General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN: 9781305580343
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 1, Problem 1.127QP
Some bottles of colorless liquids were being labeled when the technicians accidentally mixed them up and lost track of their contents. A 15.0-mL sample withdrawn from one bottle weighed 22.3 g. The technicians knew that the liquid was either acetone, benzene, chloroform, or carbon tetrachloride (which have densities of 0.792 g/cm3, 0.899 g/cm3, 1.489 g/cm3, and 1.595 g/cm3, respectively). What was the identity of the liquid?
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of ZybanⓇ:
1. Write a mechanism for the bromination of m-chloropropiophenone.
Br₂
CH2Cl2
Cl
Br
2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks).
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 1 Solutions
General Chemistry - Standalone book (MindTap Course List)
Ch. 1.3 - You place 1.85 grams of wood in a vessel with 9.45...Ch. 1.4 - Potassium is a soft, silvery-colored metal that...Ch. 1.4 - Matter can be represented as being composed of...Ch. 1.5 - Give answers to the following arithmetic setups....Ch. 1.5 - a. When you report your weight to someone, how...Ch. 1.6 - Express the following quantities using an SI...Ch. 1.6 - a. A person with a fever has a temperature of...Ch. 1.6 - Prob. 1.3CCCh. 1.7 - A piece of metal wire has a volume of 20.2 cm3 and...Ch. 1.7 - Ethanol (grain alcohol) has a density of 0.789...
Ch. 1.7 - You are working in the office of a precious metals...Ch. 1.8 - The oxygen molecule (the smallest particle of...Ch. 1.8 - A large crystal is constructed by stacking small,...Ch. 1.8 - Using the definitions 1 in. = 2.54 cm and 1 yd =...Ch. 1 - Discuss some ways in which chemistry has changed...Ch. 1 - Define the terms experiment and theory. How are...Ch. 1 - Illustrate the steps in the scientific method...Ch. 1 - Define the terms matter and mass. What is the...Ch. 1 - Prob. 1.5QPCh. 1 - Prob. 1.6QPCh. 1 - Characterize gases, liquids, and solids in terms...Ch. 1 - Prob. 1.8QPCh. 1 - Give examples of an element, a compound, a...Ch. 1 - What phases or states of matter are present in a...Ch. 1 - What distinguishes an element from a compound? Can...Ch. 1 - Prob. 1.12QPCh. 1 - Prob. 1.13QPCh. 1 - Prob. 1.14QPCh. 1 - How does the International System (SI) obtain...Ch. 1 - Prob. 1.16QPCh. 1 - Prob. 1.17QPCh. 1 - Why should units be carried along with numbers in...Ch. 1 - When the quantity 12.9 g is added to 2 1002 g,...Ch. 1 - Prob. 1.20QPCh. 1 - A 75.0-g sample of a pure liquid, liquid A, with a...Ch. 1 - Which of the following represents the smallest...Ch. 1 - Physical and Chemical Changes Say you are...Ch. 1 - a Sodium metal is partially melted. What are the...Ch. 1 - A material is believed to be a compound. Suppose...Ch. 1 - You need a thermometer that is accurate to 5C to...Ch. 1 - Imagine that you get the chance to shoot five...Ch. 1 - Say you live in a climate where the temperature...Ch. 1 - You are presented with a piece of metal in a jar....Ch. 1 - You have two identical boxes with interior...Ch. 1 - Consider the following compounds and their...Ch. 1 - Which of the following items have a mass of about...Ch. 1 - What is the length of the nail reported to the...Ch. 1 - For these questions, be sure to apply the rules...Ch. 1 - You are teaching a class of second graders some...Ch. 1 - A 15.5 g sample of sodium carbonate is added to a...Ch. 1 - Some iron wire weighing 5.6 g is placed in a...Ch. 1 - Zinc metal reacts with yellow crystals of sulfur...Ch. 1 - Aluminum metal reacts with bromine, a red-brown...Ch. 1 - Give the normal state (solid, liquid, or gas) of...Ch. 1 - Give the normal state (solid, liquid, or gas) of...Ch. 1 - Which of the following are physical changes and...Ch. 1 - For each of the following, decide whether a...Ch. 1 - A sample of mercury(II) oxide was heated to...Ch. 1 - Solid iodine, contaminated with salt, was heated...Ch. 1 - The following are properties of substances. Decide...Ch. 1 - Decide whether each of the following is a physical...Ch. 1 - Iodine is a solid having somewhat lustrous,...Ch. 1 - Mercury(II) oxide is an orange-red solid with a...Ch. 1 - Consider the following separations of materials....Ch. 1 - All of the following processes involve a...Ch. 1 - Label each of the following as a substance, a...Ch. 1 - Indicate whether each of the following materials...Ch. 1 - Which of the following are pure substances and...Ch. 1 - Which of the following are pure substances and...Ch. 1 - How many significant figures are there in each of...Ch. 1 - How many significant figures are there in each of...Ch. 1 - The circumference of the earth at the equator is...Ch. 1 - The astronomical