General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 0.11, Problem 0.15P
Gemstones are weighed in carats, with 1 carat = 200 mg (exactly). What is the mass in grams of the Hope Diamond, the world’s largest blue diamond at 44.4 carats? What is this mass in ounces?
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The structure of compound 1,3,5-trimethylbenzene (mesitylene) is given below.
How many signals would you expect to find in the 'H NMR spectrum of 1,3,5-trimethylbenzene (mesitylene)?
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×
1
How many signals do you expect in the 'H NMR spectrum for this molecule?
CI CI
Cl
Write the answer in the table below.
Also, in each of the drawing areas below is a copy of the molecule, with H atoms shown. In each copy, one of the H atoms is highlighted red. Highlight in red all
other H atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: Remember, a multiplet is considered one signal in the 'H NMR spectrum.
1
Number of signals in the 'H NMR spectrum.
☐
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same
signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional H atoms to highlight in
top molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the
same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at…
wrtie the balanced equation and find the E° when the following half- reactions are combined
Zn2+(aq) + 2e---> Zn(s) E°= -0.763V
Ag+(aq) + e---> Ag (s) E°=+0.799V
Chapter 0 Solutions
General Chemistry: Atoms First
Ch. 0.2 - Express the following quantities in scientific...Ch. 0.2 - What units do the following abbreviations...Ch. 0.5 - The normal body temperature of a healthy adult...Ch. 0.5 - Carry out the indicated temperature conversions....Ch. 0.7 - Prob. 0.5PCh. 0.7 - Chloroform, a substance once used as an...Ch. 0.8 - Prob. 0.7PCh. 0.9 - A 1.000 mL sample of acetone, a common solvent...Ch. 0.9 - Prob. 0.9PCh. 0.9 - Characterize each of the following dartboards...
Ch. 0.10 - Prob. 0.11PCh. 0.10 - Carry out the following calculations, expressing...Ch. 0.10 - What is the temperature reading on the following...Ch. 0.11 - Calculate answers to the following problems, and...Ch. 0.11 - Gemstones are weighed in carats, with 1 carat =...Ch. 0.11 - A pure diamond with a mass of 0.1000 g contains...Ch. 0.11 - Oxalic acid, found in dark-green leafy vegetables...Ch. 0 - Which block in each of the following drawings of a...Ch. 0 - How many milliliters of water does the graduated...Ch. 0 - Assume that you have two graduated cylinders, one...Ch. 0 - The following cylinder contains three liquids that...Ch. 0 - What is the difference between mass and weight?Ch. 0 - What is the difference between a derived SI unit...Ch. 0 - What SI units are used for measuring the following...Ch. 0 - What SI prefix corresponds to each of the...Ch. 0 - Prob. 0.26SPCh. 0 - Prob. 0.27SPCh. 0 - Prob. 0.28SPCh. 0 - Prob. 0.29SPCh. 0 - Prob. 0.30SPCh. 0 - Prob. 0.31SPCh. 0 - Prob. 0.32SPCh. 0 - Prob. 0.33SPCh. 0 - Prob. 0.34SPCh. 0 - Prob. 0.35SPCh. 0 - Prob. 0.36SPCh. 0 - Prob. 0.37SPCh. 0 - Prob. 0.38SPCh. 0 - Prob. 0.39SPCh. 0 - How many significant figures are in each of the...Ch. 0 - Prob. 0.41SPCh. 0 - The Vehicle Assembly Building at the John F....Ch. 0 - Prob. 0.43SPCh. 0 - Prob. 0.44SPCh. 0 - Prob. 0.45SPCh. 0 - Prob. 0.46SPCh. 0 - Prob. 0.47SPCh. 0 - Express the results of the following calculations...Ch. 0 - Prob. 0.49SPCh. 0 - Prob. 0.50SPCh. 0 - Prob. 0.51SPCh. 0 - The normal body temperature of a goat is 39.9C,...Ch. 0 - Prob. 0.53SPCh. 0 - Prob. 0.54SPCh. 0 - Prob. 0.55SPCh. 0 - Prob. 0.56SPCh. 0 - Answer parts (a)(d) of Problem 0.56 assuming that...Ch. 0 - The density of silver is 10.5 g/cm3. What is the...Ch. 0 - Prob. 0.59SPCh. 0 - Prob. 0.60SPCh. 0 - Gaseous hydrogen has a density of 0.0899 g/L at...Ch. 0 - Prob. 0.62SPCh. 0 - Prob. 0.63SPCh. 0 - Prob. 0.64SPCh. 0 - Prob. 0.65SPCh. 0 - Prob. 0.66SPCh. 0 - Prob. 0.67SPCh. 0 - Prob. 0.68SPCh. 0 - Prob. 0.69SPCh. 0 - Prob. 0.70SPCh. 0 - Prob. 0.71SPCh. 0 - Prob. 0.72SPCh. 0 - Prob. 0.73SPCh. 0 - Prob. 0.74CHPCh. 