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OWLv2 for Ebbing/Gammon's General Chemistry, 11th Edition, [Instant Access], 1 term (6 months)
11th Edition
ISBN: 9781305673939
Author: Darrell Ebbing; Steven D. Gammon
Publisher: Cengage Learning US
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Chapter 1, Problem 1.6QP
Interpretation Introduction
Interpretation:
The changes that occur when metal mercury is reacted with oxygen that is present in air has to be described.
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For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 →> NO₂+ NO3_(K1)
NO2 + NO3 → N2O5 (k-1)
NO2 + NO3 →
→
NO2 + O2 + NO (K2)
NO + N2O5-
NO2 + NO2 + NO2 (K3)
d[N₂O5] __2k‚k₂[N2O5]
Indicate whether the following rate expression is acceptable:
dt
k₁₁+ k₂
Consider the following decomposition reaction of N2O5(g):
For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 → NO2 + NO3 (K1)
NO2 + NO3 → N2O5 (k-1)
NO2 + NO3 → NO2 + O2 + NO (K2)
NO + N2O5 → NO2 + NO2 + NO2 (K3)
Indicate whether the following rate expression is acceptable:
d[N2O5]
= -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³
dt
In a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.
Chapter 1 Solutions
OWLv2 for Ebbing/Gammon's General Chemistry, 11th Edition, [Instant Access], 1 term (6 months)
Ch. 1.3 - You place 1.85 grams of wood in a vessel with 9.45...Ch. 1.4 - Potassium is a soft, silvery-colored metal that...Ch. 1.4 - Matter can be represented as being composed of...Ch. 1.5 - Give answers to the following arithmetic setups....Ch. 1.5 - a. When you report your weight to someone, how...Ch. 1.6 - Express the following quantities using an SI...Ch. 1.6 - a. A person with a fever has a temperature of...Ch. 1.6 - Prob. 1.3CCCh. 1.7 - A piece of metal wire has a volume of 20.2 cm3 and...Ch. 1.7 - Ethanol (grain alcohol) has a density of 0.789...
Ch. 1.7 - You are working in the office of a precious metals...Ch. 1.8 - The oxygen molecule (the smallest particle of...Ch. 1.8 - A large crystal is constructed by stacking small,...Ch. 1.8 - Using the definitions 1 in. = 2.54 cm and 1 yd =...Ch. 1 - Discuss some ways in which chemistry has changed...Ch. 1 - Define the terms experiment and theory. How are...Ch. 1 - Illustrate the steps in the scientific method...Ch. 1 - Define the terms matter and mass. What is the...Ch. 1 - Prob. 1.5QPCh. 1 - Prob. 1.6QPCh. 1 - Characterize gases, liquids, and solids in terms...Ch. 1 - Prob. 1.8QPCh. 1 - Give examples of an element, a compound, a...Ch. 1 - What phases or states of matter are present in a...Ch. 1 - What distinguishes an element from a compound? Can...Ch. 1 - Prob. 1.12QPCh. 1 - Prob. 1.13QPCh. 1 - Prob. 1.14QPCh. 1 - How does the International System (SI) obtain...Ch. 1 - Prob. 1.16QPCh. 1 - Prob. 1.17QPCh. 1 - Why should units be carried along with numbers in...Ch. 1 - When the quantity 12.9 g is added to 2 1002 g,...Ch. 1 - Prob. 1.20QPCh. 1 - A 75.0-g sample of a pure liquid, liquid A, with a...Ch. 1 - Which of the following represents the smallest...Ch. 1 - Physical and Chemical Changes Say you are...Ch. 1 - a Sodium metal is partially melted. What are the...Ch. 1 - A material is believed to be a compound. 