CHEMISTRY-TEXT
8th Edition
ISBN: 9780134856230
Author: Robinson
Publisher: PEARSON
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Chapter 1, Problem 1.28CP
Interpretation Introduction
To determine:
Temperature reading from a Celsius thermometer and significant figures in temperature reading.
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Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Could you redraw these and also explain how to solve them for me pleas
Chapter 1 Solutions
CHEMISTRY-TEXT
Ch. 1 - Express the diameter of a nanoparticle(0.000 000...Ch. 1 - APPLY 1.2 Express the following quantities in...Ch. 1 - PRACTICE 1.3 The melting point of table salt is...Ch. 1 - Prob. 1.4ACh. 1 - PRACTICE 1.5 Chloroform, a substance once used as...Ch. 1 - APPLY 1.6 You are beachcombing on summer vacation...Ch. 1 - PRACTICE 1.7 Some radioactive materials emit a...Ch. 1 - Prob. 1.8ACh. 1 - How many significant figures does each of the...Ch. 1 - Read the volume of the buret and reportyour answer...
Ch. 1 - Examine the figure in Worked Example 1.6. Which...Ch. 1 - A 1.000 mL sample of acetone, a common solvent...Ch. 1 - Carry out the following calculations, expressing...Ch. 1 - APPLY 1.14 A sodium chloride solution was prepared...Ch. 1 - PRACTICE 1.15 Gemstones are weighed in carats,...Ch. 1 - PRACTICE 1.15 Gemstones are weighed in carats,...Ch. 1 - The maximum dimensions of a soccer field are 90.0...Ch. 1 - APPLY 1.18 How large, in cubic centimeters, is the...Ch. 1 - Prob. 1.19PCh. 1 - Prob. 1.20PCh. 1 - Use Figure 1.10 to estimate in powers of 10 (a)...Ch. 1 - On the nanoscale, materials often exhibit...Ch. 1 - Refer to Figure 1.11. Which cube has a...Ch. 1 - Catalytic converters use nanoscale particles of...Ch. 1 - Platinum is an expensive and rare metal used...Ch. 1 - Prob. 1.26PCh. 1 - Which block in each of the following drawings of a...Ch. 1 - Prob. 1.28CPCh. 1 - How many milliliters of water does the graduated...Ch. 1 - Assume that you have two graduated cylinders, one...Ch. 1 - The following cylinder contains three liquids that...Ch. 1 - The following statements pertain to the...Ch. 1 - The following statements pertain to the...Ch. 1 - Label the following statements about the world’s...Ch. 1 - Label the following statements as quantitative or...Ch. 1 - Refer to Figure 1.2. What is developed when...Ch. 1 - What is the difference between a hypothesis and...Ch. 1 - What SI units are used for measuring the following...Ch. 1 - Prefixes for multiples of SI units are used to...Ch. 1 - Prob. 1.40SPCh. 1 - Prob. 1.41SPCh. 1 - Bottles of wine sometimes carry the notation...Ch. 1 - Which quantity in each of the following pairs is...Ch. 1 - Which quantity in each of the following pairs is...Ch. 1 - How many picograms are in 1 mg? In 35 ng?Ch. 1 - How many microliters are in 1 L? In 20 mL?Ch. 1 - Prob. 1.47SPCh. 1 - Express the following measurements in scientific...Ch. 1 - Convert the following measurements from scientific...Ch. 1 - An experimental procedure call for 250 mg of...Ch. 1 - A virus has a diameter of 5.2108m . What is the...Ch. 1 - Which is larger, a Fahrenheit degree or a Celsius...Ch. 1 - What is the difference between a kelvin and a...Ch. 1 - The normal body temperature of a goat is 39.9 °C,...Ch. 1 - Of the 90 or so naturally occurring elements, only...Ch. 1 - Suppose that your oven is calibrated in degrees...Ch. 1 - Tungsten, the element used to make filaments in...Ch. 1 - Suppose you were dissatisfied with both Celsius...Ch. 1 - Answer parts (a)(d) of Problem 1.58 assuming that...Ch. 1 - Sodium chloride has a melting point of 1074 K and...Ch. 1 - A 125 mL sample of water at 293.2 K was heated for...Ch. 1 - What is the difference between a derived SI unit...Ch. 1 - Which volume in each pair is larger, and by...Ch. 1 - What is the volume in L of a cube with an edge...Ch. 1 - What is the volume in mL of a cube with an edge...Ch. 1 - What is the density of glass in g/cm3 if a sample...Ch. 1 - What is the density of lead in g/cm3 if a sample...Ch. 1 - A vessel contains 4.67 L of bromine whose density...Ch. 1 - Aspirin has a density of 1.40g/cm3 . What is the...Ch. 1 - Gaseous hydrogen has a density of 0.0899 g/L at...Ch. 1 - The density of silver is 10.5g/cm3 . What is the...Ch. 1 - Prob. 1.72SPCh. 1 - Prob. 1.73SPCh. 1 - You would like to determine if a set of antique...Ch. 1 - An experiment is performed to determine if pennies...Ch. 1 - The density of chloroform, a widely used organic...Ch. 1 - More sulfuric acid (density=1.8302g/cm3) is...Ch. 1 - Prob. 1.78SPCh. 1 - Assume that the kinetic energy of a 1400 kg car...Ch. 1 - Prob. 1.80SPCh. 1 - Prob. 1.81SPCh. 1 - Prob. 1.82SPCh. 1 - Prob. 1.83SPCh. 1 - Prob. 1.84SPCh. 1 - What is the difference in mass between a nickel...Ch. 1 - How many significant figures are in each of the...Ch. 1 - Prob. 1.87SPCh. 1 - Prob. 1.88SPCh. 1 - The diameter of the Earth at the equator is...Ch. 1 - Round off the following quantities to the number...Ch. 1 - Round off the following quantities to the number...Ch. 1 - Express the results of the following calculations...Ch. 1 - Express the results of the following calculations...Ch. 1 - Carry out the following conversions. (a) How many...Ch. 1 - Convert the following quantities into SI units...Ch. 1 - Prob. 1.96SPCh. 1 - In the United States, the emissions limit for...Ch. 1 - Prob. 1.98SPCh. 1 - Prob. 1.99SPCh. 1 - Prob. 1.100SPCh. 1 - Concentrations of substances dissolved in solution...Ch. 1 - Prob. 1.102SPCh. 1 - Prob. 1.103SPCh. 1 - Which is larger in each pair, and by approximate...Ch. 1 - The density of polystyrene, a plastic commonly...Ch. 1 - The density of polypropylene, a plastic commonly...Ch. 1 - Prob. 1.107MPCh. 1 - A 1.0-ounce piece of chocolate contains 15 mg of...Ch. 1 - Prob. 1.109MPCh. 1 - Prob. 1.110MPCh. 1 - Prob. 1.111MPCh. 1 - A bag of Hershey’s Kisses contains the following...Ch. 1 - Vinaigrette salad dressing consists mainly of oil...Ch. 1 - At a certain point, the Celsius and Fahrenheit...Ch. 1 - Prob. 1.115MPCh. 1 - A calibrated flask was filled to the 25.00 mL mark...Ch. 1 - Brass is a copper-zinc alloy. What is the mass in...Ch. 1 - Ocean currents are measured in Sverdrups (sv)...Ch. 1 - The element gallium (Ga) has the second-largest...
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