Connect 2-Year Online Access for General, Organic, and Biochemistry
9th Edition
ISBN: 9781259677946
Author: Denniston
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 1.5, Problem 1.11PP
Interpretation Introduction
Interpretation:
Given
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2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
Chapter 1 Solutions
Connect 2-Year Online Access for General, Organic, and Biochemistry
Ch. 1.1 - Prob. 1.1PPCh. 1.2 - Is each of the following materials a pure...Ch. 1.2 - Intravenous therapy may be used to introduce a...Ch. 1.2 - Cloudy urine can be a symptom of a bladder...Ch. 1.2 - Classify each of the following as either a...Ch. 1.2 - Prob. 1.3QCh. 1.2 - Prob. 1.4QCh. 1.2 - Prob. 1.4PPCh. 1.2 - Label each property as intensive or extensive:
the...Ch. 1.2 - Label each property as intensive or extensive:
the...
Ch. 1.4 - How many significant figures are contained in each...Ch. 1.4 - Prob. 1.8QCh. 1.4 - Prob. 1.9QCh. 1.4 - Prob. 1.10QCh. 1.4 - Prob. 1.11QCh. 1.4 - Prob. 1.12QCh. 1.4 - Prob. 1.13QCh. 1.4 - Prob. 1.14QCh. 1.4 - Prob. 1.5PPCh. 1.4 - Prob. 1.15QCh. 1.4 - Prob. 1.16QCh. 1.4 - Prob. 1.6PPCh. 1.4 - Prob. 1.17QCh. 1.4 - Prob. 1.18QCh. 1.5 - Convert 360 ft to mi.
Ch. 1.5 - Convert:
750 cm to mm
1.5 × 108 μL to cL
0.00055...Ch. 1.5 - Convert:
0.50 in to m
0.75 qt to L
56.8 g to...Ch. 1.5 - Convert:
1.5 cm2 to m2
3.6 m2 to cm2
Ch. 1.5 - Convert 0.791 g/mL to kg/L.
Ch. 1.6 - The freezing temperature of water is 32°F....Ch. 1.6 - Prob. 1.19QCh. 1.6 - Prob. 1.20QCh. 1.6 - Prob. 1.13PPCh. 1.6 - Prob. 1.14PPCh. 1.6 - Prob. 1.15PPCh. 1.6 - Calculate the volume, in mL, of 10.0 g of a saline...Ch. 1 - Define chemistry and explain how burning wood is...Ch. 1 - Prob. 1.22QPCh. 1 - Why is experimentation an important part of the...Ch. 1 - Prob. 1.24QPCh. 1 - What data would be required to estimate the total...Ch. 1 - What data would be required to estimate the mass...Ch. 1 - What are the characteristics of methane emphasized...Ch. 1 - Discuss the difference between hypothesis and...Ch. 1 - Discuss the difference between theory and...Ch. 1 - We use aspects of the scientific method in our...Ch. 1 - Experimentation has shown that stem cell research...Ch. 1 - Observed increases in global temperatures are...Ch. 1 - Prob. 1.35QPCh. 1 - List the three states of matter.
Ch. 1 - Explain the differences among the three states of...Ch. 1 - Prob. 1.39QPCh. 1 - Prob. 1.40QPCh. 1 - Prob. 1.41QPCh. 1 - Prob. 1.42QPCh. 1 - Prob. 1.43QPCh. 1 - Prob. 1.44QPCh. 1 - Explain the difference between chemical properties...Ch. 1 - List the differences between chemical changes and...Ch. 1 - Label each of the following as pertaining to...Ch. 1 - Prob. 1.48QPCh. 1 - Prob. 1.49QPCh. 1 - Prob. 1.50QPCh. 1 - Label each of the following as either a physical...Ch. 1 - Prob. 1.52QPCh. 1 - Label each of the following properties of sodium...Ch. 1 - Prob. 1.54QPCh. 1 - Label each of the following as either a pure...Ch. 1 - Prob. 1.56QPCh. 1 - Label each of the following as either a...Ch. 1 - Prob. 1.58QPCh. 1 - Prob. 1.59QPCh. 1 - Prob. 1.60QPCh. 1 - Prob. 1.61QPCh. 1 - Mass is the measure of what property of matter?
