In J. J. Thompson’s experiment depicted in Figures 1.10 and 1.11, assume that the electrons are initially traveling at a speed of
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Chapter 1 Solutions
PRINCIPLES OF MODERN CHEMISTRY
- Look up the van der Waals constants, b, for H2, N2, O2, and Cl2. Based on the periodic table, predict atomic radii for H, N, O, and Cl. Use these values to explain the sizes of the b constants.arrow_forwardDoes the main emission line for SrCl2 have a longer or shorter wavelength than that of the yellow line from NaCI?arrow_forwardW 4. (a) A laser emits light that has a frequency of 4.69 X 10¹4 s¹. What is the energy of one photon of this radiation? V (b) If the laser emits a pulse containing 5.0 X 1017 photons of this radiation, what is the total energy of that pulse? (c) If the laser emits 1.3 X 10-2 J of energy during a pulse, how many photons are emitted?arrow_forward
- What is the energy of photon that causes a hydrogen atom to undergo a transition from n-1→ n=2? State your answer in electronvolts (eV) (without units) to three significant figures. Note: 1 eV= 1.602 x 10-19 J.arrow_forward(A) A photon has a wavelength of 599 nm. Calculate the energy of the photon in joules. Enter your answer in scientific notation. (b) what is the wave length (in nm) of radiation that has an energy content of 9.53 x 103 kJ/mol? (B part 2) in which region of the electromagnetic spectrum is this radiation found? (c) what are the possible values for ml when the principal quantum number (n) is 2 and the angular momentum quantum number is 0?arrow_forwardUsing Planck's constant as h = 6.63 × 10−34 J⋅s, what is the wavelength of a proton with a speed of 5.00 × 106 m/s? The mass of a proton is 1.66 × 10−27 kg. Remember to identify your data, show your work, and report the answer using the correct number of significant digits and units.arrow_forward
- An EM wave has a wavelength of 1.54 angstroms. What is the frequency of this wave? What is the energy (in J) of one photons of this radiation? (1 angstrom = 1 x 10–10m exact, The Planck constant h = 6.626 x 10–34 J·s)arrow_forward(a) How does the Bohr model differ from the quantum mechanical model of the atom? Describe at least 2 differences.(b) Define each of the 4 quantum numbers (n, l, ml, ms) and what they physically represent about the orbital and/or electron.(d) How many quantum numbers are needed to completely define a specific orbital? Provide the quantum numbers for the 2s orbital.(d) How many quantum numbers are needed to completely define a specific electron? Provide the quantum numbers for the second electron to fill into a 2s orbital.arrow_forwardCompare the wavelengths of an electron (mass 9.11X10⁻³¹kg) and a proton (mass 1.67X10⁻²⁷kg), eachhaving (a) a speed of 3.4106m/s; (b) a kinetic energy of2.7X10¹⁵ J.arrow_forward
- Current theories of atomic structure suggest that all matter and all energy demonstrate both particle-like and wave-like properties under the appropriate conditions, although the wave-like nature of matter becomes apparent only in very small and very fast moving particles. The relationship between the wavelengths (A) observed for a particle and the mass and velocity of that particle is called the de Broglie relationship. It is λ = h my in which h is Planck's constant ( 6.63 x 10-34 J-s), rences] m represents the mass of the particle in kilograms, and v represents the velocity of the particle in meters per second. a. Calculate the de Broglie wavelength for an electron moving at 0.91 times the speed of light. Wavelength = b. Calculate the de Broglie wavelength for a 140. g ball moving at a speed of 10 m/s. Wavelength = c. Calculate the de Broglie wavelength for a 66 kg person walking at a speed of 6.0 km/h. Wavelength = m m marrow_forwardThe quantum numbers for the electron(s) in the valence shell of thallium (81TI) are: NOTE: the designation electron(s) with brackets around the s means that there might be only one: "electron" or there might be more than one: "electrons" O (6,1,-1,2) (6,1,0,½) (6,1,1,½) O (6,1,-1,12) O (6,0,0,±12) (6,1,-1,½) O (6,0,0,±½/2)arrow_forwardA photon of light from a laser has an energy of 2.287 × 10−19 J. What is the total energy in two moles of these photos?arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co