General, Organic, and Biochemistry
9th Edition
ISBN: 9780078021541
Author: Katherine J Denniston, Joseph J Topping, Dr Danae Quirk Dorr
Publisher: McGraw-Hill Education
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Chapter 1, Problem 1.95QP
Interpretation Introduction
Interpretation:
Given
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Part VI.
Ca H 10 O is the molecular formula of compound Tom and gives the
in the table below. Give a possible structure for compound Tom.
13C
Signals summarized
C1
C2
C3
C4
C5
C6
C7
13C shift (ppm)
23.5
27.0
33.0
35.8
127
162
205
DEPT-90
+
DEPT-135
+
+
2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at
373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and
molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.
Part VII. Below are the 'HNMR
13
3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
ли
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8
f1 (ppm)
Chapter 1 Solutions
General, Organic, and Biochemistry
Ch. 1.1 - Prob. 1.1PPCh. 1.2 - Is each of the following materials a pure...Ch. 1.2 - Intravenous therapy may be used to introduce a...Ch. 1.2 - Cloudy urine can be a symptom of a bladder...Ch. 1.2 - Classify each of the following as either a...Ch. 1.2 - Prob. 1.3QCh. 1.2 - Prob. 1.4QCh. 1.2 - Prob. 1.4PPCh. 1.2 - Label each property as intensive or extensive:
the...Ch. 1.2 - Label each property as intensive or extensive:
the...
Ch. 1.4 - How many significant figures are contained in each...Ch. 1.4 - Prob. 1.8QCh. 1.4 - Prob. 1.9QCh. 1.4 - Prob. 1.10QCh. 1.4 - Prob. 1.11QCh. 1.4 - Prob. 1.12QCh. 1.4 - Prob. 1.13QCh. 1.4 - Prob. 1.14QCh. 1.4 - Prob. 1.5PPCh. 1.4 - Prob. 1.15QCh. 1.4 - Prob. 1.16QCh. 1.4 - Prob. 1.6PPCh. 1.4 - Prob. 1.17QCh. 1.4 - Prob. 1.18QCh. 1.5 - Convert 360 ft to mi.
Ch. 1.5 - Convert:
750 cm to mm
1.5 × 108 μL to cL
0.00055...Ch. 1.5 - Convert:
0.50 in to m
0.75 qt to L
56.8 g to...Ch. 1.5 - Convert:
1.5 cm2 to m2
3.6 m2 to cm2
Ch. 1.5 - Convert 0.791 g/mL to kg/L.
Ch. 1.6 - The freezing temperature of water is 32°F....Ch. 1.6 - Prob. 1.19QCh. 1.6 - Prob. 1.20QCh. 1.6 - Prob. 1.13PPCh. 1.6 - Prob. 1.14PPCh. 1.6 - Prob. 1.15PPCh. 1.6 - Calculate the volume, in mL, of 10.0 g of a saline...Ch. 1 - Define chemistry and explain how burning wood is...Ch. 1 - Prob. 1.22QPCh. 1 - Why is experimentation an important part of the...Ch. 1 - Prob. 1.24QPCh. 1 - What data would be required to estimate the total...Ch. 1 - What data would be required to estimate the mass...Ch. 1 - What are the characteristics of methane emphasized...Ch. 1 - Discuss the difference between hypothesis and...Ch. 1 - Discuss the difference between theory and...Ch. 1 - We use aspects of the scientific method in our...Ch. 1 - Experimentation has shown that stem cell research...Ch. 1 - Observed increases in global temperatures are...Ch. 1 - Prob. 1.35QPCh. 1 - List the three states of matter.
Ch. 1 - Explain the differences among the three states of...Ch. 1 - Prob. 1.39QPCh. 1 - Prob. 1.40QPCh. 1 - Prob. 1.41QPCh. 1 - Prob. 1.42QPCh. 1 - Prob. 1.43QPCh. 1 - Prob. 1.44QPCh. 1 - Explain the difference between chemical properties...Ch. 1 - List the differences between chemical changes and...Ch. 1 - Label each of the following as pertaining to...Ch. 1 - Prob. 1.48QPCh. 1 - Prob. 1.49QPCh. 1 - Prob. 1.50QPCh. 1 - Label each of the following as either a physical...Ch. 1 - Prob. 1.52QPCh. 1 - Label each of the following properties of sodium...Ch. 1 - Prob. 1.54QPCh. 1 - Label each of the following as either a pure...Ch. 1 - Prob. 1.56QPCh. 1 - Label each of the following as either a...Ch. 1 - Prob. 1.58QPCh. 1 - Prob. 1.59QPCh. 1 - Prob. 1.60QPCh. 1 - Prob. 1.61QPCh. 1 - Mass is the measure of what property of matter?
