LL CHEM: MOL NAT CHNG W/CNCT AC
9th Edition
ISBN: 9781264502042
Author: SILBERBERG
Publisher: MCG
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Question
Chapter 1, Problem 1.5P
(a)
Interpretation Introduction
Interpretation:
Definition of physical and chemical properties is to be stated. Also, the type of change that occurs when the
Concept introduction:
The physical change can be represented as follows:
The representation of chemical change is as follows:
(b)
Interpretation Introduction
Interpretation:
Definition of physical and chemical properties is to be stated. Also, the type of change that occurs when iron in discarded automobiles slowly forms reddish brown, crumbly rust is to be determined.
Concept introduction:
The physical change can be represented as follows:
The representation of chemical change is as follows:
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 1 Solutions
LL CHEM: MOL NAT CHNG W/CNCT AC
Ch. 1.1 - Is the following change chemical or physical?
Ch. 1.1 - Is the following change chemical or physical?
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Ch. 1.3 - A landowner wants to spray herbicide on a field...Ch. 1.3 - Prob. 1.6BFPCh. 1.3 - Prob. 1.7AFPCh. 1.3 - Prob. 1.7BFPCh. 1.3 - Mercury melts at 234 K, lower than any other pure...Ch. 1.3 - Prob. 1.8BFPCh. 1.4 - For each of the following quantities, underline...Ch. 1.4 - Prob. 1.9BFPCh. 1.4 - Prob. 1.10AFPCh. 1.4 - Prob. 1.10BFPCh. 1 - Prob. 1.1PCh. 1 - Describe solids, liquids, and gases in terms of...Ch. 1 - Use your descriptions from Problem 1.2 to identify...Ch. 1 - Define physical property and chemical property....Ch. 1 - Prob. 1.5PCh. 1 - Which of the following is a chemical change?...Ch. 1 - Prob. 1.8PCh. 1 - Prob. 1.9PCh. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Prob. 1.14PCh. 1 - Prob. 1.15PCh. 1 - Prob. 1.16PCh. 1 - Prob. 1.17PCh. 1 - Prob. 1.18PCh. 1 - Prob. 1.19PCh. 1 - Prob. 1.20PCh. 1 - Prob. 1.21PCh. 1 - Prob. 1.22PCh. 1 - Prob. 1.23PCh. 1 - What is the length in inches (in) of a 100.-m...Ch. 1 - Prob. 1.25PCh. 1 - Prob. 1.26PCh. 1 - Prob. 1.27PCh. 1 - Prob. 1.28PCh. 1 - Prob. 1.29PCh. 1 - Prob. 1.30PCh. 1 - The speed of light in a vacuum is 2.998 × 108 m/s....Ch. 1 - Prob. 1.32PCh. 1 - Prob. 1.33PCh. 1 - Prob. 1.34PCh. 1 - Prob. 1.35PCh. 1 - A small cube of aluminum measures 15.6 mm on a...Ch. 1 - A steel ball-bearing with a circumference of 32.5...Ch. 1 - Prob. 1.38PCh. 1 - Prob. 1.39PCh. 1 - A 25.0-g sample of each of three unknown metals is...Ch. 1 - Prob. 1.41PCh. 1 - Prob. 1.42PCh. 1 - Prob. 1.43PCh. 1 - Prob. 1.44PCh. 1 - Prob. 1.45PCh. 1 - Prob. 1.46PCh. 1 - Prob. 1.47PCh. 1 - Prob. 1.48PCh. 1 - Prob. 1.49PCh. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Round off each number in the following calculation...Ch. 1 - Prob. 1.53PCh. 1 - Prob. 1.54PCh. 1 - Prob. 1.55PCh. 1 - Prob. 1.56PCh. 1 - Write the following numbers in scientific...Ch. 1 - Prob. 1.58PCh. 1 - Prob. 1.59PCh. 1 - Prob. 1.60PCh. 1 - Prob. 1.61PCh. 1 - Prob. 1.62PCh. 1 - Prob. 1.63PCh. 1 - Prob. 1.64PCh. 1 - Which of the following include exact numbers?
The...Ch. 1 - Prob. 1.66PCh. 1 - Prob. 1.67PCh. 1 - Prob. 1.68PCh. 1 - The following dartboards illustrate the types of...Ch. 1 - Prob. 1.70PCh. 1 - Prob. 1.71PCh. 1 - Bromine is used to prepare the pesticide methyl...Ch. 1 - Prob. 1.73PCh. 1 - Prob. 1.74PCh. 1 - Prob. 1.75PCh. 1 - Prob. 1.76PCh. 1 - Prob. 1.77PCh. 1 - Prob. 1.78PCh. 1 - Prob. 1.79PCh. 1 - Prob. 1.80PCh. 1 - Prob. 1.81PCh. 1 - Prob. 1.82P
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