Unit Operations Of Chemical Engineering
Unit Operations Of Chemical Engineering
7th Edition
ISBN: 9789339213237
Author: MCCABE, WARREN
Publisher: Tata McGraw-Hill Education India
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Chapter 1, Problem 1.5P

(a)

Interpretation Introduction

Interpretation:

The volumetric flowrate of the entering gas being treated is to be calculated.

Concept Introduction:

The formula to calculate the volumetric flowrate (V˙) of a fluid from the velocity (v) of the fluid is:

  V˙=Av ...... (1)

Here, A is the cross-sectional area of the pipe or column through which the fluid id flowing.

(b)

Interpretation Introduction

Interpretation:

The amount of ammonia being absorbed is to be calculated.

Concept Introduction:

The formula to calculate the volumetric flowrate (V˙) of a fluid from the velocity (v) of the fluid is:

  V˙=Av ...... (1)

Here, A is the cross-sectional area of the pipe or column through which the fluid id flowing.

In a system, a conserved quantity (total mass, the mass of a particular species, energy or momentum) is balanced and can be written as:

  input+generationoutputconsumpumtion=accumulation

Here, ‘input’ is the stream which enters the system. ‘generation’ is the term used for the quantity that is produced within the system. ‘output’ is the stream which leaves the system. ‘consumption’ is the term used for the quantity that is consumed within the system. ‘accumulation’ is used for the quantity which is built up within the system.

All the equations which are formed are then solved simultaneously to calculate the values of the unknown variables.

An ideal gas is a gas that obeys ideal gas laws which is a simplified equation of states.

A real gas behaves as an ideal gas at a higher temperature and lower pressure. At STP, 1 lbmol of an ideal gas has a volume of 359 ft3 and the temperature is taken in the Rankine scale.

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For each set of measurements below, calculate the Grubbs statistic, G, look up the appropriate critical value of G from Table 4.6, and determine whether the Grubbs test supports discarding the first value in the list at the 95% level of confidence. a) 106.0, 165.0, 167.5, 170.5, 163.5, 170.7 (Geale -2.028; Gerit 1.822; yes, the Grubbs test supports discarding 106.0) b) 214.8, 263.0, 229.9, 236.9, 221.8, 230.8, 241.1 c) 357.0, 309.3, 304.9, 314.8, 305.8, 295.3, 284.7, 299.5 TABLE 4-6 Critical values of G for rejection of outlier Number of observations otsulsve os Tenos nagsibarito G to buboxy (95% confidence) 456 1.463 1.672 1.822 7 1.938 8 upa 2.032 9 2.110 10 2.176 - 1 12 15 20 11 2.234 2.285 2.409 2.557
#1 A irreversible isothermal gas-phase isomerization reaction is given as: AB. This reaction is conducted in a 400L batch reactor and 100 mol of A (NAD = 100 mol) is charged into this reactor. The rate of reaction is determined as a function of the conversion of reactant A and the results are given below. The temperature was constant at 500K and the total pressure was constant at 830 kPa. The entering number of moles of species A is 100 mol. Calculate the time necessary to achieve 80% conversion. 0 0.1 0.2 0.4 -TA (mol/m³.s) 0.45 0.37 0.3 0.195 0.6 0.113 0.7 0.079 0.8 0.05
#3 A irreversible isothermal liquid-phase reaction is given as: A → B is conducted in continuous flow systems. The rate of reaction is determined as a function of the conversion of reactant A and the results are given below. The temperature was constant at 500K. The entering molar flow rate of A is 0.4 mol/min. a) If this reaction is conducted in two CSTRS in series. Calculate the required reactor volume of each CSTRS if conversion X₁ = 0.4 and conversion X2 = 0.8. b) If this reaction is conducted in two PFRS in series. Calculate the required reactor volume of each PFRS if conversion X₁ = 0.4 and conversion X2 = 0.8. c) If this reaction is conducted in a PFR followed by a CSTR. Calculate the required reactor volume of PFR if conversion X₁ = 0.4 and of CSTR if conversion X2 = 0.8. X -A (mol/L.min) 0 0.1 0.2 0.4 0.6 0.7 0.8 0.45 0.37 0.3 0.195 0.113 0.079 0.05
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