Chemistry: Atoms First
3rd Edition
ISBN: 9781259923142
Author: Burdge
Publisher: MCG
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Chapter 1, Problem 1.104QP
Interpretation Introduction
Interpretation: For the given details,
it should be converted the given rate to dollars per Littre of gas
It should be determined the cost to boil a 2.1 L kettle of water
Concept introduction:
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 1 Solutions
Chemistry: Atoms First
Ch. 1.2 - illustrates conversions between these two...Ch. 1.2 - Prob. 1PPACh. 1.2 - According to the website of the National...Ch. 1.2 - If a single degree on the Celsius scale is...Ch. 1.2 - A body temperature above 39C constitutes a high...Ch. 1.2 - The average temperature at the summit of Mt....Ch. 1.2 - Prob. 2PPBCh. 1.2 - If a single degree on the Fahrenheit scale is...Ch. 1.2 - Prob. 1.3WECh. 1.2 - Given that 20.0 mL of mercury has a mass of 272 g....
Ch. 1.2 - Prob. 3PPBCh. 1.2 - Using the picture of the graduated cylinder and...Ch. 1.3 - Determine the number of significant figures in the...Ch. 1.3 - Determine the number of significant figures in the...Ch. 1.3 - Using scientific notation, express the number one...Ch. 1.3 - Perform the following arithmetic operations and...Ch. 1.3 - Perform the following arithmetic operations, and...Ch. 1.3 - Prob. 5PPBCh. 1.3 - Prob. 1.6WECh. 1.3 - Prob. 6PPACh. 1.3 - Prob. 6PPBCh. 1.3 - Several pieces of aluminum metal with a total mass...Ch. 1.4 - The Food and Drug Administration (FDA) recommends...Ch. 1.4 - The American Heart Association recommends that...Ch. 1.4 - A gold nugget has a mass of 0.9347 oz. What is its...Ch. 1.4 - The diagram contains several objects that are...Ch. 1.4 - Prob. 1.8WECh. 1.4 - Prob. 8PPACh. 1.4 - The density of mercury is 13.6 g/cm3. What is its...Ch. 1.4 - Each diagram [(i) or (ii)] shows the objects...Ch. 1 - Prob. 1.1QPCh. 1 - Explain what is meant by the scientific method.Ch. 1 - What is the difference between a hypothesis and a...Ch. 1 - Classily each of the following statements as a...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Name the SI base units that are important in...Ch. 1 - Write the numbers represented by the following...Ch. 1 - What units do chemists normally use for the...Ch. 1 - What is the difference between mass and weight? If...Ch. 1 - Prob. 1.10QPCh. 1 - Prob. 1.11QPCh. 1 - Prob. 1.12QPCh. 1 - Prob. 1.13QPCh. 1 - Prob. 1.14QPCh. 1 - The density of water at 40C is 0.992 g/mL. What is...Ch. 1 - Prob. 1.16QPCh. 1 - Prob. 1.17QPCh. 1 - Prob. 1.18QPCh. 1 - Prob. 1.19QPCh. 1 - Prob. 1.20QPCh. 1 - Indicate which of the following numbers is an...Ch. 1 - Prob. 1.22QPCh. 1 - Distinguish between the terms accuracy and...Ch. 1 - Express the following numbers in scientific...Ch. 1 - Prob. 1.25QPCh. 1 - Prob. 1.26QPCh. 1 - Express the answers to the following calculations...Ch. 1 - Determine the number of significant figures in...Ch. 1 - Prob. 1.29QPCh. 1 - Carry out the following operations as if they were...Ch. 1 - Prob. 1.31QPCh. 1 - Three students (A, B, and C) are asked to...Ch. 1 - Prob. 1.33QPCh. 1 - Prob. 1.34QPCh. 1 - Prob. 1.35QPCh. 1 - The density of the metal bar shown is 8.16 g/cm3....Ch. 1 - The following shows an experiment used to...Ch. 1 - Prob. 1.38QPCh. 1 - Prob. 1.39QPCh. 1 - Prob. 1.40QPCh. 1 - Carry out the following conversions: (a) 1.1 1022...Ch. 1 - The average speed of helium at 25C is 1255 m/s....Ch. 1 - Prob. 1.43QPCh. 1 - Prob. 1.44QPCh. 1 - Prob. 1.45QPCh. 1 - Prob. 1.46QPCh. 1 - Prob. 1.47QPCh. 1 - Prob. 1.48QPCh. 1 - Prob. 1.49QPCh. 1 - Prob. 1.50QPCh. 1 - Prob. 1.51QPCh. 1 - Prob. 1.52QPCh. 1 - The density of ammonia gas under certain...Ch. 1 - Prob. 1.54QPCh. 1 - Prob. 1.55QPCh. 1 - Prob. 1.56QPCh. 1 - Prob. 1.57QPCh. 1 - Classify each of the following as a pure...Ch. 1 - What is the difference between a qualitative...Ch. 1 - Prob. 1.60QPCh. 1 - Prob. 1.61QPCh. 1 - Determine which of the following properties are...Ch. 1 - Prob. 1.63QPCh. 1 - Determine whether the following statements...Ch. 1 - Determine whether each of the following describes...Ch. 1 - Determine whether each of the following describes...Ch. 1 - ADDITIONAL PROBLEMS 1.67 Using the appropriate...Ch. 1 - Prob. 1.68QPCh. 1 - Winch of the following statements describe...Ch. 1 - Prob. 1.70QPCh. 1 - Prob. 1.71QPCh. 1 - In determining the density of a rectangular metal...Ch. 1 - Prob. 1.73QPCh. 1 - Prob. 1.74QPCh. 1 - Prob. 1.75QPCh. 1 - Prob. 1.76QPCh. 1 - A piece of platinum metal weighing 234.0 g is...Ch. 1 - The experiment described in Problem 1.77 is a...Ch. 1 - A copper sphere has a mass of 2.17 103 g. and its...Ch. 1 - Lithium has a very low density (density = 0.53...Ch. 1 - Prob. 1.81QPCh. 1 - Vanillin (used to flavor vanilla ice cream and...Ch. 1 - Prob. 1.83QPCh. 1 - Prob. 1.84QPCh. 1 - Prob. 1.85QPCh. 1 - Prob. 1.86QPCh. 1 - Prob. 1.87QPCh. 1 - Magnesium is used in alloys, in batteries, and in...Ch. 1 - Prob. 1.89QPCh. 1 - The surface area and average depth of the Pacific...Ch. 1 - Calculate the percent error for the following...Ch. 1 - Prob. 1.92QPCh. 1 - Chalcopyrite contains 34.63 percent copper by...Ch. 1 - Prob. 1.94QPCh. 1 - One gallon of gasoline in an automobile's engine...Ch. 1 - Prob. 1.96QPCh. 1 - The worlds total petroleum reserve is estimated at...Ch. 1 - Prob. 1.98QPCh. 1 - Prob. 1.99QPCh. 1 - Chlorine is used to disinfect swimming pools. The...Ch. 1 - Prob. 1.101QPCh. 1 - Prob. 1.102QPCh. 1 - Prob. 1.103QPCh. 1 - Prob. 1.104QPCh. 1 - Prob. 1.105QPCh. 1 - Prob. 1.106QPCh. 1 - Prob. 1.107QPCh. 1 - Prob. 1.108QPCh. 1 - Prob. 1.109QPCh. 1 - Prob. 1.110QPCh. 1 - In January 2009, the National Aeronautics and...Ch. 1 - Prob. 1.112QPCh. 1 - Prob. 1.113QPCh. 1 - Prob. 1.114QPCh. 1 - Prob. 1.115QPCh. 1 - The composition of pennies has changed over the...
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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