0 - Prob. 0.75CHPCh. 0 - Sodium chloride has a melting point of 1074 K and...Ch. 0 - Prob. 0.77CHPCh. 0 - Prob. 0.78CHPCh. 0 - Prob. 0.79CHPCh. 0 - Prob. 0.80CHPCh. 0 - Prob. 0.81CHPCh. 0 - Prob. 0.82CHPCh. 0 - Vinaigrette salad dressing consists mainly of...Ch. 0 - At a certain point, the Celsius and Fahrenheit...Ch. 0 - Prob. 0.85CHPCh. 0 - Prob. 0.86CHPCh. 0 - An Eastern diamondback rattlesnake was milked...Ch. 0 - Prob. 0.88CHPCh. 0 - Prob. 0.89CHPCh. 0 - Prob. 0.90CHPCh. 0 - Ocean currents are measured in sverdrups (Sv)...Ch. 0 - Prob. 0.92CHPCh. 0 - Prob. 0.93CHP
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- Consider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 'H NMR spectrum? Note: A multiplet is considered one signal. ☐arrow_forwardStudy this 'H NMR spectrum, and then answer the questions about it in the table below. Check 1.0- 0.5- 0.0 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 What unit symbol should be written on the horizontal axis? What is the chemical shift & of the doublet? If there is no doublet, just check the box instead. Give your answer to 2 significant digits. What is the chemical shift of the signal immediately upfield of the doublet? If there is no doublet, or no signal upfield of it, check the box instead. What is the chemical shift & of the least deshielded proton? If you can't tell without more information, check the box instead. 血 8 = ☐ There is no doublet. 8 = ☐ No such signal. 8 = 0 Need more information.arrow_forwardhow many moles of H2O2 are required to react with 11g of N2H4 according to the following reaction? (atomic weights: N=14.01, H=1.008, O= 16.00) 7H2O2 + N2H4 -> 2HNO3 + 8H20arrow_forward
- calculate the number of moles of H2 produced from 0.78 moles of Ga and 1.92 moles HCL? 2Ga+6HCL->2GaCl3+3H2arrow_forwardan adult human breathes 0.50L of air at 1 atm with each breath. If a 50L air tank at 200 atm is available, how man y breaths will the tank providearrow_forwardWhat are the advantages and/or disadvantages of using the MOHR titration method & AOEC method?arrow_forward
- Are there any alternative methods better than the MOHR titration to quantitatively determine salt in a sample?arrow_forwardhybridization of nitrogen of complex moleculesarrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO2 (g) = N2O4(g) AGº = -5.4 kJ Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system: Under these conditions, will the pressure of N2O4 tend to rise or fall? Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to '2' rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. 00 rise ☐ x10 fall yes no ☐ atm G Ar 1arrow_forward
- Why do we analyse salt?arrow_forwardCurved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. H H CH3OH, H+ H Select to Add Arrows H° 0:0 'H + Q HH ■ Select to Add Arrows CH3OH, H* H. H CH3OH, H+ HH ■ Select to Add Arrows i Please select a drawing or reagent from the question areaarrow_forwardWhat are examples of analytical methods that can be used to analyse salt in tomato sauce?arrow_forward
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