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Decide...Ch. 1 - Decide whether each of the following is a physical...Ch. 1 - Iodine is a solid having somewhat lustrous,...Ch. 1 - Mercury(II) oxide is an orange-red solid with a...Ch. 1 - Consider the following separations of materials....Ch. 1 - All of the following processes involve a...Ch. 1 - Label each of the following as a substance, a...Ch. 1 - Indicate whether each of the following materials...Ch. 1 - Which of the following are pure substances and...Ch. 1 - Which of the following are pure substances and...Ch. 1 - How many significant figures are there in each of...Ch. 1 - How many significant figures are there in each of...Ch. 1 - The circumference of the earth at the equator is...Ch. 1 - The astronomical unit equals the mean distance...Ch. 1 - Assuming all numbers are measured quantities, do...Ch. 1 - Assuming all numbers are measured quantities, do...Ch. 1 - Prob. 1.63QPCh. 1 - Prob. 1.64QPCh. 1 - Write the following measurements, without...Ch. 1 - Write the following measurements, without...Ch. 1 - Using scientific notation, convert: a 6.15 ps to s...Ch. 1 - Using scientific notation, convert: a 6.20 km to m...Ch. 1 - Convert: a 68F to degrees Celsius b 23F to degrees...Ch. 1 - Convert: a 51F to degrees Celsius b 11F to degrees...Ch. 1 - Salt and ice are stirred together to give a...Ch. 1 - Prob. 1.72QPCh. 1 - A certain sample of the mineral galena (lead...Ch. 1 - A flask contains a 30.0 mL sample of acetone (nail...Ch. 1 - A liquid with a volume of 8.5 mL has a mass of...Ch. 1 - Prob. 1.76QPCh. 1 - Platinum has a density of 21.4 g/cm3. 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Note...Ch. 1 - Prob. 1.88QPCh. 1 - The first measurement of sea depth was made in...Ch. 1 - The estimated amount of recoverable oil from the...Ch. 1 - A fish tank is 24.2 in. long, 15.9 in. deep, and...Ch. 1 - The population density of worms in a particular...Ch. 1 - Prob. 1.93QPCh. 1 - An antacid tablet weighing 0.853 g contained...Ch. 1 - When a mixture of aluminum powder and iron(III)...Ch. 1 - When chlorine gas is bubbled into a solution of...Ch. 1 - A beaker weighed 50.90 g. To the beaker was added...Ch. 1 - Prob. 1.98QPCh. 1 - Describe each of the following as a physical or...Ch. 1 - Describe each of the following as a physical or...Ch. 1 - Analyses of several samples of a material...Ch. 1 - A red-orange solid contains only mercury and...Ch. 1 - A cubic box measures 39.3 cm on an edge. 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- For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forwardGiven the reaction R + Q → P, indicate the rate law with respect to R, with respect to P and with respect to P.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
- k₁ Given the reaction A B, indicate k-1 d[A] (A). the rate law with respect to A: (B). the rate law with respect to B: d[B] dt dtarrow_forwardk₁ Given the reaction R₂ R + R, indicate k-1 (A). the rate law with respect to R2: (B). the rate law with respect to R: d[R₂] dt d[R] dtarrow_forwardGiven the reaction R+ Q → P, indicate (A). the rate law with respect to P: (B). the rate law with respect to R: (C). the rate law with respect to Q: d[P] dt d[R] dt d[Q] dtarrow_forward
- The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.arrow_forwarda. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)? b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
- a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here? b. What is the purpose of the Na2SO4? c. What equipment would you use to “concentrate [a solution] under reduced pressure”?arrow_forwardWhen N,N-dimethylaniline is treated with bromine both the ortho and para products are observed. However when treated with a mixture of nitric acid and sulfuric acid only the meta product is observed. Explain these results and support your answer with the appropriate drawings *Hint amines are bases* N HNO3 H2SO4 N NO2 N Br2 N Br + N 8-8-8 FeBr3 Brarrow_forwardDraw a mechanism that explains the formation of compound OMe SO3H 1. Fuming H2SO4arrow_forward
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