General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 0.2, Problem 0.1P
Express the following quantities in scientific notation:
- (a) The diameter of a sodium atom, 0.000000000372 m
- (b) The distance from the Earth to the Sun, 150,000,000,000 m
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Problem 3. Provide a mechanism for the following transformation:
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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
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Draw the missing reagent X you think will make this synthesis work in the drawing area below.
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There is no reagent that will make this synthesis work without complications.
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Predict the major products of this organic reaction:
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Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
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Chapter 0 Solutions
General Chemistry: Atoms First
Ch. 0.2 - Express the following quantities in scientific...Ch. 0.2 - What units do the following abbreviations...Ch. 0.5 - The normal body temperature of a healthy adult...Ch. 0.5 - Carry out the indicated temperature conversions....Ch. 0.7 - Prob. 0.5PCh. 0.7 - Chloroform, a substance once used as an...Ch. 0.8 - Prob. 0.7PCh. 0.9 - A 1.000 mL sample of acetone, a common solvent...Ch. 0.9 - Prob. 0.9PCh. 0.9 - Characterize each of the following dartboards...
Ch. 0.10 - Prob. 0.11PCh. 0.10 - Carry out the following calculations, expressing...Ch. 0.10 - What is the temperature reading on the following...Ch. 0.11 - Calculate answers to the following problems, and...Ch. 0.11 - Gemstones are weighed in carats, with 1 carat =...Ch. 0.11 - A pure diamond with a mass of 0.1000 g contains...Ch. 0.11 - Oxalic acid, found in dark-green leafy vegetables...Ch. 0 - Which block in each of the following drawings of a...Ch. 0 - How many milliliters of water does the graduated...Ch. 0 - Assume that you have two graduated cylinders, one...Ch. 0 - The following cylinder contains three liquids that...Ch. 0 - What is the difference between mass and weight?Ch. 0 - What is the difference between a derived SI unit...Ch. 0 - What SI units are used for measuring the following...Ch. 0 - What SI prefix corresponds to each of the...Ch. 0 - Prob. 0.26SPCh. 0 - Prob. 0.27SPCh. 0 - Prob. 0.28SPCh. 0 - Prob. 0.29SPCh. 0 - Prob. 0.30SPCh. 0 - Prob. 0.31SPCh. 0 - Prob. 0.32SPCh. 0 - Prob. 0.33SPCh. 0 - Prob. 0.34SPCh. 0 - Prob. 0.35SPCh. 0 - Prob. 0.36SPCh. 0 - Prob. 0.37SPCh. 0 - Prob. 0.38SPCh. 0 - Prob. 0.39SPCh. 0 - How many significant figures are in each of the...Ch. 0 - Prob. 0.41SPCh. 0 - The Vehicle Assembly Building at the John F....Ch. 0 - Prob. 0.43SPCh. 0 - Prob. 0.44SPCh. 0 - Prob. 0.45SPCh. 0 - Prob. 0.46SPCh. 0 - Prob. 0.47SPCh. 0 - Express the results of the following calculations...Ch. 0 - Prob. 0.49SPCh. 0 - Prob. 0.50SPCh. 0 - Prob. 0.51SPCh. 0 - The normal body temperature of a goat is 39.9C,...Ch. 0 - Prob. 0.53SPCh. 0 - Prob. 0.54SPCh. 0 - Prob. 0.55SPCh. 0 - Prob. 0.56SPCh. 0 - Answer parts (a)(d) of Problem 0.56 assuming that...Ch. 0 - The density of silver is 10.5 g/cm3. What is the...Ch. 0 - Prob. 0.59SPCh. 0 - Prob. 0.60SPCh. 0 - Gaseous hydrogen has a density of 0.0899 g/L at...Ch. 0 - Prob. 0.62SPCh. 0 - Prob. 0.63SPCh. 0 - Prob. 0.64SPCh. 0 - Prob. 0.65SPCh. 0 - Prob. 0.66SPCh. 0 - Prob. 0.67SPCh. 0 - Prob. 0.68SPCh. 0 - Prob. 0.69SPCh. 0 - Prob. 0.70SPCh. 0 - Prob. 0.71SPCh. 0 - Prob. 0.72SPCh. 0 - Prob. 0.73SPCh. 0 - Prob. 0.74CHPCh. 0 - Prob. 0.75CHPCh. 0 - Sodium chloride has a melting point of 1074 K and...Ch. 0 - Prob. 0.77CHPCh. 0 - Prob. 0.78CHPCh. 0 - Prob. 0.79CHPCh. 0 - Prob. 0.80CHPCh. 0 - Prob. 0.81CHPCh. 0 - Prob. 0.82CHPCh. 0 - Vinaigrette salad dressing consists mainly of...Ch. 0 - At a certain point, the Celsius and Fahrenheit...Ch. 0 - Prob. 0.85CHPCh. 0 - Prob. 0.86CHPCh. 0 - An Eastern diamondback rattlesnake was milked...Ch. 0 - Prob. 0.88CHPCh. 0 - Prob. 0.89CHPCh. 0 - Prob. 0.90CHPCh. 0 - Ocean currents are measured in sverdrups (Sv)...Ch. 0 - Prob. 0.92CHPCh. 0 - Prob. 0.93CHP
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- For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टेarrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. དྲ。 ✗MgBr ? O CI Will the first product that forms in this reaction create a new C-C bond? Yes No • ? Will the first product that forms in this reaction create a new CC bond? Yes No × : ☐ Xarrow_forwardPredict the major products of this organic reaction: OH NaBH4 H ? CH3OH Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. ☐ : Sarrow_forward
- Predict the major products of this organic reaction: 1. LIAIHA 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. X : ☐arrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©arrow_forwardAs the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G marrow_forward
- Including activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.arrow_forwardgive example for the following(by equation) a. Converting a water insoluble compound to a soluble one. b. Diazotization reaction form diazonium salt c. coupling reaction of a diazonium salt d. indacator properties of MO e. Diazotization ( diazonium salt of bromobenzene)arrow_forward2-Propanone and ethyllithium are mixed and subsequently acid hydrolyzed. Draw and name the structures of the products.arrow_forward
- (Methanesulfinyl)methane is reacted with NaH, and then with acetophenone. Draw and name the structures of the products.arrow_forward3-Oxo-butanenitrile and (E)-2-butenal are mixed with sodium ethoxide in ethanol. Draw and name the structures of the products.arrow_forwardWhat is the reason of the following(use equations if possible) a.) In MO preperation through diazotization: Addition of sodium nitrite in acidfied solution in order to form diazonium salt b.) in MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at low pH c.) In MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at pH 4.5 d.) Avoiding not cooling down the reaction mixture when preparing the diazonium salt e.) Cbvcarrow_forward
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