Connect 2-Year Online Access for General, Organic, and Biochemistry
9th Edition
ISBN: 9781259677946
Author: Denniston
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 1, Problem 1.99QP
Interpretation Introduction
Interpretation:
A
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 1 Solutions
Connect 2-Year Online Access for General, Organic, and Biochemistry
Ch. 1.1 - Prob. 1.1PPCh. 1.2 - Is each of the following materials a pure...Ch. 1.2 - Intravenous therapy may be used to introduce a...Ch. 1.2 - Cloudy urine can be a symptom of a bladder...Ch. 1.2 - Classify each of the following as either a...Ch. 1.2 - Prob. 1.3QCh. 1.2 - Prob. 1.4QCh. 1.2 - Prob. 1.4PPCh. 1.2 - Label each property as intensive or extensive:
the...Ch. 1.2 - Label each property as intensive or extensive:
the...
Ch. 1.4 - How many significant figures are contained in each...Ch. 1.4 - Prob. 1.8QCh. 1.4 - Prob. 1.9QCh. 1.4 - Prob. 1.10QCh. 1.4 - Prob. 1.11QCh. 1.4 - Prob. 1.12QCh. 1.4 - Prob. 1.13QCh. 1.4 - Prob. 1.14QCh. 1.4 - Prob. 1.5PPCh. 1.4 - Prob. 1.15QCh. 1.4 - Prob. 1.16QCh. 1.4 - Prob. 1.6PPCh. 1.4 - Prob. 1.17QCh. 1.4 - Prob. 1.18QCh. 1.5 - Convert 360 ft to mi.
Ch. 1.5 - Convert:
750 cm to mm
1.5 × 108 μL to cL
0.00055...Ch. 1.5 - Convert:
0.50 in to m
0.75 qt to L
56.8 g to...Ch. 1.5 - Convert:
1.5 cm2 to m2
3.6 m2 to cm2
Ch. 1.5 - Convert 0.791 g/mL to kg/L.
Ch. 1.6 - The freezing temperature of water is 32°F....Ch. 1.6 - Prob. 1.19QCh. 1.6 - Prob. 1.20QCh. 1.6 - Prob. 1.13PPCh. 1.6 - Prob. 1.14PPCh. 1.6 - Prob. 1.15PPCh. 1.6 - Calculate the volume, in mL, of 10.0 g of a saline...Ch. 1 - Define chemistry and explain how burning wood is...Ch. 1 - Prob. 1.22QPCh. 1 - Why is experimentation an important part of the...Ch. 1 - Prob. 1.24QPCh. 1 - What data would be required to estimate the total...Ch. 1 - What data would be required to estimate the mass...Ch. 1 - What are the characteristics of methane emphasized...Ch. 1 - Discuss the difference between hypothesis and...Ch. 1 - Discuss the difference between theory and...Ch. 1 - We use aspects of the scientific method in our...Ch. 1 - Experimentation has shown that stem cell research...Ch. 1 - Observed increases in global temperatures are...Ch. 1 - Prob. 1.35QPCh. 1 - List the three states of matter.
Ch. 1 - Explain the differences among the three states of...Ch. 1 - Prob. 1.39QPCh. 1 - Prob. 1.40QPCh. 1 - Prob. 1.41QPCh. 1 - Prob. 1.42QPCh. 1 - Prob. 1.43QPCh. 1 - Prob. 1.44QPCh. 1 - Explain the difference between chemical properties...Ch. 1 - List the differences between chemical changes and...Ch. 1 - Label each of the following as pertaining to...Ch. 1 - Prob. 1.48QPCh. 1 - Prob. 1.49QPCh. 1 - Prob. 1.50QPCh. 1 - Label each of the following as either a physical...Ch. 1 - Prob. 1.52QPCh. 1 - Label each of the following properties of sodium...Ch. 1 - Prob. 1.54QPCh. 1 - Label each of the following as either a pure...Ch. 1 - Prob. 1.56QPCh. 1 - Label each of the following as either a...Ch. 1 - Prob. 1.58QPCh. 1 - Prob. 1.59QPCh. 1 - Prob. 1.60QPCh. 1 - Prob. 1.61QPCh. 1 - Mass is the measure of what property of matter?