unit equals the mean distance...Ch. 1 - Assuming all numbers are measured quantities, do...Ch. 1 - Assuming all numbers are measured quantities, do...Ch. 1 - Prob. 1.63QPCh. 1 - Prob. 1.64QPCh. 1 - Write the following measurements, without...Ch. 1 - Write the following measurements, without...Ch. 1 - Using scientific notation, convert: a 6.15 ps to s...Ch. 1 - Using scientific notation, convert: a 6.20 km to m...Ch. 1 - Convert: a 68F to degrees Celsius b 23F to degrees...Ch. 1 - Convert: a 51F to degrees Celsius b 11F to degrees...Ch. 1 - Salt and ice are stirred together to give a...Ch. 1 - Prob. 1.72QPCh. 1 - A certain sample of the mineral galena (lead...Ch. 1 - A flask contains a 30.0 mL sample of acetone (nail...Ch. 1 - A liquid with a volume of 8.5 mL has a mass of...Ch. 1 - Prob. 1.76QPCh. 1 - Platinum has a density of 21.4 g/cm3. What is the...Ch. 1 - What is the mass of a 43.8-mL sample of gasoline,...Ch. 1 - Ethanol has a density of 0.789 g/cm3. What volume...Ch. 1 - Bromine is a red-brown liquid with a density of...Ch. 1 - Sodium hydrogen carbonate, known commercially as...Ch. 1 - The acidic constituent in vinegar is acetic acid....Ch. 1 - The different colors of light have different...Ch. 1 - Water consists of molecules (groups of atoms). A...Ch. 1 - The total amount of fresh water on earth is...Ch. 1 - A submicroscopic particle suspended in a solution...Ch. 1 - How many grams are there in 3.58 short tons? Note...Ch. 1 - Prob. 1.88QPCh. 1 - The first measurement of sea depth was made in...Ch. 1 - The estimated amount of recoverable oil from the...Ch. 1 - A fish tank is 24.2 in. long, 15.9 in. deep, and...Ch. 1 - The population density of worms in a particular...Ch. 1 - Prob. 1.93QPCh. 1 - An antacid tablet weighing 0.853 g contained...Ch. 1 - When a mixture of aluminum powder and iron(III)...Ch. 1 - When chlorine gas is bubbled into a solution of...Ch. 1 - A beaker weighed 50.90 g. To the beaker was added...Ch. 1 - Prob. 1.98QPCh. 1 - Describe each of the following as a physical or...Ch. 1 - Describe each of the following as a physical or...Ch. 1 - Analyses of several samples of a material...Ch. 1 - A red-orange solid contains only mercury and...Ch. 1 - A cubic box measures 39.3 cm on an edge. What is...Ch. 1 - A cylinder with circular cross section has a...Ch. 1 - An aquarium has a rectangular cross section that...Ch. 1 - A spherical tank has a radius of 175.0 in....Ch. 1 - Obtain the difference in volume between two...Ch. 1 - What is the difference in surface area between two...Ch. 1 - Perform the following arithmetic setups and...Ch. 1 - Prob. 1.110QPCh. 1 - For each of the following, write the measurement...Ch. 1 - For each of the following, write the measurement...Ch. 1 - Write each of the following in terms of the SI...Ch. 1 - Write each of the following in terms of the SI...Ch. 1 - Tungsten metal, which is used in lightbulb...Ch. 1 - Titanium metal is used in aerospace alloys to add...Ch. 1 - Calcium carbonate, a white powder used in...Ch. 1 - Prob. 1.118QPCh. 1 - Gallium metal can be melted by the heat of ones...Ch. 1 - Mercury metal is liquid at normal temperatures but...Ch. 1 - Zinc metal can be purified by distillation...Ch. 1 - Iodine is a bluish-black solid. It forms a...Ch. 1 - An aluminum alloy used in the construction of...Ch. 1 - Vanadium metal is added to steel to impart...Ch. 1 - The density of quartz mineral was determined by...Ch. 1 - Prob. 1.126QPCh. 1 - Some bottles of colorless liquids were being...Ch. 1 - Providing no reaction occurs, a solid will float...Ch. 1 - Platinum metal is used in jewelry; it is also used...Ch. 1 - Ultrapure silicon is used to make solid-state...Ch. 1 - Vinegar contains acetic acid (about 5% by mass)....Ch. 1 - Ethyl acetate has a characteristic fruity odor and...Ch. 1 - Prob. 1.133QPCh. 1 - Prob. 1.134QPCh. 1 - Convert; a 5.91 kg of chrome yellow to milligrams...Ch. 1 - Convert: a 7.19 g of cyanocobalamin (vitamin B12)...Ch. 1 - The largest of the Great Lakes is Lake Superior,...Ch. 1 - The average flow of the Niagara River is 3.50 km3...Ch. 1 - A room measures 10.0 ft 11.0 ft and is 9.0 ft...Ch. 1 - Prob. 1.140QPCh. 1 - The masses of diamonds and gems are measured in...Ch. 1 - One year of world production of gold was 49.6 106...Ch. 1 - Prob. 1.143QPCh. 1 - All good experiments start with a scientific...Ch. 1 - Prob. 1.145QPCh. 1 - Prob. 1.146QPCh. 1 - Prob. 1.147QPCh. 1 - A 33.0-g sample of an unknown liquid at 20.0C is...Ch. 1 - A 124-g sample of a pure liquid, liquid A, with a...Ch. 1 - On a long trip you travel 832 miles in 21 hours....Ch. 1 - The density of lead at 20C is 11.3 g/cm3. Rank the...Ch. 1 - Prob. 1.152QPCh. 1 - Prob. 1.153QPCh. 1 - The density of liquid water at 80C is 972 