Chapter 1, Problem 1.64AP

(a)

Interpretation Introduction

Interpretation:

The reason has to explainfor the given molecule is impossible.

Concept introduction:

The electron configuration is the distribution of electrons of an atom or molecule in atomic or molecular orbitals.

1. 1. Electrons occupy the lowest energy orbitals. The increasing order of orbital energy is $\text{s, p, d and f}$. The lowest energy orbital is $\text{1s}$. The energy order of the orbital for the first three period is given below,

   $\text{1s, 2s, 2p, 3s,}\text{and 3p}$.

2. 2. The orbital which is closer to the nucleus has lower energy, therefore the 2s is lower in energy than 3s. Accordingly $2s$ is lower in energy than $\text{2p and 4s}$ is lower in energy than $\text{3d}$.
3. 3. In general, the orbitals can hold maximum of two electrons, the two electrons must have opposite spin.

The subshell ordering by Aufbau principle is given below, $\text{1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p, 8s, }\mathrm{...}$

According to the electron configuration the valence electron of carbon is four and the number of valence electron of hydrogen is one.

(b)

Interpretation Introduction

Interpretation:

The reason has to explain for the given molecule is impossible.

Concept introduction:

The electron configuration is the distribution of electrons of an atom or molecule in atomic or molecular orbitals.

1. 1. Electrons occupy the lowest energy orbitals. The increasing order of orbital energy is $\text{s, p, d and f}$. The lowest energy orbital is $\text{1s}$. The energy order of the orbital for the first three period is given below,

   $\text{1s, 2s, 2p, 3s,}\text{and 3p}$.

2. 2. The orbital which is closer to the nucleus has lower energy, therefore the 2s is lower in energy than 3s. Accordingly $2s$ is lower in energy than $\text{2p and 4s}$ is lower in energy than $\text{3d}$.
3. 3. In general, the orbitals can hold maximum of two electrons, the two electrons must have opposite spin.

The subshell ordering by Aufbau principle is given below, $\text{1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p, 8s, }\mathrm{...}$

According to the electron configuration the valence electron of carbon is four and the number of valence electron of hydrogen is one.