General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 0.2, Problem 0.1P
Express the following quantities in scientific notation:
- (a) The diameter of a sodium atom, 0.000000000372 m
- (b) The distance from the Earth to the Sun, 150,000,000,000 m
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
Check
Br
(Choose one)
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
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HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
OA
B
OC
ch
B
C
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 0 Solutions
General Chemistry: Atoms First
Ch. 0.2 - Express the following quantities in scientific...Ch. 0.2 - What units do the following abbreviations...Ch. 0.5 - The normal body temperature of a healthy adult...Ch. 0.5 - Carry out the indicated temperature conversions....Ch. 0.7 - Prob. 0.5PCh. 0.7 - Chloroform, a substance once used as an...Ch. 0.8 - Prob. 0.7PCh. 0.9 - A 1.000 mL sample of acetone, a common solvent...Ch. 0.9 - Prob. 0.9PCh. 0.9 - Characterize each of the following dartboards...
Ch. 0.10 - Prob. 0.11PCh. 0.10 - Carry out the following calculations, expressing...Ch. 0.10 - What is the temperature reading on the following...Ch. 0.11 - Calculate answers to the following problems, and...Ch. 0.11 - Gemstones are weighed in carats, with 1 carat =...Ch. 0.11 - A pure diamond with a mass of 0.1000 g contains...Ch. 0.11 - Oxalic acid, found in dark-green leafy vegetables...Ch. 0 - Which block in each of the following drawings of a...Ch. 0 - How many milliliters of water does the graduated...Ch. 0 - Assume that you have two graduated cylinders, one...Ch. 0 - The following cylinder contains three liquids that...Ch. 0 - What is the difference between mass and weight?Ch. 0 - What is the difference between a derived SI unit...Ch. 0 - What SI units are used for measuring the following...Ch. 0 - What SI prefix corresponds to each of the...Ch. 0 - Prob. 0.26SPCh. 0 - Prob. 0.27SPCh. 0 - Prob. 0.28SPCh. 0 - Prob. 0.29SPCh. 0 - Prob. 0.30SPCh. 0 - Prob. 0.31SPCh. 0 - Prob. 0.32SPCh. 0 - Prob. 0.33SPCh. 0 - Prob. 0.34SPCh. 0 - Prob. 0.35SPCh. 0 - Prob. 0.36SPCh. 0 - Prob. 0.37SPCh. 0 - Prob. 0.38SPCh. 0 - Prob. 0.39SPCh. 0 - How many significant figures are in each of the...Ch. 0 - Prob. 0.41SPCh. 0 - The Vehicle Assembly Building at the John F....Ch. 0 - Prob. 0.43SPCh. 0 - Prob. 0.44SPCh. 0 - Prob. 0.45SPCh. 0 - Prob. 0.46SPCh. 0 - Prob. 0.47SPCh. 0 - Express the results of the following calculations...Ch. 0 - Prob. 0.49SPCh. 0 - Prob. 0.50SPCh. 0 - Prob. 0.51SPCh. 0 - The normal body temperature of a goat is 39.9C,...Ch. 0 - Prob. 0.53SPCh. 0 - Prob. 0.54SPCh. 0 - Prob. 0.55SPCh. 0 - Prob. 0.56SPCh. 0 - Answer parts (a)(d) of Problem 0.56 assuming that...Ch. 0 - The density of silver is 10.5 g/cm3. What is the...Ch. 0 - Prob. 0.59SPCh. 0 - Prob. 0.60SPCh. 0 - Gaseous hydrogen has a density of 0.0899 g/L at...Ch. 0 - Prob. 0.62SPCh. 0 - Prob. 0.63SPCh. 0 - Prob. 0.64SPCh. 0 - Prob. 0.65SPCh. 0 - Prob. 0.66SPCh. 0 - Prob. 0.67SPCh. 0 - Prob. 0.68SPCh. 0 - Prob. 0.69SPCh. 0 - Prob. 0.70SPCh. 0 - Prob. 0.71SPCh. 0 - Prob. 0.72SPCh. 0 - Prob. 0.73SPCh. 0 - Prob. 0.74CHPCh. 0 - Prob. 0.75CHPCh. 0 - Sodium chloride has a melting point of 1074 K and...Ch. 0 - Prob. 0.77CHPCh. 0 - Prob. 0.78CHPCh. 0 - Prob. 0.79CHPCh. 0 - Prob. 0.80CHPCh. 0 - Prob. 0.81CHPCh. 0 - Prob. 0.82CHPCh. 0 - Vinaigrette salad dressing consists mainly of...Ch. 0 - At a certain point, the Celsius and Fahrenheit...Ch. 0 - Prob. 0.85CHPCh. 0 - Prob. 0.86CHPCh. 0 - An Eastern diamondback rattlesnake was milked...Ch. 0 - Prob. 0.88CHPCh. 0 - Prob. 0.89CHPCh. 0 - Prob. 0.90CHPCh. 0 - Ocean currents are measured in sverdrups (Sv)...Ch. 0 - Prob. 0.92CHPCh. 0 - Prob. 0.93CHP
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- calculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forwardtrue or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forward
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