Ch. 1 - Explain the difference between mass and weight.
Ch. 1 - Prob. 1.65QPCh. 1 - Prob. 1.66QPCh. 1 - How is the metric unit of L defined?
Ch. 1 - What English unit of volume is similar to a L?
Ch. 1 - Rank the following from shortest to longest...Ch. 1 - Rank the following from least to greatest mass.
Ch. 1 - Determine the temperature reading of the following...Ch. 1 - Prob. 1.72QPCh. 1 - Prob. 1.73QPCh. 1 - Prob. 1.74QPCh. 1 - How many significant figures are represented in...Ch. 1 - Prob. 1.76QPCh. 1 - Round the following numbers to three significant...Ch. 1 - Round the following numbers to three significant...Ch. 1 - Perform each of the following operations,...Ch. 1 - Prob. 1.80QPCh. 1 - Prob. 1.81QPCh. 1 - Prob. 1.82QPCh. 1 - Prob. 1.83QPCh. 1 - Prob. 1.84QPCh. 1 - Prob. 1.85QPCh. 1 - Prob. 1.86QPCh. 1 - Give the abbreviation and meaning of the following...Ch. 1 - Fill in the blank with the missing abbreviation...Ch. 1 - Write the two conversion factors that can be...Ch. 1 - Write the two conversion factors that can be...Ch. 1 - Prob. 1.91QPCh. 1 - Prob. 1.92QPCh. 1 - Prob. 1.93QPCh. 1 - Prob. 1.94QPCh. 1 - Convert 1.50 × 104 μg to mg.
Ch. 1 - Prob. 1.96QPCh. 1 - A typical office has 144 ft2 of floor space....Ch. 1 - Prob. 1.98QPCh. 1 - Prob. 1.99QPCh. 1 - Prob. 1.100QPCh. 1 - Prob. 1.101QPCh. 1 - Prob. 1.102QPCh. 1 - Prob. 1.103QPCh. 1 - Prob. 1.104QPCh. 1 - Which mass is smaller: 5.0 mg or 5.0 μg?
Ch. 1 - Which volume is smaller: 1.0 L or 1.0 qt?
Ch. 1 - Prob. 1.107QPCh. 1 - Prob. 1.108QPCh. 1 - Prob. 1.109QPCh. 1 - Prob. 1.110QPCh. 1 - Prob. 1.111QPCh. 1 - Prob. 1.112QPCh. 1 - Prob. 1.113QPCh. 1 - Prob. 1.114QPCh. 1 - Convert 50.0°F to:
°C
K
Ch. 1 - The weather station posted that the low for the...Ch. 1 - The thermostat shows that the room temperature is...Ch. 1 - Convert 300.0 K to:
°C
°F
Ch. 1 - Prob. 1.119QPCh. 1 - Prob. 1.120QPCh. 1 - Calculate the density of a 3.00 × 102 g object...Ch. 1 - Calculate the density of 50.0 g of an isopropyl...Ch. 1 - What volume, in L, will 8.00 × 102 g of air occupy...Ch. 1 - Prob. 1.124QPCh. 1 - What is the mass, in g, of a piece of iron that...Ch. 1 - What is the mass of a femur (leg bone) having a...Ch. 1 - For the treatment of cystic fibrosis, it has been...Ch. 1 - You are given a piece of wood that is either...Ch. 1 - You are given three bars of metal. Each is labeled...Ch. 1 - Refer to Question 1.135. Suppose that each of the...Ch. 1 - The density of methanol at 20°C is 0.791 g/mL....Ch. 1 - The density of methanol at 20°C is 0.791 g/mL....Ch. 1 - Prob. 1.133QPCh. 1 - The specific gravity of a patient’s urine sample...Ch. 1 - The density of grain alcohol is 0.789 g/mL. Given...Ch. 1 - Prob. 1.136QPCh. 1 - The density of whole human blood in a healthy...Ch. 1 - Prob. 1.138QPCh. 1 - An instrument used to detect metals in drinking...Ch. 1 - Prob. 2CPCh. 1 - Aspirin has been recommended to minimize the...Ch. 1 - The diameter of an aluminum atom is 250 picometers...
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