kg/m3...Ch. 1 - Prob. 1.155QPCh. 1 - At 20C liquid gasoline gas has a density of 0.75...Ch. 1 - The figures below represent a gas trapped in...Ch. 1 - An ice cube measures 3.50 cm on each edge and...Ch. 1 - The total length of all the DNA molecules...Ch. 1 - Prospectors are considering searching for gold on...Ch. 1 - A solution is prepared by dissolving table salt,...Ch. 1 - Water and saline (salt) solution have in common...Ch. 1 - When 11.1 g of marble chips (calcium carbonate) is...Ch. 1 - Zinc ore (zinc sulfide) is treated with sulfuric...Ch. 1 - A steel sphere has a radius of 1.58 in. If this...Ch. 1 - A weather balloon filled with helium has a...Ch. 1 - Prob. 1.167QPCh. 1 - Prob. 1.168QPCh. 1 - A sample of an ethanolwater solution has a volume...Ch. 1 - You have a piece of gold jewelry weighing 9.35 g....Ch. 1 - A sample of vermilion-colored mineral was weighed...Ch. 1 - A sample of a bright blue mineral was weighed in...Ch. 1 - Prob. 1.173QPCh. 1 - An experimenter places a piece of a solid metal...Ch. 1 - Prob. 1.175QPCh. 1 - The expected outcome for the amount of sugar in a...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Synthesis of Ibuprofen-Part 2: 1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how to make naproxen from the compound below. Show all intermediates and reagents in your synthesis. Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction steps would need to change/add? 3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardAcid Catalyzed Aromatization of Carvone: 1. Starting with the ketone, below, draw a mechanism for the reaction to give the phenol as shown. H2SO4 HO- H₂O 2. Why do we use CDCl instead of CHCl, for acquiring our NMR spectra? 3. Why does it not matter which enantiomer of carvone is used for this reaction? What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardAssign this H NMRarrow_forward
- Please complete these blanks need that asaparrow_forwardNitration of Methyl Benzoate: 1. Predict the major product for the reaction below AND provide a mechanism. Include ALL resonance structures for the intermediate. C(CH3)3 NO₂* ? 2. Assuming the stoichiometry is 1:1 for the reaction above, what volume of concentrated nitric acid would be required to mononitrate 0.50 grams of the compound above? What product(s) might you expect if you nitrated phenol instead of methyl benzoate? Explain your reasoning. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardSodium Borohydride Reduction (continued on the next page): 1. Draw the product of each of the reactions below and give the formula mass to the nearest whole number. ? (1) NaBH (2) acid (1) NaBD4 (2) acid ? 2. In mass spectra, alcohols typically break as shown in equation 8 in chapter 11 (refer to your lab manual). The larger group is generally lost and this gives rise to the base peak in the mass spectrum. For the products of each of the reactions in question # 1, draw the ion corresponding to the base peak for that product and give its mass to charge ratio (m/z). 3. Given the reaction below, calculate how many mg of 1-phenyl-1-butanol that can be produced using 31 mg NaBH4 and an excess of butyrophenone. 4. + NaBH4 OH (after workup with dilute HCI) What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forward
- Aspirin from Wintergreen: 1. In isolating the salicylic acid, why is it important to press out as much of the water as possible? Write a step-by-step mechanism for the esterification of salicylic acid with acetic anhydride catalyzed by concentrated H₂SO4. 3. Calculate the exact monoisotopic mass of aspirin showing your work. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardSynthesis of Ibuprofen-Part 1: 1. What characteristic absorption band changes would you expect in the IR spectrum on going from p-isobutylacetophenone to 1-(4-isobutylphenyl)-ethanol and then to 1-(4-isobutylphenyl)-1-choroethane as you did in the experiment today? Give approximate wavenumbers associated with each functional group change. Given that the mechanism of the chlorination reaction today involves formation of a benzylic carbocation, explain why the following rearranged product is not formed. محرم محمد 3. Why do we use dilute HCl for the first step of the reaction today and concentrated HCI for the second step? What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardAssign only the C NMRarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Measurement and Significant Figures; Author: Professor Dave Explains;https://www.youtube.com/watch?v=Gn97hpEkTiM;License: Standard YouTube License, CC-BY
Trigonometry: Radians & Degrees (Section 3.2); Author: Math TV with Professor V;https://www.youtube.com/watch?v=U5a9e1J_V1Y;License: Standard YouTube License, CC-BY