Ch. 1 - Explain the difference between mass and weight.
Ch. 1 - Prob. 1.65QPCh. 1 - Prob. 1.66QPCh. 1 - How is the metric unit of L defined?
Ch. 1 - What English unit of volume is similar to a L?
Ch. 1 - Rank the following from shortest to longest...Ch. 1 - Rank the following from least to greatest mass.
Ch. 1 - Determine the temperature reading of the following...Ch. 1 - Prob. 1.72QPCh. 1 - Prob. 1.73QPCh. 1 - Prob. 1.74QPCh. 1 - How many significant figures are represented in...Ch. 1 - Prob. 1.76QPCh. 1 - Round the following numbers to three significant...Ch. 1 - Round the following numbers to three significant...Ch. 1 - Perform each of the following operations,...Ch. 1 - Prob. 1.80QPCh. 1 - Prob. 1.81QPCh. 1 - Prob. 1.82QPCh. 1 - Prob. 1.83QPCh. 1 - Prob. 1.84QPCh. 1 - Prob. 1.85QPCh. 1 - Prob. 1.86QPCh. 1 - Give the abbreviation and meaning of the following...Ch. 1 - Fill in the blank with the missing abbreviation...Ch. 1 - Write the two conversion factors that can be...Ch. 1 - Write the two conversion factors that can be...Ch. 1 - Prob. 1.91QPCh. 1 - Prob. 1.92QPCh. 1 - Prob. 1.93QPCh. 1 - Prob. 1.94QPCh. 1 - Convert 1.50 × 104 μg to mg.
Ch. 1 - Prob. 1.96QPCh. 1 - A typical office has 144 ft2 of floor space....Ch. 1 - Prob. 1.98QPCh. 1 - Prob. 1.99QPCh. 1 - Prob. 1.100QPCh. 1 - Prob. 1.101QPCh. 1 - Prob. 1.102QPCh. 1 - Prob. 1.103QPCh. 1 - Prob. 1.104QPCh. 1 - Which mass is smaller: 5.0 mg or 5.0 μg?
Ch. 1 - Which volume is smaller: 1.0 L or 1.0 qt?
Ch. 1 - Prob. 1.107QPCh. 1 - Prob. 1.108QPCh. 1 - Prob. 1.109QPCh. 1 - Prob. 1.110QPCh. 1 - Prob. 1.111QPCh. 1 - Prob. 1.112QPCh. 1 - Prob. 1.113QPCh. 1 - Prob. 1.114QPCh. 1 - Convert 50.0°F to:
°C
K
Ch. 1 - The weather station posted that the low for the...Ch. 1 - The thermostat shows that the room temperature is...Ch. 1 - Convert 300.0 K to:
°C
°F
Ch. 1 - Prob. 1.119QPCh. 1 - Prob. 1.120QPCh. 1 - Calculate the density of a 3.00 × 102 g object...Ch. 1 - Calculate the density of 50.0 g of an isopropyl...Ch. 1 - What volume, in L, will 8.00 × 102 g of air occupy...Ch. 1 - Prob. 1.124QPCh. 1 - What is the mass, in g, of a piece of iron that...Ch. 1 - What is the mass of a femur (leg bone) having a...Ch. 1 - For the treatment of cystic fibrosis, it has been...Ch. 1 - You are given a piece of wood that is either...Ch. 1 - You are given three bars of metal. Each is labeled...Ch. 1 - Refer to Question 1.135. Suppose that each of the...Ch. 1 - The density of methanol at 20°C is 0.791 g/mL....Ch. 1 - The density of methanol at 20°C is 0.791 g/mL....Ch. 1 - Prob. 1.133QPCh. 1 - The specific gravity of a patient’s urine sample...Ch. 1 - The density of grain alcohol is 0.789 g/mL. Given...Ch. 1 - Prob. 1.136QPCh. 1 - The density of whole human blood in a healthy...Ch. 1 - Prob. 1.138QPCh. 1 - An instrument used to detect metals in drinking...Ch. 1 - Prob. 2CPCh. 1 - Aspirin has been recommended to minimize the...Ch. 1 - The diameter of an aluminum atom is 250 picometers...
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