
Chemistry: Atoms First
3rd Edition
ISBN: 9781259923142
Author: Burdge
Publisher: MCG
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Question
Chapter 1.3, Problem 1.6WE
Interpretation Introduction
Interpretation:
The density of the gas should be calculated with giving the appropriate significant figure.
Concept Introduction:
Density: The density of the substance is calculated using the formula:
For the given set of calculations the significant figures and their correct measurement has to be given.
Significant figures: The digits having a meaning in a given number are called as significant figures.
Significant figures –calculation rules
- Significant figure is a non-zero number (4443.2 has five significant figures)
- Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
- Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
- Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
- Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures). In this cases use scientific notation to avoid ambiguity.
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Review of this week's reaction:
H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O --->
H₂NC(=NH)N(CH3)CH2COOH (creatine)
Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing
the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts)
Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts)
Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3
pts)
NH2(C=NH)-N(CH)CH2COOH
This bond
Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem
Q9 is valid). (4 pts)
Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should
be ready to understand the first half of one of the Grignard reactions presented in a past…
Propose a synthesis pathway for the
following transformations. b) c) d)
Chapter 1 Solutions
Chemistry: Atoms First
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