
Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Question
Chapter 1, Problem 1.81PAE
Interpretation Introduction
Interpretation:
the differences in the design of steel-framed versus aluminum framed bicycles
Concept Introduction: The less dense the material is the lighter it is. The higher the elastic modulus of a material in the easily it can be bent or welded.
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1. Predict the organic product(s) of the following reactions. Assume excess of reagents unless
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b)
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2) H3O+
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2) H3O+
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There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below:
QUESTION: Summarise and report these results including an indication of measurement uncertainty.
In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical).
Mass of Taurine (mg)
Mass of Taurine (mg)
(Table continued)
152.01
152.23
151.87
151.45
154.11
152.64
152.98
153.24
152.88
151.45
153.49
152.48
150.68
152.33
151.52
153.63
152.48
151.68
153.17
153.40
153.77
153.67
152.34
153.16
152.57
153.02
152.86
151.50
151.23
152.57
152.72
151.54
146.47
152.38
152.44
152.54
152.53
152.54
151.32…
Indicate the rate expressions for reactions that have order 0, 1, and 2.
Chapter 1 Solutions
Chemistry for Engineering Students
Ch. 1 - Prob. 1COCh. 1 - Prob. 2COCh. 1 - Draw pictures to illustrate simple chemical...Ch. 1 - Explain the difference between inductive and...Ch. 1 - Use appropriate techniques to convert measurements...Ch. 1 - Express the results of calculations using the...Ch. 1 - Use the web to determine the mass of a steel...Ch. 1 - Prob. 1.2PAECh. 1 - Where does the scientific method start? What is...Ch. 1 - Use the web to determine the amount of aluminum...
Ch. 1 - Use the web to find current prices offered for...Ch. 1 - Use the web to determine the differences in the...Ch. 1 - When we make observations in the laboratory, which...Ch. 1 - Which of the following items are matter and which...Ch. 1 - Which macroscopic characteristics differentiate...Ch. 1 - How can a liquid be distinguished from a fine...Ch. 1 - Some farmers use ammonia, NHS, as a fertilizer....Ch. 1 - 1.10 Do the terms element and atom mean the same...Ch. 1 - 1.11 Label each of the following as either a...Ch. 1 - 1.12 Why do physical properties play a role in...Ch. 1 - 1.13 Physical properties may change because of a...Ch. 1 - 1.14 Which part of the following descriptions of a...Ch. 1 - Use a molecular level description to explain why...Ch. 1 - All molecules attract each other to some extent,...Ch. 1 - 1.15 We used the example of attendance at a...Ch. 1 - 1.16 Complete the following statement: Data that...Ch. 1 - 1.17 Complete the following statement: Data that...Ch. 1 - 1.18 Two golfers are practicing shots around a...Ch. 1 - Prob. 1.23PAECh. 1 - 1.20 Suppose that you are waiting at a corner for...Ch. 1 - 1.21 When a scientist looks at an experiment and...Ch. 1 - 1.22 What is the difference between a hypothesis...Ch. 1 - 1.23 Should the words theory and model be used...Ch. 1 - 1.24 What is a law of nature? Are all scientific...Ch. 1 - 1.25 Describe a miscommunication that can arise...Ch. 1 - 1.26 What is the difference between a qualitative...Ch. 1 - 1.27 Identify which of the following units are...Ch. 1 - 1.28 What is a “derived” unit?Ch. 1 - 1.29 Rank the following prefixes in order of...Ch. 1 - 1.30 The largest computers now include disk...Ch. 1 - Prob. 1.35PAECh. 