
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198727873
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 1, Problem 1.13P
Interpretation Introduction
Interpretation:
Van der Waals parameters of the gas constant the radius of the molecules has to be estimated using given critical constants values.
Concept Introduction:
Van der Waals equation:
The deviation from
Where,
a and b are constants
P is the pressure
V is the volume
T is the temperature
R is molar gas constant
n is the mole
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 1 Solutions
Elements Of Physical Chemistry
Ch. 1 - Prob. 1A.1STCh. 1 - Prob. 1A.2STCh. 1 - Prob. 1A.3STCh. 1 - Prob. 1A.4STCh. 1 - Prob. 1B.1STCh. 1 - Prob. 1B.2STCh. 1 - Prob. 1B.3STCh. 1 - Prob. 1B.4STCh. 1 - Prob. 1B.5STCh. 1 - Prob. 1C.1ST
Ch. 1 - Prob. 1C.2STCh. 1 - Prob. 1A.1ECh. 1 - Prob. 1A.2ECh. 1 - Prob. 1A.3ECh. 1 - Prob. 1A.4ECh. 1 - Prob. 1A.5ECh. 1 - Prob. 1A.6ECh. 1 - Prob. 1A.7ECh. 1 - Prob. 1A.8ECh. 1 - Prob. 1A.9ECh. 1 - Prob. 1A.10ECh. 1 - Prob. 1A.11ECh. 1 - Prob. 1A.12ECh. 1 - Prob. 1A.13ECh. 1 - Prob. 1A.14ECh. 1 - Prob. 1B.1ECh. 1 - Prob. 1B.2ECh. 1 - Prob. 1B.3ECh. 1 - Prob. 1B.4ECh. 1 - Prob. 1B.5ECh. 1 - Prob. 1B.6ECh. 1 - Prob. 1B.7ECh. 1 - Prob. 1B.8ECh. 1 - Prob. 1C.1ECh. 1 - Prob. 1C.2ECh. 1 - Prob. 1C.3ECh. 1 - Prob. 1C.4ECh. 1 - Prob. 1C.5ECh. 1 - Prob. 1C.6ECh. 1 - Prob. 1C.7ECh. 1 - Prob. 1C.8ECh. 1 - Prob. 1C.9ECh. 1 - Prob. 1.1DQCh. 1 - Prob. 1.2DQCh. 1 - Prob. 1.3DQCh. 1 - Prob. 1.4DQCh. 1 - Prob. 1.5DQCh. 1 - Prob. 1.6DQCh. 1 - Prob. 1.7DQCh. 1 - Prob. 1.3PCh. 1 - Prob. 1.4PCh. 1 - Prob. 1.5PCh. 1 - Prob. 1.6PCh. 1 - Prob. 1.7PCh. 1 - Prob. 1.8PCh. 1 - Prob. 1.9PCh. 1 - Prob. 1.10PCh. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Prob. 1.14PCh. 1 - Prob. 1.1PRCh. 1 - Prob. 1.2PRCh. 1 - Prob. 1.3PRCh. 1 - Prob. 1.4PR
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