Ch. 1 - Explain the difference between mass and weight.
Ch. 1 - Prob. 1.65QPCh. 1 - Prob. 1.66QPCh. 1 - How is the metric unit of L defined?
Ch. 1 - What English unit of volume is similar to a L?
Ch. 1 - Rank the following from shortest to longest...Ch. 1 - Rank the following from least to greatest mass.
Ch. 1 - Determine the temperature reading of the following...Ch. 1 - Prob. 1.72QPCh. 1 - Prob. 1.73QPCh. 1 - Prob. 1.74QPCh. 1 - How many significant figures are represented in...Ch. 1 - Prob. 1.76QPCh. 1 - Round the following numbers to three significant...Ch. 1 - Round the following numbers to three significant...Ch. 1 - Perform each of the following operations,...Ch. 1 - Prob. 1.80QPCh. 1 - Prob. 1.81QPCh. 1 - Prob. 1.82QPCh. 1 - Prob. 1.83QPCh. 1 - Prob. 1.84QPCh. 1 - Prob. 1.85QPCh. 1 - Prob. 1.86QPCh. 1 - Give the abbreviation and meaning of the following...Ch. 1 - Fill in the blank with the missing abbreviation...Ch. 1 - Write the two conversion factors that can be...Ch. 1 - Write the two conversion factors that can be...Ch. 1 - Prob. 1.91QPCh. 1 - Prob. 1.92QPCh. 1 - Prob. 1.93QPCh. 1 - Prob. 1.94QPCh. 1 - Convert 1.50 × 104 μg to mg.
Ch. 1 - Prob. 1.96QPCh. 1 - A typical office has 144 ft2 of floor space....Ch. 1 - Prob. 1.98QPCh. 1 - Prob. 1.99QPCh. 1 - Prob. 1.100QPCh. 1 - Prob. 1.101QPCh. 1 - Prob. 1.102QPCh. 1 - Prob. 1.103QPCh. 1 - Prob. 1.104QPCh. 1 - Which mass is smaller: 5.0 mg or 5.0 μg?
Ch. 1 - Which volume is smaller: 1.0 L or 1.0 qt?
Ch. 1 - Prob. 1.107QPCh. 1 - Prob. 1.108QPCh. 1 - Prob. 1.109QPCh. 1 - Prob. 1.110QPCh. 1 - Prob. 1.111QPCh. 1 - Prob. 1.112QPCh. 1 - Prob. 1.113QPCh. 1 - Prob. 1.114QPCh. 1 - Convert 50.0°F to:
°C
K
Ch. 1 - The weather station posted that the low for the...Ch. 1 - The thermostat shows that the room temperature is...Ch. 1 - Convert 300.0 K to:
°C
°F
Ch. 1 - Prob. 1.119QPCh. 1 - Prob. 1.120QPCh. 1 - Calculate the density of a 3.00 × 102 g object...Ch. 1 - Calculate the density of 50.0 g of an isopropyl...Ch. 1 - What volume, in L, will 8.00 × 102 g of air occupy...Ch. 1 - Prob. 1.124QPCh. 1 - What is the mass, in g, of a piece of iron that...Ch. 1 - What is the mass of a femur (leg bone) having a...Ch. 1 - For the treatment of cystic fibrosis, it has been...Ch. 1 - You are given a piece of wood that is either...Ch. 1 - You are given three bars of metal. Each is labeled...Ch. 1 - Refer to Question 1.135. Suppose that each of the...Ch. 1 - The density of methanol at 20°C is 0.791 g/mL....Ch. 1 - The density of methanol at 20°C is 0.791 g/mL....Ch. 1 - Prob. 1.133QPCh. 1 - The specific gravity of a patient’s urine sample...Ch. 1 - The density of grain alcohol is 0.789 g/mL. Given...Ch. 1 - Prob. 1.136QPCh. 1 - The density of whole human blood in a healthy...Ch. 1 - Prob. 1.138QPCh. 1 - An instrument used to detect metals in drinking...Ch. 1 - Prob. 2CPCh. 1 - Aspirin has been recommended to minimize the...Ch. 1 - The diameter of an aluminum atom is 250 picometers...
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