh. 1 - Prob. 38UTCCh. 1 - Prob. 39UTCCh. 1 - Prob. 40UTCCh. 1 - Prob. 41UTCCh. 1 - Prob. 42UTCCh. 1 - Select the correct phrase(s) to complete the...Ch. 1 - Select the correct phrase(s) to complete the...Ch. 1 - Prob. 45APPCh. 1 - Prob. 46APPCh. 1 - Prob. 47APPCh. 1 - Prob. 48APPCh. 1 - Evaluate each of the following: (1.4)...Ch. 1 - Prob. 50APPCh. 1 - A bag of gumdrops contains 16 orange gumdrops, 8...Ch. 1 - Prob. 52APPCh. 1 - Write each of the following in scientific...Ch. 1 - Write each of the following in scientific...Ch. 1 - Prob. 55APPCh. 1 - Write each of the following as a standard number:...Ch. 1 - Prob. 57APPCh. 1 - Prob. 58APPCh. 1 - Prob. 59CPCh. 1 - Prob. 60CPCh. 1 - Prob. 61CPCh. 1 - The following problems are related to the topics...Ch. 1 - The following problems are related to the topics...Ch. 1 - Prob. 64CP
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