EBK STUDENT SOLUTIONS MANUAL TO ACCOMPA
7th Edition
ISBN: 9781119360902
Author: HYSLOP
Publisher: YUZU
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Textbook Question
Chapter 0, Problem 12PE
Practice Exercise 0.12
The definition of the size of the
Practice Exercise 0.12
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Students have asked these similar questions
n Feb 3
A
T
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4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how
you confirmed the structure.
5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of
Limonene.
6. (1 pts) Predict the 1H NMR spectral data of R-Limonene.
Proton NMR: 5.3 pon multiplet (H Ring
Part VI.
Ca H 10 O is the molecular formula of compound Tom and gives the
in the table below. Give a possible structure for compound Tom.
13C
Signals summarized
C1
C2
C3
C4
C5
C6
C7
13C shift (ppm)
23.5
27.0
33.0
35.8
127
162
205
DEPT-90
+
DEPT-135
+
+
2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at
373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and
molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.
Chapter 0 Solutions
EBK STUDENT SOLUTIONS MANUAL TO ACCOMPA
Ch. 0 - Practice Exercise 0.1
Using the chapter titles...Ch. 0 - Prob. 2PECh. 0 - Prob. 3PECh. 0 - Prob. 4PECh. 0 - Prob. 5PECh. 0 - Prob. 6PECh. 0 - Prob. 7PECh. 0 - Prob. 8PECh. 0 - Prob. 9PECh. 0 - Practice Exercise 0.10 Aluminum atoms have a mass...
Ch. 0 - Practice Exercise 0.11 How much heavier is the...Ch. 0 - Practice Exercise 0.12 The definition of the size...Ch. 0 - Practice Exercise 0.13 Naturally occurring boron...Ch. 0 - Practice Exercise 0.14
Neon, the gas used in neon...Ch. 0 - Prob. 1RQCh. 0 - 0.2 Knowing what we know today, which of the...Ch. 0 - 0.3 In what ways does the atomic theory affect the...Ch. 0 - Shake a few crystals of salt into your hand and...Ch. 0 - Are there any examples of crystals in nature that...Ch. 0 - 0.6 Heat is one form of energy. If a reaction...Ch. 0 - Can you think of a chemical reaction that starts...Ch. 0 - 0.8 Some large biological molecules rely on...Ch. 0 - 0.9 What elements were formed (a) during the first...Ch. 0 - Prob. 10RQCh. 0 - 0.11 What is the predominant element in the solar...Ch. 0 - Prob. 12RQCh. 0 - What physical factors caused elements and minerals...Ch. 0 - Is this separation still occurring on the earth?Ch. 0 - 0.15 What measuring devices did early chemists...Ch. 0 - 0.16 In your own words, describe how Daltons...Ch. 0 - Which of the laws of chemical combination is used...Ch. 0 - Prob. 18RQCh. 0 - Where in an atom is nearly all of its mass...Ch. 0 - What is a nucleon? Which ones have we studied?Ch. 0 - 0.21 How was the charge-to-mass ratio of the...Ch. 0 - 0.22 How did Robert Millikan determine the charge...Ch. 0 - How was the proton discovered?Ch. 0 - What experiment did Rutherford carry out to...Ch. 0 - Why dont we count the electrons when determining...Ch. 0 - Define the terms atomic number and mass number....Ch. 0 - Prob. 27RQCh. 0 - Write the symbols of the isotopes that contain the...Ch. 0 - What is wrong with the following statement? The...Ch. 0 - 0.30 The atomic number of silver, Ag, is 47 and it...Ch. 0 - A certain element X forms a compound with oxygen...Ch. 0 - Nitrogen reacts with a metal to form a compound in...Ch. 0 - Give the numbers of neutrons, protons, and...Ch. 0 - 0.34 Give the numbers of electrons, protons, and...Ch. 0 - Iodine-131 is used to treat overactive thyroids;...Ch. 0 - Prob. 36RQCh. 0 - 0.37 One chemical substance in natural gas is a...Ch. 0 - 0.38 Carbon tetrachloride contains one carbon and...Ch. 0 - If an atom of carbon-12 had been assigned a...Ch. 0 - 0.40 One atom of has a mass that is 9.0754 times...Ch. 0 - Naturally occurring copper is composed of 69.17%...Ch. 0 - Naturally occurring magnesium (one of the elements...Ch. 0 - N2O is often called nitrous oxide or laughing gas,...Ch. 0 - An element has 24 protons in its nucleus. (a)...Ch. 0 - Iron is composed of four isotopes with the...Ch. 0 - 0.46 What color are the protons, neutrons, and...Ch. 0 - 0.47 Immediately after the big bang, helium and...Ch. 0 - Prob. 48RQCh. 0 - Scientists often validate measurements, such as...Ch. 0 - Sir James Chadwick, discovered the neutron. The...
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- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
- 13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forwardPart III. Arrange the following carbons (in blue) in order of increasing chemical shift. HO B NH 2 A CIarrow_forward
- 6. Choose the compound that will produce the spectrum below and assign the signals as carbonyl, aryl, or alkyl. 100 ō (ppm) 50 0 7. 200 150 Assign all of the protons on the spectrum below. 8. A B 4 E C 3 ō (ppm) 2 1 0 Choose the compound that will produce the spectrum below and assign the signals to the corresponding protons. OH 6 OH 3 2 1 0 4 ō (ppm)arrow_forwardIn the Thermo Fisher application note about wine analysis (Lesson 3), the following chromatogram was collected of nine components of wine. If peak 3 has a retention time of 3.15 minutes and a peak width of 0.070 minutes, and peak 4 has a retention time of 3.24 minutes and a peak width of 0.075 minutes, what is the resolution factor between the two peaks? [Hint: it will help to review Lesson 2 for this question.] MAU 300 200 T 34 5 100- 1 2 CO 6 7 8 9 0 2.4 2.6 2.8 3.0 3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 5.2 Minutes 3.22 0.62 1.04 O 1.24arrow_forwardThe diagram shows two metals, A and B, which melt at 1000°C and 1400°C. State the weight percentage of the primary constituent (grains of C) that would be obtained by solidifying a 20% alloy of B. 1000°C a+L L+C 900°С 12 α a+C 45 1200 C L+y 140096 C+Y a+ß 800°C 700°C C+B 96 92 a+B 0 10 20 30 40 50 60 70 80 90 100 A % peso B Barrow_forward
- 8. Choose the compound that will produce the spectrum below and assign the signals to the corresponding protons. 2 4 3 ō (ppm) OH 4 6 6 СОН 2 1 0arrow_forward7. Assign all of the protons on the spectrum below. A B 2 C E 2 1 3 6 4 3 2 1 0arrow_forwarde. If (3R,4R)-3,4-dichloro-2,5-dimethylhexane and (3R,4S)-3,4-dichloro-2,5-dimethylhexane are in a solution at the same concentration, would this solution be expected to rotate plane polarized light (that is, be optically active)? Please provide your reasoning for your answer. [If you read this problem carefully, you will not need to draw out the structures to arrive at your answer...]arrow_forward
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