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Chapter 1, Problem 23E

The manufacturer of a particular brand of toothpaste claims that the brand contains “no chemicals.” Using a few grammatically correct English sentences, describe what you think the company means by that statement. Would a scientist consider the manufacturer’s statement to be correct? Why or why not?

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. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavage
Which carbocation is more stable?
Are the products of the given reaction correct?  Why or why not?

Chapter 1 Solutions

Introductory Chemistry Plus MasteringChemistry with eText - Access Card Package (5th Edition) (New Chemistry Titles from Niva Tro)

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