1 - 1.32 Use the web to determine how the Btu was...Ch. 1 - 1.33 How many micrograms are equal to one gram?Ch. 1 - 1.34 Convert the value 0.120 ppb into ppm.Ch. 1 - 1.35 How was the Fahrenheit temperature scale...Ch. 1 - Superconductors are materials that have no...Ch. 1 - 1.37 Express each of the following temperatures in...Ch. 1 - 1.38 Express (a) 275 oC in K, (b) 25.55 K in oC,...Ch. 1 - 1.39 Express each of the following numbers in...Ch. 1 - 1.40 How many significant figures are there in...Ch. 1 - 1.41 How many significant figures are present in...Ch. 1 - Perform these calculations and express the result...Ch. 1 - 1.43 Calculate the following to the correct number...Ch. 1 - 1.44 In an attempt to determine the velocity of a...Ch. 1 - 1.45 A student finds that the mass of an object is...Ch. 1 - 1.46 Measurements indicate that 23.6% of the...Ch. 1 - 1.47 A student weighs 10 quarters and finds that...Ch. 1 - 1.48 A rock is placed on a balance and its mass is...Ch. 1 - 1.49 A package of eight apples has a mass of 1.00...Ch. 1 - Prob. 1.54PAECh. 1 - 1.51 A person measures 173 cm in height. What is...Ch. 1 - 1.52 The distance between two atoms in a molecule...Ch. 1 - 1.53 Carry out the following unit conversions. (a)...Ch. 1 - 1.54 Carry out each of the following conversions....Ch. 1 - 1.55 Convert 22.3 mL to (a) liters, (b) cubic...Ch. 1 - 1.56 If a vehicle is travelling 92 m/s, what is...Ch. 1 - 1.57 A load of asphalt weights 245 lb. and...Ch. 1 - 1.58 One square mile contains exactly 640 acres....Ch. 1 - 1.59 A sample of crude oil has a density of 0.87...Ch. 1 - 1.60 Mercury has a density of 13.6 g/mL. What is...Ch. 1 - 1.61 The area of the 48 contiguous states is...Ch. 1 - 1.62 The dimensions of aluminium foil in a box for...Ch. 1 - Prob. 1.67PAECh. 1 - 1.64 Wire is often sold in pound spools according...Ch. 1 - 1.65 An industrial engineer is designing a process...Ch. 1 - 1.66 An engineer is working with archaeologists to...Ch. 1 - Draw a molecular scale picture to show how a...Ch. 1 - Prob. 1.72PAECh. 1 - 1.67 On average, Earth’s crust contains about 8.1...Ch. 1 - Prob. 1.74PAECh. 1 - 1.69 The “Western Stone” in Jerusalem is one of...Ch. 1 - A load of bauxite has a density of 3.15 g/cm3. If...Ch. 1 - Prob. 1.77PAECh. 1 - Prob. 1.78PAECh. 1 - Prob. 1.79PAECh. 1 - Prob. 1.80PAECh. 1 - Prob. 1.81PAECh. 1 - Use the web to research the elastic modulus and...Ch. 1 - Prob. 1.83PAECh. 1 - 1.84 A student was given two metal cubes that...Ch. 1 - 1.85 Battery acid has a density of 1.285 g/mL and...Ch. 1 - 1.86 Unfermented grape juice used to make wine is...Ch. 1 - 1.87 A solution of ethanol in water has a volume...Ch. 1 - 1.88 Legend has it that Archimedes, a famous...Ch. 1 - 1.89 Imagine that you place a cork measuring...Ch. 1 - 1.90 A calibrated flask was filled to the 25.00-mL...
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- PROBLEMS Q1) Label the following salts as either acidic, basic, or neutral a) Fe(NOx) c) AlBr b) NH.CH COO d) HCOON (1/2 mark each) e) Fes f) NaBr Q2) What is the pH of a 0.0750 M solution of sulphuric acid?arrow_forward8. Draw all the resonance forms for each of the fling molecules or ions, and indicate the major contributor in each case, or if they are equivalent (45) (2) -PH2 سمة مدarrow_forwardA J то گای ه +0 Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01 number of moles= 0.400/277.15 = 0.00144 moles 2 x 0.00 144=0.00288 moves arams of acetophenone = 0.00144 X 120.16 = 0.1739 0.1739x2=0.3469 grams of benzaldehyde = 0.00144X106.12=0.1539 0.1539x2 = 0.3069 Starting materials: 0.3469 Ox acetophenone, 0.3069 of benzaldehyde 3arrow_forward
- 1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.arrow_forward3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗarrow_forward2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br Oarrow_forward
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- Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…arrow_forwardPropose a synthesis pathway for the following transformations. b) c) d)arrow_forwardThe rate coefficient of the gas-phase reaction 2 NO2 + O3 → N2O5 + O2 is 2.0x104 mol–1 dm3 s–1 at 300 K. Indicate whether the order of the reaction is 0, 1, or 2.arrow_forward
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