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Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

Section: Chapter Questions

Problem 1.1P

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Question

You are given the following experimental data set regarding methanol(1) and water(2) system at 298K and 1 bar.
Based on this data set estimate the molar volume of the methanol and water mixture with 75% by mole methanol at the same T and P of the experiment. Also what are the partial molar volumes of each component at this state?
(HINT: quadratic equation will be a reasonable assumption.)

Molar
Molar
Volume
Volume
(cm'/mol)
(cm/mol)
0.5416 29.326
0.5904 30.464
18.07
0.0545 19.13
0.1016 20.045
0.1532 21.054
0.2042 22.065
0.2516
0.645
0.6946 32.958
0.7391 34.048
0.7855 35.199
0.8388 | 36.54
0.8797 37.583
0.9284 38.843
40.732
31.76
23.022
23.936
0.296
0.3438 24.939
0.3937
26.01
0.4396 27.016
0.5057 28.502
1

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